Investigations Of The Adsorption Of Carbon Monoxide On Platinum And Palladium Surfaces By In-Situ FTIR-ATR-Spectroscopy

1989 ◽  
Author(s):  
E. Zippel ◽  
M. W. Breiter ◽  
R. Kellner
Keyword(s):  
Carbon Monoxide ◽  
In Situ Ftir ◽  
Atr Spectroscopy

scholarly journals Coadsorption of Nitriles and Co On Cu-Zsm-5: An In Situ FTIR Spectroscopic Study

1996 ◽  
Vol 431 ◽  
Author(s):  
J. Szanyi ◽  
M. T. Paffett
Keyword(s):  
Carbon Monoxide ◽  
Dipole Moment ◽  
Spectroscopic Study ◽  
Cross Section ◽  
In Situ Ftir ◽  
A Value

AbstractThe coadsorption of acetonitrile (ACN) or deuterated acetonitrile (dACN) with CO at Cu-ZSM-5 reveals several interesting features concerning the partial valency of Cu. Specifically, CO binds at Cu+1 and Cu° centers (in the absence of preadsorbed ACN) and exhibits C-O stretching frequencies of 2157 cm−1 and 2112 cm−1, respectively. Carbon monoxide readily adsorbs at an ACN (or dACN) saturated Cu-ZSM-5 and exhibits a C-O stretch of 2122 cm−1, a value more consistent with a partially reduced Cu+1 center. Furthermore, the IR cross section for the CN stretch in a number of nitriles (ACN, dACN, and benzonitrile) coadsorbed with CO displays interesting effects attributed to rehybridization and changes in CN dipole moment.

scholarly journals In situ FTIR study of CO2 reduction on inorganic analogues of carbon monoxide dehydrogenase

2021 ◽  
Author(s):  
Ji-Eun Lee ◽  
Akira Yamaguchi ◽  
Hideshi Ooka ◽  
Tomohiro Kazami ◽  
Masahiro Miyauchi ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Critical Role ◽  
Co2 Reduction ◽  
Carbon Monoxide Dehydrogenase ◽  
In Situ Ftir ◽  
Ftir Study ◽  
Ir Study

In situ electrochemical IR study of the CO2 reduction by inorganic analogues of carbon monoxide dehydrogenase (CODH) reveals the critical role of Ni in the activity and selectivity of Fe sulfides for CO2 reduction.

Nickel-catalyzed isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile: A kinetic study using in situ FTIR-ATR spectroscopy

2010 ◽  
Vol 155 (3-4) ◽  
pp. 271-278 ◽  
Author(s):  
Laura Bini ◽  
Erwin J.E. Houben ◽  
Evgeny A. Pidko ◽  
Christian Müller ◽  
Dieter Vogt
Keyword(s):  
Kinetic Study ◽  
In Situ Ftir ◽  
Atr Spectroscopy

Kinetic and in situ FTIR study of CO methanation on a Rh/Al2O3 catalyst

2015 ◽  
Vol 5 (9) ◽  
pp. 4532-4541 ◽  
Author(s):  
Mauricio Escobar ◽  
Francisco Gracia ◽  
Alejandro Karelovic ◽  
Romel Jiménez
Keyword(s):  
Carbon Monoxide ◽  
In Situ Ftir ◽  
Carbon Monoxide Hydrogenation ◽  
Co Methanation ◽  
Ftir Study ◽  
Infrared Measurements ◽  
Rh Catalyst ◽  
Al2o3 Catalyst

Carbon monoxide hydrogenation was studied over a γ-alumina-supported 1 wt% Rh catalyst by means of kinetic and in situ infrared measurements.

In Situ FTIR ATR Spectroscopy of the Preparation of an Oriented Monomolecular Film of Porin Omp32 on an Internal Reflecting Element by Dialysis

Langmuir ◽  
2003 ◽  
Vol 19 (18) ◽  
pp. 7451-7459 ◽  
Author(s):  
Michael Schwarzott ◽  
Harald Engelhardt ◽  
Thomas Klühspies ◽  
Dieter Baurecht ◽  
Dieter Naumann ◽  
...  
Keyword(s):  
In Situ Ftir ◽  
Monomolecular Film ◽  
Atr Spectroscopy
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