Optical Device Structures Grown By Liquid Phase Epitaxy (LPE)

1982 ◽  
Author(s):  
R. A. Logan
1986 ◽  
Vol 90 ◽  
Author(s):  
Tse Tung ◽  
M. H. Kalisher ◽  
A. P. Stevens ◽  
P. E. Herning

ABSTRACTOver the past few years, liquid-phase epitaxy (LPE) has become an established growth technique for the synthesis of HgCdTe. This paper reviews one of the most successful LPE technologies developed for HgCdTe, specifically, “infinite-melt” vertical LPE (VLPE) from Hg-rich solutions.Despite the very high Hg vapor pressure (> 10 atm) and the extremely low solubility of Cd in the Hg solution (< 10−3 mol%), this approach was believed to offer the best long-term prospect for growth of HgCdTe suitable for various device structures. Since the initial demonstration of LPE growth of HgCdTe layers from Hg solution in experiments conducted at SBRC in 1978, the VLPE technology has advanced to the point where epitaxial HgCdTe can now be grown for photoconductive (PC) and photovoltaic (PV) as well as monolithic metal-insulator-semiconductor (MIS) and high-frequency laser-detector devices with state-of-the-art performance in the entire 2–12 μm spectral region.A historical perspective and the current status of VLPE technology are reported. Particular emphasis is placed on the important role of the ther-modynamic parameters (phase diagram) and on control of stoichiometry (defect chemistry) and impurity doping (distribution coefficient) for growth of HgCdTe layers from Hg solution. Critical material characteristics, such as transport properties, minority-carrier lifetime, morphology and crystal structure, are also discussed. Finally, a comparison with the LPE technol-ogy using Te solutions, which has been the mainstay of the remainder of the IR community, is presented.


2006 ◽  
Vol 35 (6) ◽  
pp. 1192-1196 ◽  
Author(s):  
Changzhen Wang ◽  
Steve Tobin ◽  
Themis Parodos ◽  
David J. Smith

Author(s):  
N.A. Bert ◽  
A.O. Kosogov

The very thin (<100 Å) InGaAsP layers were grown not only by molecular beam epitaxy and metal-organic chemical vapor deposition but recently also by simple liquid phase epitaxy (LPE) technique. Characterization of their thickness, interfase abruptness and lattice defects is important and requires TEM methods to be used.The samples were InGaAsP/InGaP double heterostructures grown on (111)A GaAs substrate. The exact growth conditions are described in Ref.1. The salient points are that the quarternary layers were being grown at 750°C during a fast movement of substrate and a convection caused in the melt by that movement was eliminated. TEM cross-section specimens were prepared by means of conventional procedure. The studies were conducted in EM 420T and JEM 4000EX instruments.The (200) dark-field cross-sectional imaging is the most appropriate TEM technique to distinguish between individual layers in 111-v semiconductor heterostructures.


Author(s):  
F. Banhart ◽  
F.O. Phillipp ◽  
R. Bergmann ◽  
E. Czech ◽  
M. Konuma ◽  
...  

Defect-free silicon layers grown on insulators (SOI) are an essential component for future three-dimensional integration of semiconductor devices. Liquid phase epitaxy (LPE) has proved to be a powerful technique to grow high quality SOI structures for devices and for basic physical research. Electron microscopy is indispensable for the development of the growth technique and reveals many interesting structural properties of these materials. Transmission and scanning electron microscopy can be applied to study growth mechanisms, structural defects, and the morphology of Si and SOI layers grown from metallic solutions of various compositions.The treatment of the Si substrates prior to the epitaxial growth described here is wet chemical etching and plasma etching with NF3 ions. At a sample temperature of 20°C the ion etched surface appeared rough (Fig. 1). Plasma etching at a sample temperature of −125°C, however, yields smooth and clean Si surfaces, and, in addition, high anisotropy (small side etching) and selectivity (low etch rate of SiO2) as shown in Fig. 2.


1987 ◽  
Vol 23 (7) ◽  
pp. 324 ◽  
Author(s):  
P.D. Greene ◽  
A.D. Prins ◽  
D.J. Dunstan ◽  
A.R. Adams

Crystals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 189 ◽  
Author(s):  
Sandra Witkiewicz-Lukaszek ◽  
Anna Mrozik ◽  
Vitalii Gorbenko ◽  
Tetiana Zorenko ◽  
Pawel Bilski ◽  
...  

This work is dedicated to the development of new types of composite thermoluminescent (TL) detectors for simultaneous registration of the different components of ionization radiation based on the single crystalline films (SCFs) of Ce3+-doped Lu3−xGdxAl5O12:Ce (x = 0–1.5) garnet and Y3Al5O12:Ce (YAG:Ce) substrates using the liquid phase epitaxy (LPE) growth method. For this purpose, the TL properties of the mentioned epitaxial structures were examined in Risø TL/OSL-DA-20 reader under excitation by α- and β-particles from 242Am and 90Sr-90Y sources. We have shown that the cation engineering of SCF content can result in more significant separation of the TL glow curves of SCFs and substrates under α- and β-particle excitations in comparison with the prototype of such composite detectors based on the Lu3Al5O12:Ce (LuAG:Ce)/YAG:Ce epitaxial structure. Specifically, the difference between the TL glow curves of Lu1.5Gd1.5Al5O12:Ce SCFs and YAG:Ce substrates increases up to 120 K in comparison with a respective value of 80 degrees in the prototype based on the LuAG:Ce/YAG:Ce epitaxial structure. Therefore, the LPE-grown epitaxial structures containing Lu1.5Gd1.5Al5O12:Ce SCFs and Ce3+-doped YAG:Ce substrate can be successfully applied for simultaneous registration of α- and β-particles in mixed fluxes of ionization radiation.


1974 ◽  
Vol 13 (1) ◽  
pp. 203-204 ◽  
Author(s):  
Hidejiro Miki ◽  
Kazuaki Segawa ◽  
Keiji Fujibayashi

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