Preparation of low-density porous silica thin films by ambient pressure drying

2004 ◽  
Author(s):  
Lanfang Yao ◽  
Jun Shen ◽  
Guangming Wu ◽  
Xingyuan Ni ◽  
Jue Wang ◽  
...  
1995 ◽  
Vol 411 ◽  
Author(s):  
J. R. Kokan ◽  
R. A. Gerhardt

ABSTRACTImpedance Spectroscopy is being used to study the humidity sensitivity of porous silica thin films. The films are processed via a colloidal sol-gel method which leaves some remnant potassium and sodium. Previous work on bulk porous silica samples processed by the same method showed that the dielectric properties and ac conductivity were very sensitive to changes in humidity. The aim of this work was to determine if the same dependencies could be found in the thin films. The capacitance, dielectric loss, and ac conductivity of the films were measured in a controlled environment chamber from 20–80% RH for frequencies ranging from 10Hz–10MHz. In addition to characterizing films with varying amounts of residual alkali ions obtained through leaching, we have also measured films that were surface doped with controlled amounts of KCl, LiCl, or NaCl. Relative humidity dependencies in the films are not as dramatic as in the bulk samples. The reasons for this behavior are not yet clear, but may be associated with the porosity, thickness, and surface area of the films.


2013 ◽  
Vol 117 (21) ◽  
pp. 11385-11392 ◽  
Author(s):  
Anna Synak ◽  
Piotr Bojarski ◽  
Beata Grobelna ◽  
Leszek Kułak ◽  
Aneta Lewkowicz

2006 ◽  
Author(s):  
Lanfang Yao ◽  
Yongan Zhu ◽  
Dian Qu ◽  
Meifang Du ◽  
Jun Shen ◽  
...  

1996 ◽  
Vol 443 ◽  
Author(s):  
Teresa Ramos ◽  
Kevin Roderick ◽  
Alok Maskara ◽  
Douglas M. Smith

AbstractConsiderable progress has been made in development of thin films of nanoporous silica (also known as aerogels or low density xerogels) for ILD and IMD applications. Advantages of these materials include high thermal stability, small pore size, and similarity to conventional deposition processes, precursors and final material (silica). We have previously reported success in synthesizing low density, low dielectric constant (K<2) thin films using ambient pressure processing. However, processing of those films was complicated due to large number of process steps and difficulties in independently controlling both film thickness and film porosity.Nanoglass has now developed a new process which considerably reduces the number of process steps and allows independent control of both film thickness and porosity. The dielectric constant of the films can be tailored between 1.3 and 2.5. These films have improved mechanical properties due to controlled pore size and narrow pore size distribution and also because of higher density. The trade-offs between density, mechanical strength and dielectric constant for these types of porous solids will be elucidated. The known properties of the film and the process flow for deposition and post-deposition curing and the role of the relative rates of reaction, gelation, aging, and drying will be presented.


2006 ◽  
Vol 510-511 ◽  
pp. 910-913 ◽  
Author(s):  
Seung Hun Lee ◽  
Eun A Lee ◽  
Hae Jin Hwang ◽  
Ji Woong Moon ◽  
In Sub Han ◽  
...  

Hydrophobic silica aerogels were synthesized by an ambient pressure drying method from silicic acid with a different pH value, which was prepared from sodium silicate solution (water glass). In this study we chose various hydrocarbon class solvents such as pentane, hexane, heptane, and toluene, and performed surface modification in TMCS (trimethylchlorosilane)/solvent solutions in order to improve reproducibility in aerogel production. Densities of the aerogels were about 0.1 ~ 0.3 g/cm3 , and apparent porosities were 88 ~ 96 %, depending on the processing conditions. Specific surface area was approximately 730 ~ 950 m2/g, and average pore size around 10 nm.


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