Enhanced intrinsic luminescence of metal nanostructures during surface enhanced Raman scattering (Conference Presentation)

Author(s):  
Yuqing Cheng ◽  
Jingyi Zhao ◽  
Te Wen ◽  
Qihuang Gong ◽  
Aiqin Hu ◽  
...  
2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Chuyun Deng ◽  
Wanyun Ma ◽  
Jia-Lin Sun

Raman scattering signals can be enhanced by several orders of magnitude on surface-enhanced Raman scattering (SERS) substrates made from noble metal nanostructures. Some SERS substrates are even able to detect single-molecule Raman signals. A novel silver nanobud (AgNB) substrate with superior SERS activity was fabricated with a solid-state ionics method. The AgNB substrate was formed by tightly collocated unidirectional 100 nm size silver buds, presenting a highly rough surface topography. Distinct SERS signals of singleλ-DNA molecules in water were detected on AgNB substrates. AgNB substrates were compared with disordered silver nanowire (AgNW) substrates manufactured by the same method through the SERS detection ofλ-DNA solutions. This original AgNB substrate provides a reliable approach towards trace analysis of biomacromolecules and promotes the utilization of the SERS technique in biomedical research.


NANO ◽  
2021 ◽  
Author(s):  
Jing Wu ◽  
Jiali Shen ◽  
Jinghuai Fang ◽  
Lu Xu

Since the morphology and element composition of metal nanostructures strongly affect the surface plasma oscillation characteristics, it has been widely concerned in surface enhanced Raman scattering (SERS). Herein, we proposed a novel route to fabricate composite Au/Ag nanoparticle arrays with synergistic effect for electromagnetic enhancement. Ag nanoparticles were electrodeposited onto a home-made template with highly ordered bowl-like pits. After a novel method of “confined annealing”, we further achieved well-regulated spherical Ag NP arrays, and the composite Au/Ag nanoparticle arrays were finally obtained via in situ replacement. The fabricated composite nanostructures showed stable and sensitive surface enhanced Raman scattering (SERS) performance mainly due to the synergistic effect and abundant “hot spots”, with the enhancement factor (EF) of [Formula: see text] for crystal violet (CV) molecules. In addition, this simple and effective preparation process greatly improved the uniformity of three-dimensional nanostructures, providing a new idea for further improving the stability of SERS signals.


2017 ◽  
Vol 26 (3) ◽  
pp. 241 ◽  
Author(s):  
Kieu Ngoc Minh ◽  
Cao Tuan Anh ◽  
Luong Truc Quynh Ngan ◽  
Le Van Vu ◽  
Dao Tran Cao

To enhance the intensity of surface-enhanced Raman scattering (SERS), production of metal nanostructures with sharp points, lying side by side at the nanometer level plays an extremely important role. In this paper, we report on a manufacturing process in which the silver nanoparticles with the flower-like shape have been fabricated. Such silver nanoparticles have been fabricated by chemical deposition of silver particles on silicon wafers, using a solution of hydrofluoric acid (HF), silver nitrate (AgNO3) and ascorbic acid (AsA) in water, at room temperature. During the manufacturing we found that only when the concentrations of AgNO3 and AsA are appropriate, the flower-like silver nanoparticles will form. Note that while other authors mainly made flower-like silver nanoparticles in the form of suspensions, we have created flower-like silver nanoparticles with cabbage-shape on a silicon surface. The ensembles of flower-like silver nanoparticles above were used as SERS substrates to detect crystal violet (CV) in low concentrations and good results were obtained.


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