Viscoelastic polymer semiconductors for stretchable electronics: the importance of interfaces on mechanical behavior (Conference Presentation)

2018 ◽  
Author(s):  
Tianlei Sun ◽  
Runqiao Song ◽  
Nrup Balar ◽  
Brendan T. O'Connor
Keyword(s):  
Mechanical Behavior ◽  
Stretchable Electronics ◽  
Viscoelastic Polymer ◽  
Polymer Semiconductors

scholarly journals A design strategy for high mobility stretchable polymer semiconductors

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jaewan Mun ◽  
Yuto Ochiai ◽  
Weichen Wang ◽  
Yu Zheng ◽  
Yu-Qing Zheng ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Molecular Design ◽  
High Mobility ◽  
Molecular Engineering ◽  
Semiconducting Polymers ◽  
Stretchable Electronics ◽  
General Applicability ◽  
Multi Scale ◽  
Polymer Semiconductors ◽  
Engineering Strategy

AbstractAs a key component in stretchable electronics, semiconducting polymers have been widely studied. However, it remains challenging to achieve stretchable semiconducting polymers with high mobility and mechanical reversibility against repeated mechanical stress. Here, we report a simple and universal strategy to realize intrinsically stretchable semiconducting polymers with controlled multi-scale ordering to address this challenge. Specifically, incorporating two types of randomly distributed co-monomer units reduces overall crystallinity and longer-range orders while maintaining short-range ordered aggregates. The resulting polymers maintain high mobility while having much improved stretchability and mechanical reversibility compared with the regular polymer structure with only one type of co-monomer units. Interestingly, the crystalline microstructures are mostly retained even under strain, which may contribute to the improved robustness of our stretchable semiconductors. The proposed molecular design concept is observed to improve the mechanical properties of various p- and n-type conjugated polymers, thus showing the general applicability of our approach. Finally, fully stretchable transistors fabricated with our newly designed stretchable semiconductors exhibit the highest and most stable mobility retention capability under repeated strains of 1,000 cycles. Our general molecular engineering strategy offers a rapid way to develop high mobility stretchable semiconducting polymers.

Application of TEM to Deformation, Wear, and Fracture of Ceramics

1974 ◽  
Vol 32 ◽  
pp. 472-473
Author(s):  
B. J. Hockey
Keyword(s):  
Wear Resistance ◽  
High Temperature ◽  
Mechanical Behavior ◽  
Brittle Materials ◽  
High Temperature Strength ◽  
Wide Range ◽  
Corrosive Environments ◽  
Further Development

Ceramics, such as Al2O3 and SiC have numerous current and potential uses in applications where high temperature strength, hardness, and wear resistance are required often in corrosive environments. These materials are, however, highly anisotropic and brittle, so that their mechanical behavior is often unpredictable. The further development of these materials will require a better understanding of the basic mechanisms controlling deformation, wear, and fracture.The purpose of this talk is to describe applications of TEM to the study of the deformation, wear, and fracture of Al2O3. Similar studies are currently being conducted on SiC and the techniques involved should be applicable to a wide range of hard, brittle materials.

The influence of the addition of ground olive stone on the thermo-mechanical behavior of compressed earth blocks

2020 ◽  
Vol 108 (2) ◽  
pp. 203
Author(s):  
Samia Djadouf ◽  
Nasser Chelouah ◽  
Abdelkader Tahakourt
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Mechanical Behavior ◽  
Agricultural Waste ◽  
Hydraulic Press ◽  
Dry Density ◽  
Olive Stone ◽  
Compressed Earth Blocks ◽  
Clay Matrix ◽  
Earth Blocks

Sustainable development and environmental challenges incite to valorize local materials such as agricultural waste. In this context, a new ecological compressed earth blocks (CEBS) with addition of ground olive stone (GOS) was proposed. The GOS is added as partial clay replacement in different proportions. The main objective of this paper is to study the effect of GOS levels on the thermal properties and mechanical behavior of CEB. We proceeded to determining the optimal water content and equivalent wet density by compaction using a hydraulic press, at a pressure of 10 MPa. The maximum compressive strength is reached at 15% of the GOS. This percentage increases the mechanical properties by 19.66%, and decreases the thermal conductivity by 37.63%. These results are due to the optimal water responsible for the consolidation and compactness of the clay matrix. The substitution up to 30% of GOS shows a decrease of compressive strength and thermal conductivity by about 38.38% and 50.64% respectively. The decrease in dry density and thermal conductivity is related to the content of GOS, which is composed of organic and porous fibers. The GOS seems promising for improving the thermo-mechanical characteristics of CEB and which can also be used as reinforcement in CEBS.

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