Sulphonated mesoporous silica as proton exchanging layer in solid state organic transistors for bio-sensing (Conference Presentation)

Author(s):  
Soniya D. Yambem
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Gerd Buntkowsky ◽  
Sonja Döller ◽  
Nadia Haro-Mares ◽  
Torsten Gutmann ◽  
Markus Hoffmann

Abstract This review gives an overview of current trends in the investigation of confined molecules such as higher alcohols, ethylene glycol and polyethylene glycol as guest molecules in neat and functionalized mesoporous silica materials. All these molecules have both hydrophobic and hydrophilic parts. They are characteristic role-models for the investigation of confined surfactants. Their properties are studied by a combination of solid-state NMR and relaxometry with other physicochemical techniques and molecular dynamics techniques. It is shown that this combination delivers unique insights into the structure, arrangement, dynamical properties and the guest-host interactions inside the confinement.


2002 ◽  
Vol 17 (7) ◽  
pp. 1843-1848 ◽  
Author(s):  
Li-Qiong Wang ◽  
Christopher L. Aardahl ◽  
Kenneth G. Rappé ◽  
Diana N. Tran ◽  
Marisol A. Delgado ◽  
...  

Aluminum coordination distribution for alumina catalysts supported on mesoporous silica was examined. It was shown that aluminum coordination correlates to activity of the catalysts for plasma-enhanced, selective catalytic reduction of NOx with propene. Catalysts were prepared by incorporating aluminum onto the surface of a mesoporous silica support via three different post-synthesis routes to produce varying aluminum coordination. Aluminum trichloride, sodium aluminate, and aluminum isopropoxide precursors were examined. High-resolution, solid state 27Al nuclear magnetic resonance was used to determine aluminum coordination distributions for the resulting catalysts. Unsaturated aluminum sites (i.e., structural defects) correlated with increased activity at high temperatures while tetrahedrally-coordinated aluminum or BrØnsted acid sites correlated with activity at low temperatures.


2018 ◽  
Vol 55 ◽  
pp. 63-68 ◽  
Author(s):  
Benjamin Nketia-Yawson ◽  
Grace Dansoa Tabi ◽  
Yong Xu ◽  
Yong-Young Noh

2016 ◽  
Vol 45 (25) ◽  
pp. 10447-10458 ◽  
Author(s):  
Eva C. Uribe ◽  
Harris E. Mason ◽  
Jennifer A. Shusterman ◽  
Anthony Bruchet ◽  
Heino Nitsche

Solid-state NMR techniques combined with batch contact experiments elucidate how U(vi) binds to phosphonate-functionalized mesoporous silica.


2018 ◽  
Vol 9 (20) ◽  
pp. 4589-4599 ◽  
Author(s):  
Ignacio Luz ◽  
Mustapha Soukri ◽  
Marty Lail

Solid-state synthesis ensures a high loading and well dispersed growth of a large collection of metal–organic framework (MOF) nanostructures within a series of commercially available mesoporous silica allowing to render MOFs into fluidized solid sorbents for CO2 capture from post-combustion flue gas in a fluidized-bed reactor.


2016 ◽  
Vol 81 ◽  
pp. 347-364 ◽  
Author(s):  
Dimitris S. Achilias ◽  
Kostas Gerakis ◽  
Dimitrios J. Giliopoulos ◽  
Kostas S. Triantafyllidis ◽  
Dimitrios N. Bikiaris

2013 ◽  
Vol 2013 (13) ◽  
pp. 2350-2361 ◽  
Author(s):  
Nicolas Bibent ◽  
Thibault Charpentier ◽  
Sabine Devautour-Vinot ◽  
Ahmad Mehdi ◽  
Philippe Gaveau ◽  
...  

2005 ◽  
Vol 127 (9) ◽  
pp. 3057-3068 ◽  
Author(s):  
Julien Trébosc ◽  
Jerzy W. Wiench ◽  
Seong Huh ◽  
Victor S.-Y. Lin ◽  
Marek Pruski

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