Solid-State NMR Spectroscopic Studies of Propylphosphonic Acid Functionalized SBA-15 Mesoporous Silica: Characterization of Hydrogen-Bonding Interactions

2013 ◽  
Vol 2013 (13) ◽  
pp. 2350-2361 ◽  
Author(s):  
Nicolas Bibent ◽  
Thibault Charpentier ◽  
Sabine Devautour-Vinot ◽  
Ahmad Mehdi ◽  
Philippe Gaveau ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Mesoporous Silica ◽  
Solid State Nmr ◽  
Spectroscopic Studies ◽  
Hydrogen Bonding Interactions

scholarly journals Hydrogen-Bonding Interactions in T-2 Toxin Studied Using Solution and Solid-State NMR

Toxins ◽  
2011 ◽  
Vol 3 (10) ◽  
pp. 1310-1331 ◽  
Author(s):  
Praveen Chaudhary ◽  
Roxanne A. Shank ◽  
Tony Montina ◽  
James T. Goettel ◽  
Nora A. Foroud ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Solid State Nmr ◽  
Hydrogen Bonding Interactions

Solid-State NMR Characterization of Phenylbenzimidazolesulfonic Acid Coencapsulated with Cetyltrimethylammonium in Mesoporous Silica Materials

2009 ◽  
Vol 114 (2) ◽  
pp. 752-759 ◽  
Author(s):  
Raphaël Bongur ◽  
Nicolas Marx ◽  
Claire Marichal ◽  
Bénédicte Lebeau ◽  
Philippe Guarilloff
Keyword(s):  
Solid State ◽  
Mesoporous Silica ◽  
Solid State Nmr ◽  
Nmr Characterization ◽  
Silica Materials ◽  
Mesoporous Silica Materials

Synthesis and solid-state NMR characterization of cubic mesoporous silica SBA-1 functionalized with sulfonic acid groups

2011 ◽  
Vol 359 (1) ◽  
pp. 86-94 ◽  
Author(s):  
Hui-Hsu Gavin Tsai ◽  
Po-Jui Chiu ◽  
Guang-Liang Jheng ◽  
Chun-Chiang Ting ◽  
Yu-Chi Pan ◽  
...  
Keyword(s):  
Solid State ◽  
Mesoporous Silica ◽  
Solid State Nmr ◽  
Sulfonic Acid ◽  
Nmr Characterization ◽  
Cubic Mesoporous ◽  
Sulfonic Acid Groups

scholarly journals Structure and physicochemical characterization of a naproxen–picolinamide cocrystal

2017 ◽  
Vol 73 (3) ◽  
pp. 168-175 ◽  
Author(s):  
Hannah E. Kerr ◽  
Lorna K. Softley ◽  
Kuthuru Suresh ◽  
Paul Hodgkinson ◽  
Ivana Radosavljevic Evans
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Solid State Nmr ◽  
Density Functional ◽  
Physicochemical Characterization ◽  
Density Functional Theory Calculations ◽  
Cooh Group ◽  
Intrinsic Dissolution ◽  
Nmr Crystallography

Naproxen (NPX) is a nonsteroidal anti-inflammatory drug with pain- and fever-relieving properties, currently marketed in the sodium salt form to overcome solubility problems; however, alternative solutions for improving its solubility across all pH values are desirable. NPX is suitable for cocrystal formation, with hydrogen-bonding possibilities via the COOH group. The crystal structure is presented of a 1:1 cocrystal of NPX with picolinamide as a coformer [systematic name: (S)-2-(6-methoxynaphthalen-2-yl)propanoic acid–pyridine-2-carboxamide (1/1), C14H14O3·C6H6N2O]. The pharmaceutically relevant physical properties were investigated and the intrinsic dissolution rate was found to be essentially the same as that of commercial naproxen. An NMR crystallography approach was used to investigate the H-atom positions in the two crystallographically unique COOH–CONH hydrogen-bonded dimers. 1H solid-state NMR distinguished the two carboxyl protons, despite the very similar crystallographic environments. The nature of the hydrogen bonding was confirmed by solid-state NMR and density functional theory calculations.

Hydrogen Bonding of Water Confined in Mesoporous Silica MCM-41 and SBA-15 Studied by1H Solid-State NMR

2004 ◽  
Vol 10 (22) ◽  
pp. 5689-5696 ◽  
Author(s):  
Bob Grünberg ◽  
Thomas Emmler ◽  
Egbert Gedat ◽  
Ilja Shenderovich ◽  
Gerhard H. Findenegg ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Mesoporous Silica ◽  
Solid State Nmr ◽  
Mcm 41

Direct Synthesis and Solid-State NMR Characterization of Cubic Mesoporous Silica SBA-1 Functionalized with Phenyl Groups

2008 ◽  
Vol 20 (6) ◽  
pp. 2412-2422 ◽  
Author(s):  
Hsien-Ming Kao ◽  
Chia-Hsiu Liao ◽  
Tzu-Ti Hung ◽  
Yu-Chi Pan ◽  
Anthony S. T. Chiang
Keyword(s):  
Solid State ◽  
Mesoporous Silica ◽  
Solid State Nmr ◽  
Direct Synthesis ◽  
Nmr Characterization ◽  
Cubic Mesoporous

scholarly journals Use of Solid-State NMR Spectroscopy for the Characterization of Molecular Structure and Dynamics in Solid Polymer and Hybrid Electrolytes

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1207
Author(s):  
Gabrielle Foran ◽  
Nina Verdier ◽  
David Lepage ◽  
Cédric Malveau ◽  
Nicolas Dupré ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Pulse Sequence ◽  
Dynamic Properties ◽  
Double Resonance ◽  
Solid Polymer ◽  
Pulse Field ◽  
Solid State Nmr Spectroscopy

Solid-state NMR spectroscopy is an established experimental technique which is used for the characterization of structural and dynamic properties of materials in their native state. Many types of solid-state NMR experiments have been used to characterize both lithium-based and sodium-based solid polymer and polymer–ceramic hybrid electrolyte materials. This review describes several solid-state NMR experiments that are commonly employed in the analysis of these systems: pulse field gradient NMR, electrophoretic NMR, variable temperature T1 relaxation, T2 relaxation and linewidth analysis, exchange spectroscopy, cross polarization, Rotational Echo Double Resonance, and isotope enrichment. In this review, each technique is introduced with a short description of the pulse sequence, and examples of experiments that have been performed in real solid-state polymer and/or hybrid electrolyte systems are provided. The results and conclusions of these experiments are discussed to inform readers of the strengths and weaknesses of each technique when applied to polymer and hybrid electrolyte systems. It is anticipated that this review may be used to aid in the selection of solid-state NMR experiments for the analysis of these systems.

Sign in / Sign up

Export Citation Format

Share Document