Relationship between spectral reflected irradiance at the sea surface and optical properties of marine phytoplankton

1994 ◽  
Author(s):  
Bogdan Wozniak ◽  
Witold von Smekot-Wensierksi ◽  
Roland Doerffer ◽  
Hartmut Grassl
2002 ◽  
Vol 2 (2) ◽  
pp. 99-101 ◽  
Author(s):  
M.-D. Chou ◽  
R. S. Lindzen ◽  
A. Y. Hou

Abstract. In assessing the iris effect suggested by Lindzen et al. (2001), Fu et al. (2002) found that the response of high-level clouds to the sea surface temperature had an effect of reducing the climate sensitivity to external radiative forcing, but the effect was not as strong as LCH found. The approach of FBH to specifying longwave emission and cloud albedos appears to be inappropriate, and the derived cloud optical properties may not have real physical meaning. The cloud albedo calculated by FBH is too large for cirrus clouds and too small for boundary layer clouds, which underestimates the iris effect.


2020 ◽  
Vol 17 (9) ◽  
pp. 2453-2471 ◽  
Author(s):  
Helmke Hepach ◽  
Claire Hughes ◽  
Karen Hogg ◽  
Susannah Collings ◽  
Rosie Chance

Abstract. The reaction between ozone and iodide at the sea surface is now known to be an important part of atmospheric ozone cycling, causing ozone deposition and the release of ozone-depleting reactive iodine to the atmosphere. The importance of this reaction is reflected by its inclusion in chemical transport models (CTMs). Such models depend on accurate sea surface iodide fields, but measurements are spatially and temporally limited. Hence, the ability to predict current and future sea surface iodide fields, i.e. sea surface iodide concentration on a narrow global grid, requires the development of process-based models. These models require a thorough understanding of the key processes that control sea surface iodide. The aim of this study was to explore if there are common features of iodate-to-iodide reduction amongst diverse marine phytoplankton in order to develop models that focus on sea surface iodine and iodine release to the troposphere. In order to achieve this, rates and patterns of changes in inorganic iodine speciation were determined in 10 phytoplankton cultures grown at ambient iodate concentrations. Where possible these data were analysed alongside results from previous studies. Iodate loss and some iodide production were observed in all cultures studied, confirming that this is a widespread feature amongst marine phytoplankton. We found no significant difference in log-phase, cell-normalised iodide production rates between key phytoplankton groups (diatoms, prymnesiophytes including coccolithophores and phaeocystales), suggesting that a phytoplankton functional type (PFT) approach would not be appropriate for building an ocean iodine cycling model. Iodate loss was greater than iodide formation in the majority of the cultures studied, indicating the presence of an as-yet-unidentified “missing iodine” fraction. Iodide yield at the end of the experiment was significantly greater in cultures that had reached a later senescence stage. This suggests that models should incorporate a lag between peak phytoplankton biomass and maximum iodide production and that cell mortality terms in biogeochemical models could be used to parameterise iodide production.


Sensors ◽  
2020 ◽  
Vol 20 (18) ◽  
pp. 5352
Author(s):  
Emilia Baszanowska ◽  
Zbigniew Otremba ◽  
Jacek Piskozub

This paper analyzes the digital modelling of radiance reflectance of the sea surface when the water column is polluted by oil-in-water emulsion. A method tracking the fate of two billion virtual solar photons was applied to obtain the angular distribution of bottom-up radiance for a plane of sunlight striking the sea surface. For the calculations, the inherent optical properties of seawater characteristic for the Gulf of Gdańsk (southern Baltic Sea) were used. The analyses were performed for two types of oils with extremely different optical properties for an oil concentration of 10 ppm and for a roughened sea surface with a wind speed of 2 m/s. The spectral index for oil detection in seawater for different viewing angles was determined based on the results obtained for reflectance at eight wavelengths in the range of 412–676 nm for viewing angle in the range from 80° to 0°, both on the side of incidence of direct sunlight and on the opposite side. The resulting calculated spectral indexes for different wavelength combinations indicated significant dependence on the viewing angle.


Author(s):  
Giuseppe Aulicino ◽  
Yuri Cotroneo ◽  
Teodosio Lacava ◽  
Giancanio Sileo ◽  
Giannetta Fusco ◽  
...  

<p>A wave-propelled autonomous vehicle (Wave Glider) instrumented with a variety of oceanographic and meteorological sensors was launched from Gulf of Naples on the 12<sup>th </sup>of September 2012 for a two-week mission in the Southern Tyrrhenian Sea. The main objective of the mission was a preliminary evaluation of the potential of commercial autonomous platforms to provide reliable measurements of sea surface parameters which can complement existing satellite based products moving from the local to the synoptic scale. To this aim Wave Glider measurements were compared to equivalent, or near-equivalent, satellite products achieved from MODIS (Moderate Resolution Imaging Spectroradiometer) sensors onboard the EOS (Earth Observing System) satellite platforms and from AVISO (Archiving Validation and Interpretation of Satellite Oceanographic Data). Level-3 near real time and Level-4 reprocessed sea surface foundation temperature products provided by the CMEMS (Copernicus Marine Environment Monitoring Service) were also included in this study as well as high resolution model output supplied by NEMO (Nucleus for European Modelling of the Ocean). The Wave Glider was equipped with sensors to measure temperature, salinity, currents, as well as Colored Dissolved Organic Matter (CDOM), turbidity and refined fuels fluorescence. The achieved results confirmed the emerging value of Wave Gliders in the framework of multiplatform monitoring systems of the ocean surface parameters. In particular, they showed that Wave Glider measurements captured the southern Tyrrhenian Sea major surface oceanographic features, including the coast to open sea haline gradient and the presence of a cyclone-anticyclone system in the southeastern sub-region. The Wave Glider also had the capability to monitor upper ocean currents at finer spatial and temporal scales than satellite altimetric observations and model outputs. Nonetheless, results stressed the existence of several limits in the combined use of satellite and Wave Glider observations and the necessity of further analyses concerning the monitoring of the ocean optical properties. In fact, Wave Glider and satellite-based products agree in terms of sea surface temperature and currents patterns, while bio-optical properties turned out to be less well correlated. No significant traces of refined fuels have been detected along the WG track.</p>


2013 ◽  
Vol 10 (2) ◽  
pp. 3627-3676 ◽  
Author(s):  
L. Bopp ◽  
L. Resplandy ◽  
J. C. Orr ◽  
S. C. Doney ◽  
J. P. Dunne ◽  
...  

Abstract. Ocean ecosystems are increasingly stressed by human-induced changes of their physical, chemical and biological environment. Among these changes, warming, acidification, deoxygenation and changes in primary productivity by marine phytoplankton can be considered as four of the major stressors of open ocean ecosystems. Due to rising atmospheric CO2 in the coming decades, these changes will be amplified. Here, we use the most recent simulations performed in the framework of the Coupled Model Intercomparison Project 5 to assess how these stressors may evolve over the course of the 21st century. The 10 Earth System Models used here project similar trends in ocean warming, acidification, deoxygenation and reduced primary productivity for each of the IPCC's representative concentration parthways (RCP) over the 21st century. For the "business-as-usual" scenario RCP8.5, the model-mean changes in 2090s (compared to 1990s) for sea surface temperature, sea surface pH, global O2 content and integrated primary productivity amount to +2.73 °C, −0.33 pH unit, −3.45% and −8.6%, respectively. For the high mitigation scenario RCP2.6, corresponding changes are +0.71 °C, −0.07 pH unit, −1.81% and −2.0% respectively, illustrating the effectiveness of extreme mitigation strategies. Although these stressors operate globally, they display distinct regional patterns. Large decreases in O2 and in pH are simulated in global ocean intermediate and mode waters, whereas large reductions in primary production are simulated in the tropics and in the North Atlantic. Although temperature and pH projections are robust across models, the same does not hold for projections of sub-surface O2 concentrations in the tropics and global and regional changes in net primary productivity.


2003 ◽  
Vol 258 ◽  
pp. 19-30 ◽  
Author(s):  
HA Bouman ◽  
T Platt ◽  
S Sathyendranath ◽  
WKW Li ◽  
V Stuart ◽  
...  

2002 ◽  
Vol 2 (1) ◽  
pp. 173-180 ◽  
Author(s):  
M.-D. Chou ◽  
R. S. Lindzen ◽  
A. Y. Hou

Abstract. In assessing the iris effect suggested by Lindzen et al. (2001), Fu et al. (2001, 2002) found that the response of high-level clouds to the sea surface temperature had an effect of reducing the climate sensitivity to external radiative forcing, but the effect was not as strong as Lindzen et al. (2001) found. The approach of Fu et al. (2001, 2002) to specifying longwave emission and cloud albedos appears to be inappropriate, and the derived cloud optical properties may not have real physical meaning. The cloud albedo calculated by Fu et al. (2001, 2002) is too large for cirrus clouds and too small for boundary layer clouds, which underestimates the iris effect.


2013 ◽  
Vol 10 (10) ◽  
pp. 6225-6245 ◽  
Author(s):  
L. Bopp ◽  
L. Resplandy ◽  
J. C. Orr ◽  
S. C. Doney ◽  
J. P. Dunne ◽  
...  

Abstract. Ocean ecosystems are increasingly stressed by human-induced changes of their physical, chemical and biological environment. Among these changes, warming, acidification, deoxygenation and changes in primary productivity by marine phytoplankton can be considered as four of the major stressors of open ocean ecosystems. Due to rising atmospheric CO2 in the coming decades, these changes will be amplified. Here, we use the most recent simulations performed in the framework of the Coupled Model Intercomparison Project 5 to assess how these stressors may evolve over the course of the 21st century. The 10 Earth system models used here project similar trends in ocean warming, acidification, deoxygenation and reduced primary productivity for each of the IPCC's representative concentration pathways (RCPs) over the 21st century. For the "business-as-usual" scenario RCP8.5, the model-mean changes in the 2090s (compared to the 1990s) for sea surface temperature, sea surface pH, global O2 content and integrated primary productivity amount to &amp;plus;2.73 (±0.72) °C, −0.33 (±0.003) pH unit, −3.45 (±0.44)% and −8.6 (±7.9)%, respectively. For the high mitigation scenario RCP2.6, corresponding changes are +0.71 (±0.45) °C, −0.07 (±0.001) pH unit, −1.81 (±0.31)% and −2.0 (±4.1)%, respectively, illustrating the effectiveness of extreme mitigation strategies. Although these stressors operate globally, they display distinct regional patterns and thus do not change coincidentally. Large decreases in O2 and in pH are simulated in global ocean intermediate and mode waters, whereas large reductions in primary production are simulated in the tropics and in the North Atlantic. Although temperature and pH projections are robust across models, the same does not hold for projections of subsurface O2 concentrations in the tropics and global and regional changes in net primary productivity. These high uncertainties in projections of primary productivity and subsurface oxygen prompt us to continue inter-model comparisons to understand these model differences, while calling for caution when using the CMIP5 models to force regional impact models.


2019 ◽  
Author(s):  
Helmke Hepach ◽  
Claire Hughes ◽  
Karen Hogg ◽  
Susannah Collings ◽  
Rosie Chance

Abstract. The reaction between ozone and iodide at the sea surface is now known to be an important part of atmospheric ozone cycling, causing ozone deposition and the release of ozone-depleting reactive iodine to the atmosphere. The importance of this reaction is reflected by its inclusion in chemical transport models (CTMs). Such models depend on accurate sea surface iodide fields but measurements are spatially and temporally limited. The ability to predict current and future sea surface iodide fields requires the development of process-based models which in turn require a thorough understanding of the key processes controlling inorganic iodine cycling. The aim of this study was to inform the development of ocean iodine cycling models by exploring if there are common features of iodate to iodide reduction amongst diverse marine phytoplankton. In order to achieve this, rates and patterns of changes in inorganic iodine speciation were determined in 10 phytoplankton cultures grown at ambient iodate concentrations. Where possible these data were analysed alongside results from previous studies. Iodate loss and some iodide production was observed in all cultures studied, confirming that this is a widespread feature amongst marine phytoplankton. We found no significant difference in log-phase, cell-normalised iodide production rates between key phytoplankton groups (diatoms, prymesiophytes including coccolithophores and phaeocystales) suggesting that a Phytoplankton Functional Type (PFT) approach would not be appropriate for building an ocean iodine cycling model. Iodate loss was greater than iodide formation in the majority of the cultures studied, indicating the presence of an as yet unidentified missing iodine fraction. Iodide yield at the end of the experiment was significantly greater in cultures that had reached a later senescence stage. This suggests that models should incorporate a lag between peak phytoplankton biomass and maximum iodide production, and that cell mortality terms in biogeochemical models could be used to parameterize iodide production.


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