Large grain size CdTe films grown on glass substrates at low temperature

1995 ◽  
Vol 13 (6) ◽  
pp. 2994-2996 ◽  
Author(s):  
M. Zapata‐Torres ◽  
R. Castro‐Rodríguez ◽  
A. Zapata‐Navarro ◽  
John L. Wallace ◽  
Ramón Pomes ◽  
...  
1995 ◽  
Vol 410 ◽  
Author(s):  
D. Albin ◽  
D. Rose ◽  
A. Swartzlander ◽  
H. Moutinho ◽  
F. Hasoon ◽  
...  

ABSTRACTThe microstructure of CdTe sources grown on bare 7059 and SnO2-coated 7059 glass substrates used in the close-space sublimation (CSS) growth of CdTe films, is affected by nucleation conditions during their fabrication. For CdTe sources grown on bare glass substrates, denser source microstructures with smaller grains are promoted by low-temperature nucleation conditions. Growth rates of CdTe films deposited using these source plates are inversely proportional to the packing density of the grains. CdTe sources grown on glass undergo significant texture changes during their use in subsequent CSS deposition. CdTe sources grown on SnO2-coated glass substrates exhibit dense structures both with and without low-temperature nucleation and increased grain size with low-temperature nucleation. These source plates show less texture change associated with thermal annealing than their bare-glass counterparts, however, they are much more susceptible to CdO formation during subsequent CSS deposition processes in which oxygen is present. Source oxidation results in a decrease of the (111)/(220) x-ray diffraction intensity. Analysis of the (111)/(220) intensity ratio with and without source oxidation suggests the preferential formation of CdO on the (111) planes. In general, source oxidation appears to be a inversely proportional to the grain size of the source material.


1988 ◽  
Vol 63 (2) ◽  
pp. 410-413 ◽  
Author(s):  
O. Zelaya ◽  
F. Sánchez‐Sinencio ◽  
J. G. Mendoza‐Alvarez ◽  
M. H. Farías ◽  
L. Cota‐Araiza ◽  
...  

2021 ◽  
pp. 174751982098472
Author(s):  
Lalmi Khier ◽  
Lakel Abdelghani ◽  
Belahssen Okba ◽  
Djamel Maouche ◽  
Lakel Said

Kaolin M1 and M2 studied by X-ray diffraction focus on the mullite phase, which is the main phase present in both products. The Williamson–Hall and Warren–Averbach methods for determining the crystallite size and microstrains of integral breadth β are calculated by the FullProf program. The integral breadth ( β) is a mixture resulting from the microstrains and size effect, so this should be taken into account during the calculation. The Williamson–Hall chart determines whether the sample is affected by grain size or microstrain. It appears very clearly that the principal phase of the various sintered kaolins, mullite, is free from internal microstrains. It is the case of the mixtures fritted at low temperature (1200 °C) during 1 h and also the case of the mixtures of the type chamotte cooks with 1350 °C during very long times (several weeks). This result is very significant as it gives an element of explanation to a very significant quality of mullite: its mechanical resistance during uses at high temperature remains.


2009 ◽  
Vol 1165 ◽  
Author(s):  
Vello Valdna ◽  
Maarja Grossberg ◽  
Hiie Jaan ◽  
Urve Kallavus ◽  
Valdek Mikli ◽  
...  

AbstractShort-bandgap group II-VI compound cadmium telluride is widely used for the infrared optics, radiation detectors, and solar cells where p-type CdTe is needed. p-type conductivity of CdTe is mainly caused by the chlorine-based A-centers, and in part, by the less stable copper-oxygen complexes. As a rule, CdTe films are recrystallized by the help of a cadmium chloride flux that saturates CdTe with chlorine. In chlorine-saturated CdTe A-centers are converted to isoelectronic complexes that cause resistivity increasement of CdTe up to 9 orders of magnitude. Excess copper and oxygen or group I elements as sodium also deteriorate the p-type conductivity of CdTe like excess chlorine. p-type conductivity of CdTe can be restored e.g. by the vacuum annealing which removes excess chlorine from the film. Unfortunately, treatment that betters p-type conductivity of the CdTe film degrades the junction of the superstrate configuration cells. In this work we investigate possibilities to prepare p-type CdTe films on the molybdenum coated glass substrates. Samples were prepared by the vacuum evaporation and dynamic recrystallization of 6N purity CdTe on the top of Mo-coated glass substrates. Then samples were recrystallized with cadmium chloride flux under tellurium vapour pressure. Results of the test studies on the structure and electronic parameters of samples are presented and discussed.


2004 ◽  
Vol 447-448 ◽  
pp. 435-440 ◽  
Author(s):  
M. Noda ◽  
Kunio Funami ◽  
M. Hirohashi ◽  
M. Kobayashi
Keyword(s):  

1999 ◽  
Vol 74 (25) ◽  
pp. 3884-3886 ◽  
Author(s):  
A. de Andrés ◽  
M. Garcı́a-Hernández ◽  
J. L. Martı́nez ◽  
C. Prieto
Keyword(s):  

Author(s):  
Tilman Beierlein ◽  
S. Strite ◽  
A. Dommann ◽  
D. J. Smith

We have investigated the properties of InGaN grown at low temperature on glass substrates by a plasma enhanced MBE process. The goal of this study was to evaluate the potential of InGaN as an oxide-free, transparent conductor material which could be deposited at or slightly above room temperature with minimal interaction or damage to the underlying material. InxGa1−xN films deposited on glass, even without substrate heating, are highly crystalline, but the crystallinity as measured by x-ray degrades at x < 0.5. The microstructure observed by TEM of InGaN films deposited on unheated substrates is highly columnar, with typical column widths of ~10 nm. The optical absorption spectra of InGaN/glass have a distinct absorption edge at the bandgap, but also high background absorption in the bandgap. InxGa1−xN grown on glass (x > 0.5) is conductive due to its high electron concentration. InN electron Hall mobilities > 20 cm2/Vs when grown at 400°C, and ~ 7 cm2/Vs on unheated substrates were obtained. The addition of GaN degraded the electrical properties of the films to a greater extent than it improved the transparency. As a result, the best transparent conductor films were pure InN which, when deposited at 400°C, were half as transparent in the green as an indium tin oxide film having the same sheet resistance.


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