Challenges in atomic layer deposition of carbon-containing silicon-based dielectrics

2017 ◽  
Vol 35 (2) ◽  
pp. 021506 ◽  
Author(s):  
Rafaiel A. Ovanesyan ◽  
Dennis M. Hausmann ◽  
Sumit Agarwal
Author(s):  
John Roenn ◽  
Lasse Karvonen ◽  
Alexander Pyymäki-Perros ◽  
Nasser N. Peyghambarian ◽  
Harri Lipsanen ◽  
...  

Author(s):  
Le Zhang ◽  
Weixiao Hou ◽  
Tao Li ◽  
Jian He ◽  
Jiliang Mu ◽  
...  

Abstract Tuning of magnetic properties by electric field (E-field) has received extensive attention because it is compact, fast, and energy efficient. Here, multiferroic heterostructures of Fe3O4/Pt/PZN-PT (011) (lead zinc niobate-lead titanate single piezoelectric substrate) were in-situ fabricated by atomic layer deposition (ALD) using C10H10Fe and O2 as precursors at a low temperature (400oC) without a subsequent annealing process in H2 atmosphere, which is beneficial in combining with traditional silicon-based semiconductor technology. The E-field dependence of the magnetic anisotropy was studied systematically by ferromagnetic resonance spectroscopy with the larger tunable in-plane magnetic anisotropy of 152 Oe and 318 Oe obtained along the [100] and [0-11] axes, corresponding to the largest magnetoelectric coupling coefficient of 31.8 Oe.cm/kV. Also, the tunable out-of-plane magnetic anisotropy of 35 Oe was obtained along the [011] axis. The outstanding E-field tuning magnetism in the Fe3O4/Pt/PZN-PT heterostructures offers significant possibilities for novel multiferroic devices.


Nanomaterials ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 413 ◽  
Author(s):  
Yao Liu ◽  
Zhongtao Ouyang ◽  
Li Yang ◽  
Yang Yang ◽  
Jiaming Sun

Realization of a silicon-based light source is of significant importance for the future development of optoelectronics and telecommunications. Here, nanolaminate Al2O3/Tm2O3 films are fabricated on silicon utilizing atomic layer deposition, and intense blue electroluminescence (EL) from Tm3+ ions is achieved in the metal-oxide-semiconductor structured luminescent devices based on them. Precise control of the nanolaminates enables the study on the influence of the Tm dopant layers and the distance between every Tm2O3 layer on the EL performance. The 456 nm blue EL from Tm3+ ions shows a maximum power density of 0.15 mW/cm2. The EL intensities and decay lifetime decrease with excessive Tm dopant cycles due to the reduction of optically active Tm3+ ions. Cross-relaxation among adjacent Tm2O3 dopant layers reduces the blue EL intensity and the decay lifetime, which strongly depends on the Al2O3 sublayer thickness, with a critical value of ~3 nm. The EL is attributed to the impact excitation of the Tm3+ ions by hot electrons in Al2O3 matrix via Poole–Frenkel mechanism.


2011 ◽  
Vol 17 (1-3) ◽  
pp. 37-44 ◽  
Author(s):  
Steffen Strehle ◽  
Daniela Schmidt ◽  
Matthias Albert ◽  
Johann W. Bartha

2019 ◽  
Vol 37 (6) ◽  
pp. 060904 ◽  
Author(s):  
Rafaiel A. Ovanesyan ◽  
Ekaterina A. Filatova ◽  
Simon D. Elliott ◽  
Dennis M. Hausmann ◽  
David C. Smith ◽  
...  

2021 ◽  
Vol 3 (1) ◽  
pp. 59-71
Author(s):  
Degao Wang ◽  
Qing Huang ◽  
Weiqun Shi ◽  
Wei You ◽  
Thomas J. Meyer

2018 ◽  
Author(s):  
Peter George Gordon ◽  
Goran Bacic ◽  
Gregory P. Lopinski ◽  
Sean Thomas Barry

Al-doped ZnO (AZO) is a promising earth-abundant alternative to Sn-doped In<sub>2</sub>O<sub>3</sub> (ITO) as an n-type transparent conductor for electronic and photovoltaic devices; AZO is also more straightforward to deposit by atomic layer deposition (ALD). The workfunction of this material is particularly important for the design of optoelectronic devices. We have deposited AZO films with resistivities as low as 1.1 x 10<sup>-3</sup> Ωcm by ALD using the industry-standard precursors trimethylaluminum (TMA), diethylzinc (DEZ), and water at 200<sup>◦</sup>C. These films were transparent and their elemental compositions showed reasonable agreement with the pulse program ratios. The workfunction of these films was measured using a scanning Kelvin Probe (sKP) to investigate the role of aluminum concentration. In addition, the workfunction of AZO films prepared by two different ALD recipes were compared: a “surface” recipe wherein the TMA was pulsed at the top of each repeating AZO stack, and a interlamellar recipe where the TMA pulse was introduced halfway through the stack. As aluminum doping increases, the surface recipe produces films with a consistently higher workfunction as compared to the interlamellar recipe. The resistivity of the surface recipe films show a minimum at a 1:16 Al:Zn atomic ratio and using an interlamellar recipe, minimum resistivity was seen at 1:19. The film thicknesses were characterized by ellipsometry, chemical composition by EDX, and resistivity by four-point probe.<br>


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