Useful Trends for Predicting Corrosion Growth

2012 ◽  
Author(s):  
Shahani Kariyawasam ◽  
Hong Wang
Keyword(s):  
Growth Rates ◽  
Critical Size ◽  
Rate Variation ◽  
Growth Data ◽  
Limit States ◽  
Critical Limit ◽  
Inspection Interval ◽  
Integrity Management ◽  
External Corrosion ◽  
Insight Into

The objective of an effective corrosion management program is to identify and mitigate corrosion anomalies before they reach critical limit states. Often as there are many anomalies on pipelines an optimized program will mitigate the few corrosion anomalies that may grow to a critical size within the next inspection interval, without excavating many of the anomalies that will not grow to a critical size. This optimization of the inspection interval and the selection of anomalies to mitigate depend on understanding of corrosion growth. Prediction of corrosion growth is challenging because growth with time is non linear and highly location specific. These characteristics make simplistic approaches such as using maximum growth rates for all defects impractical. Therefore it is important to understand the salient aspects of corrosion growth so that appropriate decisions on excavation and re-inspection can be made without compromising safety or undertaking undue amounts of mitigative activities. In the pipeline industry corrosion growth between two in line inspections (ILIs) has been measured by comparing one ILI run to the next. However many types of ILI comparison methodologies have been used in the past. Within the last decade or two comparison techniques have evolved from box matching of defect samples to signal matching of the total defect populations. Multiple comparison analyses have been performed on the TransCanada system to establish corrosion growth rates. Comparison of the results from these various analyses gives insight into the accuracy and uncertainty of each type of estimate. In an effective integrity management process the best available corrosion growth data should be used. To do so it is important to understand the conservatism and the uncertainty involved in each type of estimate. When using a run-comparison to predict future growth it is assumed that the growth within the last ILI interval will continue (with associated uncertainty) during the next inspection interval. The validity of these assumptions is examined in this study. In the context of this paper these assumptions are validated for external corrosion on onshore pipelines. Characteristics of internal and offshore corrosion are very different in space and time variation. Correlations of external corrosion growth in onshore pipelines with defect size and location are also examined. Learning from multiple corrosion growth studies gives insight into the actual corrosion rate variation along a pipeline as well as general growth characteristics. Different types of corrosion growth modeling for use in probabilistic or deterministic integrity management programs are also discussed.

scholarly journals Ab Initio Study of Ferroelectric Critical Size of SnTe Low-Dimensional Nanostructures

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 732 ◽  
Author(s):  
Takahiro Shimada ◽  
Koichiro Minaguro ◽  
Tao Xu ◽  
Jie Wang ◽  
Takayuki Kitamura
Keyword(s):  
Density Functional ◽  
Critical Size ◽  
Density Functional Theory Calculations ◽  
Cell Width ◽  
Functional Theory ◽  
Unit Cells ◽  
Principle Density Functional Theory ◽  
Low Dimensional ◽  
Insight Into ◽  
Ferroelectric Perovskite

Beyond a ferroelectric critical thickness of several nanometers existed in conventional ferroelectric perovskite oxides, ferroelectricity in ultimately thin dimensions was recently discovered in SnTe monolayers. This discovery suggests the possibility that SnTe can sustain ferroelectricity during further low-dimensional miniaturization. Here, we investigate a ferroelectric critical size of low-dimensional SnTe nanostructures such as nanoribbons (1D) and nanoflakes (0D) using first-principle density-functional theory calculations. We demonstrate that the smallest (one-unit-cell width) SnTe nanoribbon can sustain ferroelectricity and there is no ferroelectric critical size in the SnTe nanoribbons. On the other hand, the SnTe nanoflakes form a vortex of polarization and lose their toroidal ferroelectricity below the surface area of 4 × 4 unit cells (about 25 Å on one side). We also reveal the atomic and electronic mechanism of the absence or presence of critical size in SnTe low-dimensional nanostructures. Our result provides an insight into intrinsic ferroelectric critical size for low-dimensional chalcogenide layered materials.

Systematic Approach to Measuring ILI Tool Performance

2014 ◽  
Author(s):  
Sean Keane ◽  
Karmun Cheng ◽  
Kaitlyn Korol
Keyword(s):  
Performance Measurement ◽  
Performance Measures ◽  
New Technologies ◽  
Efficient Reduction ◽  
Tool Performance ◽  
Typical Performance ◽  
Substantial Investment ◽  
Integrity Management ◽  
Insight Into

In-line inspection (ILI) tools play an important role within integrity management and substantial investment is made to continuously advance performance of the existing technologies and, where necessary, to develop new technologies. Performance measurement is typically focused for the purpose of understanding the measured performance in relation to the ILI vendor specification and for the determination of residual uncertainty regarding pipeline integrity. These performance measures may not provide the necessary insight into what type of investment into a technology is necessary to further reduce residual uncertainty regarding pipeline integrity, and beyond that, what investment, as an operator, results in an effective and efficient reduction in uncertainty. The paper proposes a reliability based approach for investigating uncertainty associated with ultrasonic crack ILI technology for the purpose of identifying efficient investment into the technology that results in an effective and measurable improvement. Typical performance measures and novel performance measurement methods are presented and reviewed with respect to what information they can provide to assist in investment decisions. Finally, general observations are made regarding Enbridge’s experience using ultrasonic crack ILI technology and areas currently being investigated.

Taking Stock of Genetic Concepts in Fisheries Management

1991 ◽  
Vol 48 (4) ◽  
pp. 722-731 ◽  
Author(s):  
R. W. Gauldie
Keyword(s):  
Fisheries Management ◽  
Growth Rates ◽  
Allele Frequencies ◽  
Frequency Variation ◽  
Sustainable Yield ◽  
Fish Stocks ◽  
Meristic Count ◽  
Intuitive Idea ◽  
Selection Mechanisms ◽  
Insight Into

The historical development of the idea of isolated stocks of fish that can be managed as separate management units has been as strongly tied to the intuitive idea of separate races as it has been to the practical necessities of jurisprudence and the estimation of both biomass and sustainable yield by fisheries managers. Demonstrating the existence of isolated fish stocks and delineating their boundaries has generally proved unsuccessful. Various techniques ranging from meristic count differences to polymorphic allelism have usually failed. However, in the pursuit of isolated stocks, biochemists have uncovered a great deal of information about the variation of polymorphic allele frequencies over time and space. Following the shift in opinion away from stochastic to natural selection mechanisms in allele frequency variation, it is evident that the observed variation in allele frequencies allows more insight into the biology of fishes than into the breeding structure of populations. These insights argue against the idea of isolated stocks of fish with homogeneous growth rates that are the basis of the sustainable yield models in favour of migration-linked stocks with heterogeneous growth rates.

scholarly journals Integrity Management of Marine Structures; With Emphasis on Design for Structural Robustness

2018 ◽  
Author(s):  
Torgeir Moan
Keyword(s):  
Structural Damage ◽  
Structural Integrity ◽  
Oil And Gas ◽  
Offshore Structures ◽  
Design Standards ◽  
Limit States ◽  
Fabrication Errors ◽  
Integrity Management ◽  
Operational Errors ◽  
And Control

Based on relevant accident experiences with oil and gas platforms, a brief overview of structural integrity management of offshore structures is given; including an account of adequate design criteria, inspection, repair and maintenance as well as quality assurance and control of the engineering processes. The focus is on developing research based design standards for Accidental Collapse Limit States to ensure robustness or damage tolerance in view damage caused by accidental loads due to operational errors and to some extent abnormal structural damage due to fabrication errors. Moreover, it is suggested to provide robustness in cases where the structural performance is sensitive to uncertain parameters. The use of risk assessment to aid decisions in lieu of uncertainties affecting the performance of novel and existing offshore structures, is briefly addressed.

Does Economic Growth Pay Political Dividends in India?

2019 ◽  
Vol 67 (1-2) ◽  
pp. 166-169
Author(s):  
Vasant V. Bang ◽  
Alok Kumar Mishra
Keyword(s):  
Economic Growth ◽  
Growth Rates ◽  
Regression Equations ◽  
Economic Policies ◽  
Growth Data ◽  
Parliamentary Elections ◽  
Independent Variables ◽  
Economic Development And Growth ◽  
Bharatiya Janata Party ◽  
Ruling Party

Since independence in 1947, India has witnessed several changes in economic policies of governments. Economic reforms were started in India in 1984 and were accelerated later in 1991. It is believed that Bharatiya Janata Party won the 2014 parliamentary elections on the promise of economic development and growth. In this article, an attempt has been made to investigate the link between economic and electoral performances in Indian elections. The data for 1951–2014 period has been analysed by establishing regression equations using vote percentage received by a ruling party as dependent variable and sectoral economic growth during the ruling tenure as independent variables. Comparisons have been made between the pre- and post-1984 eras. An important contribution of this article is that it highlights the fact that electoral performances can be better explained using sectoral growth data as compared to overall GDP growth rates. The article also highlights a significant role played by volatility in growth rates.

Dynamic Predictive Model for Growth of Bacillus cereus from Spores in Cooked Beans

2017 ◽  
Vol 81 (2) ◽  
pp. 308-315 ◽  
Author(s):  
Vijay K. Juneja ◽  
Abhinav Mishra ◽  
Abani K. Pradhan
Keyword(s):  
Bacillus Cereus ◽  
Growth Rates ◽  
Linear Models ◽  
Growth Models ◽  
Maximum Growth ◽  
Effect Of Temperature ◽  
Coefficient Of Determination ◽  
Growth Data ◽  
Three Phase ◽  
Primary Model

ABSTRACT Kinetic growth data for Bacillus cereus grown from spores were collected in cooked beans under several isothermal conditions (10 to 49°C). Samples were inoculated with approximately 2 log CFU/g heat-shocked (80°C for 10 min) spores and stored at isothermal temperatures. B. cereus populations were determined at appropriate intervals by plating on mannitol–egg yolk–polymyxin agar and incubating at 30°C for 24 h. Data were fitted into Baranyi, Huang, modified Gompertz, and three-phase linear primary growth models. All four models were fitted to the experimental growth data collected at 13 to 46°C. Performances of these models were evaluated based on accuracy and bias factors, the coefficient of determination (R2), and the root mean square error. Based on these criteria, the Baranyi model best described the growth data, followed by the Huang, modified Gompertz, and three-phase linear models. The maximum growth rates of each primary model were fitted as a function of temperature using the modified Ratkowsky model. The high R2 values (0.95 to 0.98) indicate that the modified Ratkowsky model can be used to describe the effect of temperature on the growth rates for all four primary models. The acceptable prediction zone (APZ) approach also was used for validation of the model with observed data collected during single and two-step dynamic cooling temperature protocols. When the predictions using the Baranyi model were compared with the observed data using the APZ analysis, all 24 observations for the exponential single rate cooling were within the APZ, which was set between −0.5 and 1 log CFU/g; 26 of 28 predictions for the two-step cooling profiles also were within the APZ limits. The developed dynamic model can be used to predict potential B. cereus growth from spores in beans under various temperature conditions or during extended chilling of cooked beans.

SCC Management and Integrity Planning in a Gas Pipeline

2006 ◽  
Author(s):  
David Katz ◽  
Sergio Limon ◽  
Ming Gao ◽  
Rick McNealy ◽  
Ravi Krishnamurthy ◽  
...  
Keyword(s):  
Stress Corrosion ◽  
Crack Growth ◽  
Growth Rates ◽  
Crack Detection ◽  
Management Strategies ◽  
Field Measurements ◽  
Gas Pipeline ◽  
Oil Pipeline ◽  
Integrity Management ◽  
Crack Growth Rates

Stress Corrosion Cracking (SCC) is a major integrity management concern for many gas and oil pipeline operators. Predictive models for Stress Corrosion Crack growth were developed using laboratory test data from the mid 1970’s, and limited inspection data and excavation measurements from the early 1990’s. Extensive efforts continue to be made to develop strategies for a better management of the SCC problem. In this paper, a study of crack growth rates was conducted on the Williams 16-inch gas pipeline using data from two consecutive in-line crack detection tool runs and direct field measurements. Findings from this study provide a direct measurement of crack growth rates for ILI crack features with depths ranging from 12.5%wt to 40%wt. Future integrity of the pipeline was assessed. The integrity management strategies could be further refined using the calculated crack growth rate, field excavation data and fracture mechanics based API 579 FAD approach.

An External Corrosion Direct Assessment Module for a Pipeline Integrity Management System

2006 ◽  
Author(s):  
Menno T. van Os ◽  
Piet van Mastrigt ◽  
Andrew Francis
Keyword(s):  
Management System ◽  
Structural Reliability ◽  
Individual Performance ◽  
Corrosion Activity ◽  
Time Saving ◽  
Survey Techniques ◽  
Direct Assessment ◽  
Integrity Management ◽  
External Corrosion ◽  
The Individual

A significant part of the high pressure gas transport system of Gasunie cannot be examined by in-line inspection techniques. To ensure safe operation of these pipelines, an External Corrosion Direct Assessment (ECDA) module for PIMSLIDER (a pipeline integrity management system) is currently under development. The functional specifications of this module are based on NACE RP0502-2002, a recommended practice for ECDA. In addition to this, a new probabilistic methodology has been adopted, to take account for uncertainties associated with ECDA and to quantify the contributions from aboveground surveys and excavations to the integrity of a pipeline. This methodology, which is based on Structural Reliability Analysis (SRA) and Bayesian updating techniques, is presented in more detail in paper IPC2006-10092 of this conference. The DA module of PIMSLIDER enables computerized storage, retrieval and processing of all appropriate pipeline data and therefore guarantees highly accurate, reproducible and time saving integrity analyses of the Gasunie grid. Another important function of this system is the ability to use the complete database of all pipelines to pre-assess the integrity of a particular pipeline. This automated retrieval of data from pipelines with similar characteristics and/or environmental conditions results in a substantial increase of accessible data and enables Gasunie to improve the reliability of applied statistics throughout the process. As a consequence, the overall cost of inspections and excavations can be greatly reduced. In the Pre-Assessment phase, the DA module assists the integrity manager in gathering and analyzing data necessary to determine the current condition of a pipeline. After collection and visualization of the available data, the user can identify suitable ECDA regions. Furthermore, the gathered data are used to construct prior distributions of parameters relevant to the SRA model, such as the number and size of corrosion defects and pipeline-related parameters. In the Indirect Inspections step, the DA module allows the user to store and analyze the data from aboveground surveys, in order to identify and define the severity of coating faults and areas at which corrosion activity may occur. The probabilistic methodology accounts for the individual performance of each applied survey technique in terms of missed defects and false indications, in general a major source of uncertainty in ECDA. In the Direct Examinations phase, excavations are carried out to collect data to assess possible corrosion activity. Subsequently, the ECDA module uses this information to update, among other things, the parameters concerning the performance of survey techniques, the number of defects and the corrosion rate. As a result, updated failure frequencies are calculated for each ECDA-region (after each excavation if required), which are then used by the DA module to advise the integrity manager if additional mitigating activities are necessary, or by defining a reassessment interval.

Using Ultrasound to Gauge Pipeline Internal Corrosion With Coating for ICDA

2006 ◽  
Author(s):  
Qingshan Feng ◽  
Zupei Yang
Keyword(s):  
Test Time ◽  
Thickness Gauge ◽  
Internal Corrosion ◽  
Direct Assessment ◽  
Metal Thickness ◽  
Integrity Management ◽  
External Corrosion ◽  
Key Steps ◽  
Thickness Measurements ◽  
Non Destructive

Internal corrosion direct assessment (ICDA) for pipeline enhances the abilities to assess internal corrosion in pipeline and is based on the principle that corrosion is most likely where water first accumulates. ICDA employs the same four-step process as all other direct assessment methods. The important step is direct examinations: the pipeline is excavated and examined at locations prioritized to have the highest likelihood of corrosion. A variety of inservice non-destructive examination processes are available to pipeline operators to inspect for internal corrosion. Manual assessment of internal corrosion is considered more challenging than normal external corrosion assessments since the corrosion feature is not visible and must be interpreted by the ultrasonic response, but in the past ultrasonic test need always remove the coating and then measure on the surface of bare pipe, which brings the measurement point of the pipe body more risk because of weaker quality of patch coating. Recently, advances in the design of ultrasonic corrosion thickness gauges utilizing dual element transducers have made it possible to take accurate metal thickness measurements while coatings need not to be removed. This feature is often referred to as echo-to-echo thickness measurements. Using the ultrasound thickness gauge to measure pipeline internal corrosion while external coatings need not to be removed can keep the integrity of coating, make pipeline operating and monitoring more economical and improve inspection activities to estimate corrosion in pipelines for ICDA. Gauge equipment requirement, Measurement procedures and Accuracy were validated in laboratory. How to arrange the gauge locations, interval test time and data treatment and analysis also are the key steps of ICDA for integrity management.

Effect of Salt Water Temperature on the Crack Growth Characteristics of 12 Chrome Steel

1974 ◽  
Vol 96 (2) ◽  
pp. 81-87 ◽  
Author(s):  
R. Eisenstadt ◽  
K. M. Rajan
Keyword(s):  
Stress Intensity ◽  
Crack Growth ◽  
Corrosion Fatigue ◽  
Growth Rates ◽  
Salt Water ◽  
Water Solution ◽  
Correction Term ◽  
Growth Data ◽  
Rotating Beam ◽  
Crack Growth Rates

The corrosion fatigue crack growth rates on 12 chrome steels of typical composition, 12Cr, 0.2C, 1Mo, 1W, of 150,000-ksi yield is relatively unaffected by 4.5 percent NaCl salt water solution at room temperature. There is a significant rise in the crack growth rates of 12 chrome steels with increasing temperature for salt water corrosion fatigue of about 4 to 1 for 160 deg F—4.5 percent solution. In correlating rotating beam understressing data on average crack growth rate versus stress intensity factor with 0-maximum data generated by other techniques, the value 1−R Kmax equivalent to n = 0.5 in the expression Keff = Kmax (1 − R)n correlates the rotating beam data adequately with the 0-Max data for other techniques. A correction factor for eccentric crack fronts on solid round specimens for rotating beam crack growth data to calculate stress intensity factors for solid notched round bars has been developed. The correction term is 4rd2 for the following stress intensity expression. K1=2.257Mr3+4rd20.80t+7.12r−1/2

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