Low Application Temperature Graded Structure Polyolefin Coating System Based on a Next Generation FBE for Strain-Based Design Pipelines Using High Strength Steel

Author(s):  
Stephen J. Edmondson ◽  
Dennis T. Wong ◽  
Robert E. Steele

Pipelines combining strain-based design with the use of thin walled, high strength steel (X80 or higher) present a significant challenge in terms of the availability of suitable coating systems. FBE-based coatings typically require the pipe to be heated to temperatures in the range of 230°C to 250°C for a period of up to 10 minutes in order to achieve optimum properties. The problem is that some of the key properties of such steels can change when they are subjected to such a heat cycle, resulting in a reduction in the tensile elongation at yield, a key requirement with strain-based design pipelines. When such pipelines are being constructed in remote areas, such as Northern Canada, there is the additional requirement that the coating must be robust enough to withstand transportation, handling and construction damage, and be bendable to temperatures as low as −50°C. Graded Structure Polyolefin Systems (GSPO) such as Bredero Shaw’s High Performance Composite Coating (HPCC) have established an excellent track record on pipelines constructed in very cold conditions through very rough terrain. However, such coatings are historically based on conventional fusion-bonded epoxy coatings designed for optimum performance when applied to pipes heated to 230 to 250°C. This paper describes a new version GSPO coating which can be produced without having the pipe temperature exceed 200°C at any point in the process, and which provides performance virtually identical to that of the standard GSPO product. It is the result of a cooperative development between Bredero Shaw and DuPont Powder Coatings, and is based on a new generation of FBE which can be processed at temperatures as low as 175°C with very little sacrifice in resistance to adhesion, as characterized by hot cathodic disbondment. Because the FBE has primary responsibility for providing corrosion resistance, the performance of the new generation FBE applied at low application temperatures was first compared to that of well-established FBE applied at their recommended application temperatures. Cathodic Disbondment (CD) was selected as the key performance test for adhesion because it simulates field conditions for disbonding of a coating from a pipeline with impressed current cathodic protection. Because the measurement of disbondment is on a continuous numerical scale, statistical analysis is possible. The new generation FBE coating performs significantly better in CD testing than conventional FBE when applied at lower application temperatures. Its performance is comparable to the best conventional FBE when applied at 240°C. This performance is maintained in the Low Application Temperature GSPO coating.

2013 ◽  
Vol 756-759 ◽  
pp. 161-165
Author(s):  
Qi Yin Shi ◽  
Chao Liu ◽  
Li Lin Cao ◽  
Zhen Wang

On the basis of the theoretical study and application of ordinary steel-encased concrete composite beam, this paper will focus on a new high-strength steel-encased concrete composite beam, and mainly studies high-performance steel Q420 and Q460, as well as high-strength concrete C60 and C80. Besides, an experimental study of 5 simply-supported beams is made, and the load-deflection curves of new SCCB are analyzed. The calculation formula of load which changes with depth of section and bending strength of the cross section is also analyzed. It is suggested that the calculated results announced should be identical with the experimental results.


2020 ◽  
Vol 6 (46) ◽  
pp. eaba9543 ◽  
Author(s):  
Zhangwei Wang ◽  
Wenjun Lu ◽  
Huan Zhao ◽  
Christian H. Liebscher ◽  
Junyang He ◽  
...  

High-performance lightweight materials are urgently needed, given the pressing quest for weight reduction and the associated energy savings and emission reduction. Here, by incorporating the multi–principal element feature of compositionally complex alloys, we develop the concept of lightweight steels further and propose a new class of compositionally complex steels (CCSs). This approach allows us to use the high solid solution strengthening and shift the alloys’ compositions into previously unattainable phase regions where both nanosized shearable κ-carbides and non-shearable B2 particles are simultaneously formed. The achievement of dual-nanoprecipitation in our CCSs leads to materials with ultrahigh specific tensile strength (up to 260 MPa·cm3 g−1) and excellent tensile elongation (13 to 38%), a combination outperforming all other high-strength high-entropy alloys and advanced lightweight steels. Our concept of CCSs is thus useful for guiding the design of ultrastrong lightweight metallic materials.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sahar A. Mostafa ◽  
Mohamed M. EL-Deeb ◽  
Ahmed A. Farghali ◽  
A. Serag Faried

AbstractCorrosion resistance of high strength steel (HHS) embedded in ultra-high performance concrete (UHPC) immersed in 3.5% NaCl solution is evaluated in the absence and presence of nano silica (NS), nano glass waste (NGW), nano rice husk ash (NRHA) and nano metakaolin (NMK) using open circuit potential, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) under normal and accelerated conditions. Data showed that the corrosion rate in the accelerated conditions is higher compared by the normal conditions due to the increasing in the rate of both anodic and cathodic reactions in the presence of anodic current. On the other hand, the presence of the studied nano materials decreases both the anodic and cathodic overpotentials, and shifts both the open circuit potential (Eocp) and corrosion potential (Ecorr) of HSS to more noble values, as well as decreases the values of the corrosion current densities (Icorr) in both normal and accelerated conditions. Furthermore, EIS analysis illustrates that the presence of these materials enhances both the concrete bulk resistance and the charge transfer resistance at HSS/UHPC interface, which retards the flow of the electrons between the anodic and cathodic sites, thus impeding the propagation of the corrosion process. The inhibitory effect of the studied nano materials for the corrosion of HSS is interpreted on the basis of the change in the microstructure and the compressive strength of the UHPC.


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