Inhibitor Selection for Internal Corrosion Control of Pipelines

Author(s):  
S. Papavinasam ◽  
R. W. Revie

Addition of inhibitors can provide a cost-effective method for controlling internal corrosion of pipelines. To select appropriate inhibitors and their concentrations, several laboratory experiments are usually performed. Test methodologies to evaluate inhibitors for a particular field should be carried out to simulate the conditions in the pipeline. Because several interacting parameters influence corrosion, and hence inhibitor performance, simulation of field operating conditions in the laboratory is often difficult. In this paper, user-friendly software to optimize the laboratory experimental conditions to simulate field operating conditions is discussed. The merits of the program in selecting commercial inhibitors and in designing cost-effective inhibitors for future application are described.

Author(s):  
Dave McColl ◽  
Adam Whiting

Pipeline infrastructure is the backbone of the energy industry and remains the safest and most cost effective method for transporting oil and gas. For decades corrosion has presented a significant challenge to pipeline operators. According to Alberta Energy Regulator data, internal corrosion is considered to be the root cause for more than 54% of all documented pipeline failures in Alberta [1]. Spoolable composite pipeline technologies have become a mainstream corrosion solution over the last 10 years, however these products are limited to smaller pipelines, typically less than 6 inches in diameter. Traditional slip-lining (field installed plastic lined steel pipe) is used for internal corrosion protection of larger pipelines, however it is costly, requiring labour intensive field construction, often completed in inhospitable environmental conditions. As a result project delays and cost over-runs are commonplace. Recognizing the need for a cost effective pipeline corrosion solution for larger gathering pipelines, an innovative technology was developed that combines a unique mechanical pipe joining system with an integrated electro-fusion coupler. The new joining system enables insertion of an HDPE liner in a factory environment where costs and quality can be tightly controlled. The new joining system eliminates conventional welding of the pipeline in the field and instead uses a custom field press to quickly energize the mechanical pipe joint. Field scope is significantly reduced, construction completed in less time, and associated costs greatly reduced. This paper discusses the testing completed to qualify the new joining system for use in oilfield gathering pipelines. The qualification test plan includes all requirements identified in applicable regulatory standards (primarily CSA Z662-11), and prudent engineering requirements based on anticipated field handling and anticipated operating conditions. The test regime was ultimately designed to ensure the suitability of the pipeline system for intended service. Testing included hydrostatic burst, static gas pressure, bend, cyclic pressure and thermal, vacuum, tensile, and compressive tests on the joint. The test results show that in all cases the jointing system successfully met the established design performance criteria and in most cases exceeded the actual mechanical properties of the parent pipe, thus proving the joining system ready for field installations.


The choice of cost-effective method of anticorrosive protection of steel structures is an urgent and time consuming task, considering the significant number of protection ways, differing from each other in the complex of technological, physical, chemical and economic characteristics. To reduce the complexity of solving this problem, the author proposes a computational tool that can be considered as a subsystem of computer-aided design and used at the stage of variant and detailed design of steel structures. As a criterion of the effectiveness of the anti-corrosion protection method, the cost of the protective coating during the service life is accepted. The analysis of existing methods of steel protection against corrosion is performed, the possibility of their use for the protection of the most common steel structures is established, as well as the estimated period of effective operation of the coating. The developed computational tool makes it possible to choose the best method of protection of steel structures against corrosion, taking into account the operating conditions of the protected structure and the possibility of using a protective coating.


Author(s):  
Ferhat Alkan ◽  
Joana Silva ◽  
Eric Pintó Barberà ◽  
William J Faller

Abstract Motivation Ribosome Profiling (Ribo-seq) has revolutionized the study of RNA translation by providing information on ribosome positions across all translated RNAs with nucleotide-resolution. Yet several technical limitations restrict the sequencing depth of such experiments, the most common of which is the overabundance of rRNA fragments. Various strategies can be employed to tackle this issue, including the use of commercial rRNA depletion kits. However, as they are designed for more standardized RNAseq experiments, they may perform suboptimally in Ribo-seq. In order to overcome this, it is possible to use custom biotinylated oligos complementary to the most abundant rRNA fragments, however currently no computational framework exists to aid the design of optimal oligos. Results Here, we first show that a major confounding issue is that the rRNA fragments generated via Ribo-seq vary significantly with differing experimental conditions, suggesting that a “one-size-fits-all” approach may be inefficient. Therefore we developed Ribo-ODDR, an oligo design pipeline integrated with a user-friendly interface that assists in oligo selection for efficient experiment-specific rRNA depletion. Ribo-ODDR uses preliminary data to identify the most abundant rRNA fragments, and calculates the rRNA depletion efficiency of potential oligos. We experimentally show that Ribo-ODDR designed oligos outperform commercially available kits and lead to a significant increase in rRNA depletion in Ribo-seq. Availability Ribo-ODDR is freely accessible at https://github.com/fallerlab/Ribo-ODDR Supplementary information Supplementary data are available at Bioinformatics online.


Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 625 ◽  
Author(s):  
Martin Luther Yeboah ◽  
Xinyuan Li ◽  
Shixue Zhou

In this investigation, an easily-operated and cost-effective method is utilized to synthesize biochar in ambient air, and the prepared biochar is used in a novel manner as a milling aid for fabricating Mg-biochar composites for hydrogen storage. X-ray diffractometry reveals that increasing the content of palm kernel shell biochar (PKSBC) from 5 wt.% to 20 wt.% enhances the hydrogen absorption performance by increasing the conversion of Mg into MgH2 from 83% to 93%. A 40 °C reduction in decomposition temperature of MgH2 is recorded from differential scanning calorimetry curves when the content of PKSBC is increased to 20 wt.%. Magnesium is milled and hydrided under the same experimental conditions and used as a reference material. It is proposed that these property enhancements can be attributed to the fact that PKSBC acts as an anti-sticking agent for elemental Mg powders, helping in the achievement of a more dispersed composite with reduced Mg particle size due to its layered-like carbon structure.


Author(s):  
Charles W. White ◽  
Nathan T. Weiland

Direct supercritical carbon dioxide (sCO2) power cycles are an efficient and potentially cost-effective method of capturing CO2 from fossil-fueled power plants. These cycles combust natural gas or syngas with oxygen in a high pressure (200–300 bar), heavily diluted sCO2 environment. The cycle thermal efficiency is significantly impacted by the proximity of the operating conditions to the CO2 critical point (31 °C, 73.7 bar) as well as to the level of working fluid dilution by minor components, thus it is crucial to correctly model the appropriate thermophysical properties of these sCO2 mixtures. These properties are also important for determining how water is removed from the cycle and for accurate modeling of the heat exchange within the recuperator. This paper presents a quantitative evaluation of ten different property methods that can be used for modeling direct sCO2 cycles in Aspen Plus®. Reference fluid thermodynamic and transport properties (REFPROP) is used as the de facto standard for analyzing high-purity indirect sCO2 systems, however, the addition of impurities due to the open nature of the direct sCO2 cycle introduces uncertainty to the REFPROP predictions as well as species that REFPROP cannot model. Consequently, a series of comparative analyses were performed to identify the best physical property method for use in Aspen Plus® for direct-fired sCO2 cycles. These property methods are assessed against several mixture property measurements and offer a relative comparison to the accuracy obtained with REFPROP. The Lee–Kessler–Plocker equation of state (EOS) is recommended if REFPROP cannot be used.


Author(s):  
Erick B. Cushman ◽  
Bob Gwin ◽  
Reed Shipman

An operationally critical, manned control station’s design was challenged to meet stringent airborne noise requirements. Through an innovative, interdisciplinary engineering approach, a solution was implemented, resulting in the first production unit meeting airborne noise requirements. The manned control station was initially designed with nine tubeaxial fans continuously operating at maximum rated speed to provide sufficient cooling to internal components at the station’s worst-case maximum ambient operating temperature of 122°F. Initial testing of a prototype unit showed airborne noise requirements were exceeded by as much as 22 dB (re 20 micro-Pascals). Fan speed reduction and installation of temporary internal acoustic absorption material were tested to measure effectiveness, but were not sufficient to meet airborne noise requirements. The normal operating condition of the control station was reviewed and detailed modeling and testing of the station’s actual cooling requirements under various operating scenarios was conducted. During this process, it was recognized that under normal operating conditions, the worst-case ambient operating temperatures were improbable and that a balancing of cooling requirements and acoustic requirements was possible. A new cost-effective method of fan control in conjuction with the installation of permanent internal absorption material and a redesign of ventilation ducting was implemented. In normal ambient temperature conditions, six of the nine internal fans operate at minimum rated speed. If ambient temperatures rise above normal (the control station’s airborne noise requirments only apply at normal “non-casualty” ambient temperatures), three additional exhaust fans automatically turn on at minimum rated speed to minimize additional airborne noise contributions. If ambient temperatures continue to rise, all nine fans are automatically switched on at maximum rated speed to protect the internal components of the operationally critical control station. Acoustic performance evaluations predicted these improvements would result in meeting the stringent airborne noise requirements. These predictions were validated during testing of the first production unit, which passed all airborne noise requirements.


Author(s):  
Luis I. Di´ez ◽  
Cristo´bal Corte´s ◽  
Mariano Berdusa´n ◽  
Eduardo Ferrer

Co-firing of coal and biomass in existing coal-fired power stations is a cost-effective method to reduce CO2 emissions in energy generation. Nevertheless, the introduction of biomass has to be carefully considered since it could significantly modify combustion and heat transfer phenomena and enhance fouling and corrosion inside the boiler. This paper investigates the effect of substituting a fraction of coal by biomass on the heat transfer and ash deposition rates, by performing pilot tests under different operating conditions in a pulverized fuel combustion rig. Fouling rates have been characterized by means of air-cooled deposition probes installed at one tube bank, reproducing the performance of a large-scale superheater. Heat transfer has been simulated coupling thermal radiation models with semi-empirical approaches for the tube bank behaviour. Ash samples compiled from the wind- and the lee-side of the probe has been collected and analysed by SEM (Scanning Electron Microscopy). Low-to-moderate fouling rates have been typically observed for the tested coal and coal + biomass blends, but with somewhat potassium enrichment at the lee-side deposits when biomass is introduced. As a matter of fact, sootblowing manoeuvres in utility boilers should not be affected when co-firing the tested fuels. Furthermore, chlorine-induced corrosion on heat transfer surfaces is not expected to be significant since the concentration of chlorine in the sampled deposits has been always found to be negligible.


2019 ◽  
Vol 5 (5) ◽  
pp. eaav2249 ◽  
Author(s):  
Dongju Shin ◽  
Wookjae Lee ◽  
Ji Hyun Lee ◽  
Duhee Bang

The development of high-throughput single-cell RNA sequencing (scRNA-seq) has enabled access to information about gene expression in individual cells and insights into new biological areas. Although the interest in scRNA-seq has rapidly grown in recent years, the existing methods are plagued by many challenges when performing scRNA-seq on multiple samples. To simultaneously analyze multiple samples with scRNA-seq, we developed a universal sample barcoding method through transient transfection with short barcode oligonucleotides. By conducting a species-mixing experiment, we have validated the accuracy of our method and confirmed the ability to identify multiplets and negatives. Samples from a 48-plex drug treatment experiment were pooled and analyzed by a single run of Drop-Seq. This revealed unique transcriptome responses for each drug and target-specific gene expression signatures at the single-cell level. Our cost-effective method is widely applicable for the single-cell profiling of multiple experimental conditions, enabling the widespread adoption of scRNA-seq for various applications.


2018 ◽  
Author(s):  
Dongju Shin ◽  
Wookjae Lee ◽  
Ji Hyun Lee ◽  
Duhee Bang

AbstractTo simultaneously analyze multiple samples of various conditions with scRNA-seq, we developed a universal sample barcoding method through transient transfection of SBOs. A 48-plex drug treatment experiment of pooled samples analyzed by a single run of Drop-Seq revealed a unique transcriptome response for each drug and target-specific gene expression signatures at the single-cell level. Our cost-effective method is widely applicable for single-cell profiling of multiple experimental conditions.


2021 ◽  
Author(s):  
Sanders Sebastian

Abstract Background: It has always been a challenge to increase the concentration of malaria parasites in blood without compromising on specificity. The conventional thick smear method is a good sensitive tool. But the disadvantage is that a lot of expertise and experience is needed to perform this. A pilot study was undertaken to improvise the quantitative buffy coat (QBC) method so that the advantages of both thick and thin smears could be combined. Methods: Used QBC capillary tubes were washed off the blood and the dye and thoroughly cleaned and dried. The floats were preserved. Blood samples of ten malaria positive patients collected already in EDTA bottles were drawn onto the washed and dried QBC capillaries. The float was re-inserted and centrifugation done as recommended by the QBC manufacturers. The capillary tubes were broken with the aid of a diamond pencil at the area were parasites infested cells were most likely to be seen ie just below the buffy coat area. Smears were made onto a slide with this material and stained using the conventional Romanowsky method of staining. Ordinary microscopy was carried out and parasitaemia were quantified as number per oil immersion field and the results were compared with the recorded thin film reports. Five known negative controls were treated similarly. Results: Parasites’ number was found to be on an average ten times higher per oil immersion field compared to the conventional methods. Negative controls yielded valid outcomes. Conclusion: This preliminary study promises to be a useful tool in screening for malaria in endemic areas where resources are limited. It also adds to the specificity compared with the original QBC method. Larger study involving more samples is required to further validate the results. Any easy method (preferably automated) to cut the capillary tube thereby eliminating the risk of infection to the operator would help a long way in making the method more user friendly.


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