Synthesizing Magnetic Nanocomposite Fibers by Electrospinning Method

2008 ◽  
Author(s):  
R. Asmatulu ◽  
W. Khan ◽  
K. D. Nguyen ◽  
M. B. Yildirim
Keyword(s):  
Magnetic Nanoparticles ◽  
Ammonium Hydroxide ◽  
Magnetic Nanocomposite ◽  
Ferrous Chloride ◽  
Inorganic Particles ◽  
Electrospinning Method ◽  
Nanocomposite Fibers ◽  
Co Precipitation ◽  
Chloride Salts ◽  
Poly Acrylonitrile

Flexible magnetic nanocomposite fibers were produced by electrospinning method using a polymeric solution containing poly(acrylonitrile) and magnetite nanoparticles. Magnetic nanoparticles (∼10 nm) were prepared by a chemical co-precipitation of ferric and ferrous chloride salts in the presence of an ammonium hydroxide solution. The effect of magnetic particle concentrations (e.g., 0%, 1%, 5%, 10%, 20% and 30%) on nanocomposite fibers, distribution and morphology were studied using scanning electron microscopy (SEM). The experimental study indicated that the average diameters of the magnetic nanocomposite fibers were between 400 nm and 1.08 μm. The magnetic responds were also found to increase linearly with increasing percent loading of the magnetic nanoparticles. It is concluded that this study provides promising results for various applications, such as filtration and separation of micron and nanosize organic and inorganic particles, HF antenna fabrication and biomedical.

Fabrication of Magnetic Nanocomposite Spheres for Targeted Drug Delivery

2008 ◽  
Author(s):  
R. Asmatulu ◽  
A. Fakhari ◽  
H. L. Wamocha ◽  
H. H. Hamdeh ◽  
J. C. Ho
Keyword(s):  
Electron Microscopy ◽  
Drug Delivery ◽  
Targeted Drug Delivery ◽  
Ammonium Hydroxide ◽  
Magnetic Nanocomposite ◽  
Basic Solution ◽  
Ferrous Chloride ◽  
Oil Emulsion ◽  
Targeted Drug ◽  
Co Precipitation

Biodegradable magnetic nanocomposite spheres were synthesized using magnetite nanoparticles and poly (D,L-lactide-co-glycolide) (PLGA) for the purpose of magnetic targeted drug delivery. Magnetic nanoparticles (∼10 nm) were prepared by a chemical co-precipitation of ferric and ferrous chloride salts in the presence of a strong basic solution (ammonium hydroxide). An oil-in-oil emulsion/solvent evaporation technique was conducted at 7000 rpm and 1.5–2 hrs agitation for the synthesis of nanocomposite spheres. Prior to the experiment, PLGA was dissolved in acetonitrile (phase I), and then added drop-wise into the viscous paraffin oil combined with Span 80 (phase II). The effect of magnetic particle concentrations (0%, 5%, 10%, 20% and 30%) on nanocomposite particles, the particle distribution and morphology were investigated using dynamic laser light scattering (DLLS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The test results proved that the magnetic nanocomposite spheres were in the range of 200 nm to 1.03 μm.

scholarly journals Drug-Carrying Magnetic Nanocomposite Particles for Potential Drug Delivery Systems

2009 ◽  
Vol 2009 ◽  
pp. 1-6 ◽  
Author(s):  
R. Asmatulu ◽  
A. Fakhari ◽  
H. L. Wamocha ◽  
H. Y. Chu ◽  
Y. Y. Chen ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Drug Delivery ◽  
Magnetic Nanoparticles ◽  
Quantum Interference ◽  
Ammonium Hydroxide ◽  
Magnetic Nanocomposite ◽  
Blocking Temperature ◽  
Basic Solution ◽  
Ferrous Chloride ◽  
Oil Emulsion

Drug-carrying magnetic nanocomposite spheres were synthesized using magnetite nanoparticles and poly (D,L-lactide-co-glycolide) (PLGA) for the purpose of magnetic targeted drug delivery. Magnetic nanoparticles (∼13 nm on average) of magnetite were prepared by a chemical coprecipitation of ferric and ferrous chloride salts in the presence of a strong basic solution (ammonium hydroxide). An oil-in-oil emulsion/solvent evaporation technique was conducted at 7000 rpm and 1.5–2 hours agitation for the synthesis of nanocomposite spheres. Specifically, PLGA and drug were first dissolved in acetonitrile (oily phase I) and combined with magnetic nanoparticles, then added dropwise into viscous paraffin oil combined with Span 80 (oily phase II). With different contents (0%, 10%, 20%, and 25%) of magnetite, the nanocomposite spheres were evaluated in terms of particle size, morphology, and magnetic properties by using dynamic laser light scattering (DLLS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and a superconducting quantum interference device (SQUID). The results indicate that nanocomposite spheres (200 nm to 1.1 μm in diameter) are superparamagnetic above the blocking temperature near 40 K and their magnetization saturates above 5 000 Oe at room temperature.

scholarly journals Biodegradable Magnetic Nanocomposite Spheres Fabrication by O∕O Emulsion∕Solvent Evaporation Technique for Drug Delivery Purposes

2008 ◽  
Vol 2 (2) ◽  
Author(s):  
R. Asmatulu ◽  
A. Fakhari
Keyword(s):  
Magnetic Field ◽  
Drug Delivery ◽  
Magnetic Nanoparticles ◽  
Uv Light ◽  
Solvent Evaporation ◽  
Ferrous Chloride ◽  
Strong Base ◽  
Nanocomposite Particles ◽  
Pump Speed ◽  
Evaporation Technique

Drug targeting systems are important research areas for many diseases treatments (e.g., cancer, nerve damage, heart and artery, diabetic, eye and other medical treatments). Currently, magnetic field, electric field, ultrasound, temperature, UV light and∕or mechanical force systems are considered more for research and development. Magnetic targeted drug delivery system is usually preferred because targeted systems improve the therapeutic index of drug molecules by minimizing the toxic side effects on healthy cells and tissues. In this study, magnetic nanoparticles (∼10nm) were prepared by a chemical coprecipitation of ferric and ferrous chloride salts in the presence of a strong base (ammonium hydroxide) and used for a drug delivery purposes. An oil-in-oil emulsion∕solvent evaporation technique was chosen for the synthesis of nanocomposite spheres. Percentages of magnetic nanoparticles (%5, %10, %20 and%30) and poly(D,L-lactide-co-glycolide) were combined together to produce nanocomposite particles with diameters of 500nmto1.2micronmeter. The effect of particle concentrations on nanocomposite particle size and distribution and morphology were investigated by using scanning electron microscopy (SEM) and laser light scattering (LLS). Additionally, external magnetic fields with various magnet distance, magnetic field, pump speed and solid contents were applied to the nanocomposite particles in a liquid media to find out the effect of variables for the targeting of drug carrying nanocomposite spheres.

scholarly journals Characterization of glycidyl methacrylate based magnetic nanocomposites

2019 ◽  
Vol 73 (1) ◽  
pp. 25-35
Author(s):  
Bojana Markovic ◽  
Vojislav Spasojevic ◽  
Aleksandra Dapcevic ◽  
Zorica Vukovic ◽  
Vladimir Pavlovic ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Magnetic Nanoparticles ◽  
Glycidyl Methacrylate ◽  
Mercury Porosimetry ◽  
Magnetic Nanocomposite ◽  
Magnetic Nanocomposites ◽  
Tem Analysis ◽  
X Ray ◽  
Force Microscopy ◽  
Transmission Electron

Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful amino- functionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.

Heating of Zn-Substituted Manganese Ferrite Magnetic Nanoparticles in Alternating Magnetic Field

2015 ◽  
Vol 233-234 ◽  
pp. 761-765
Author(s):  
T.M. Elkhova ◽  
A.K. Yakushechkina ◽  
A.S. Semisalova ◽  
Y.K. Gun’ko ◽  
Yu.I. Spichkin ◽  
...  
Keyword(s):  
Magnetic Nanoparticles ◽  
Specific Absorption Rate ◽  
Metal Salt ◽  
Relaxation Mechanism ◽  
Manganese Ferrite ◽  
Zn Content ◽  
Magnetic Liquids ◽  
Naoh Solution ◽  
Brown Relaxation ◽  
Co Precipitation

In this report, were studied the heating capability of magnetic nanoparticles (MNps) made from Zn-substituted manganese ferrite compounds ZnxMn1-xFe2O4 with Zn content varying from 0% to 90%. The MNps of diameter 5-25 nm were synthesized by co-precipitation of metal salt solution with NaOH solution. It was shown, that specific absorption rate (SAR) for the compound with Zn content of 20% is bigger than the other ones exhibited 1.5 W/g. Also SAR for the magnetic liquids made of the MNps shows bigger SAR values, which indicates the Brown relaxation mechanism in the system.

Synthesis and Characterization of Nanopraticle Hematite (α-Fe2O3) Minerals from Natural Iron Sand Using Co-Precipitation Method and its Potential Applications as Extrinsic Semiconductor Materials Type-N

2019 ◽  
Vol 967 ◽  
pp. 259-266 ◽  
Author(s):  
Muhammad Rizal Fahlepy ◽  
Yuyu Wahyuni ◽  
Muhamma Andhika ◽  
Arini Tiwow Vistarani ◽  
Subaer
Keyword(s):  
Ammonium Hydroxide ◽  
Raw Material ◽  
Semiconductor Materials ◽  
Precipitation Method ◽  
Precipitation Process ◽  
Sem Image ◽  
Natural Iron ◽  
Before And After ◽  
Potential Applications ◽  
Co Precipitation

This research is about nanoparticles hematite (NPH) synthesized and characterized from natural iron sands using co-precipitation method and its potential applications as extrinsic semiconductor materials type-N. The aims of this study is to determine the process parameters to obtain hematite of high purity degree and to observe its physical characteristics as an extrinsic semiconductor materials type-N. The iron sand was first separated by magnetic technique and then dissolved into HCl solution before conducting the precipitation process. Precipitation was done by dripping ammonium hydroxide (NH4OH). Precipitated powder was dried at 80°C for 2 hours, and then calcined at 500°C, 600°C 700°C for 2 hours respectively. The composition of iron sands, purity degree, hematite mineral grain size, and space group were analyzed by XRF, XRD, FTIR and SEM. The XRF analysis result of raw material, showed that dominant element and composition in the sample is Fe with purity degree is 90.51%. The XRD result before and after precipitation showed Fe3O4 and α-Fe2O3. Fe3O4 purity degree was obtained 85%, and α-Fe2O3 in NPH500, NPH600, NPH700 were 63%, 83%, and 76%, respectively. FTIR spectral showed crystalline hematite characteristics stong band of 472.07 to 559.62 cm-1. SEM image showed the morphology of agglomeration particulates, when the calcinaton temperature increases, the agglomeration will be seperated due to thermal energy. Based on the charaterization results it was found that the natural iron sand synthesized has the potential to be applied as an N-type extrinsic semiconductor material.

An Investigation on Structural and Optical Properties of Nanocrystalline Bismuth Ferrite and Manganese Sillenite Powders

2020 ◽  
Vol 835 ◽  
pp. 317-323
Author(s):  
D.A. Rayan ◽  
E.A. Abdel-Mawla ◽  
S.K. Mohamed ◽  
A.A. Mohamed ◽  
Mohamed M. Rashad
Keyword(s):  
Optical Properties ◽  
Bismuth Ferrite ◽  
Ammonium Hydroxide ◽  
Band Gap Energy ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Munk Function ◽  
Ft Ir ◽  
Uv Visible ◽  
Co Precipitation

Nanocrystalline bismuth ferrite BFO; BiFeO3 and manganese sillenite, BMO; Bi12MnO20 (BMO) powders have been successfully elaborated using a facile co-precipitation approach. The formed materials were examined using X-ray diffraction analysis (XRD), field emission scanning electron microscopy (FE-SEM). Furthermore, the change in the optical properties was performed based on Fourier transform infrared spectroscopy (FT-IR) and UV-visible spectrophotometer. Typical, pure BiFeO3 and Bi12MnO20 phases were detected for the precursors precipitated at pH 10 based on ammonium hydroxide as a base then annealed at 500°C for 2h. Eventually, the optical band gap energy of BFO and BMO using Kubelka–Munk function based on Tauc’s plot was found to be 2.12 and 2.79 eV, respectively.

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