Investigation of Electrode Degradation in Alkaline Fuel Cells: A Research Proposal

Author(s):  
J. M. Rivas ◽  
J. Martinez-Frias ◽  
Salvador M. Aceves

Recent efforts in the development of fuel cell technology have concentrated on Proton Exchange Membrane, Solid Oxide, Molten Carbonate, and more recently, Direct Methanol fuel cells. Alkaline fuel cells, on the other hand, have received considerably less attention despite their successful use in the early years of the NASA Space Program. Alkaline fuel cells, however, still offer considerable potential as a viable energy conversion alternative, especially if the cell is incorporated into a regenerative system where the required reaction gases are produced. In this work, a review of the current status of development of alkaline fuel cells is undertaken with the objective of identifying areas for advancement of alkaline fuel cell technology. Specific areas of research have been identified and are described. These areas include detailed studies characterizing the evolution of the degradation of electrodes in alkaline fuel cells.

Author(s):  
Mingruo Hu

Abstract Potentially large amount of hydrogen resource in China could theoretically supply 100 × 106 fuel cell passenger cars yearly. The Chinese government highly values the hydrogen and fuel cell technology. Policies and plans have been put forward densely in the recent five years. Numerous companies, research institutes, and universities are developing proton exchange membrane fuel cell (PEMFC) and solid oxide fuel cell (SOFC)-related technologies. A preliminary local supplier chain of fuel cell-related technology has been formed. However, the lifetime is still a key issue for the fuel cell technology. More than 3500 fuel cell range extender electric vehicles were manufactured during 2016 and 2018, and at the beginning of 2019, there have been more than 40 hydrogen refueling stations including both under operation and under construction. It is estimated the number of fuel cell-based electric vehicles will reach 36,000 by the end of 2020; therefore, lack of hydrogen refueling station has become a key restriction for development of the fuel cell vehicle industry.


Author(s):  
Chong-Fang Ma ◽  
Hang Guo ◽  
Fang Ye ◽  
Jian Yu

As a clean, high efficiency power generation technology, fuel cell is a promising choice of next generation power device. Widely application of fuel cells will make a contribution to save fuels and reduce atmospheric pollution. In recent years, fuel cells science, technology and engineering have attracted great interest in China. There are more and more Chinese scientists and engineers embark upon fuel cell projects. The government also encourages academic institutions and companies to enter into this area. Research and development of fuel cells are growing rapidly in China. There are many chances and challenges in fuel cells’ research and development. The state of the art of research and development of fuel cells in China was overviewed in this paper. The types of fuel cells addressed in this paper included alkaline fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, solid oxide fuel cells, proton exchange membrane fuel cells and direct methanol fuel cells.


2013 ◽  
Vol 724-725 ◽  
pp. 715-722 ◽  
Author(s):  
R. K. Calay ◽  
Mohamad Y. Mustafa ◽  
Mahmoud F. Mustafa

In this paper; technological challenges and commercialization barriers for Proton Exchange Membrane (PEM) fuel cell are presented. Initially, the criteria that must be met by the energy source of the future is presented from the point of view of the authors. Sustainability, high energy content and combustion independence are recognized as the main decisive factor of future fuels, which are all met by hydrogen, consequently the application of fuel cells as combustion free direct energy converters of the future. Fuel cell technology as an alternative to heat engines is discussed in the context of the current status of fuel cells in various applications. Finally, the challenges facing fuel cell technology to replace heat engines from the commercial and research points of view are presented and discussed supported by current trends in the industry. It is concluded that there have been several advancements and breakthrough in materials, manufacturing and fabricating techniques of fuel cells since the eighties, many of these challenges which are associated with cost and durability still exist when compared with the already matured technology of internal combustion engines. Any effort to achieve these goals would be a significant contribution to the technology of the fuel cell.


Author(s):  
Jun Jie Chen ◽  
Xu Hui Gao ◽  
Long Fei Yan ◽  
De Guang Xu

Fuel cells are under development for a range of applications for transport, stationary and portable power appliances. Fuel cell technology has advanced to the stage where commercial field trials for both transport and stationary applications are in progress. Direct Carbon Fuel Cells (DCFC) utilize solid carbon as the fuel and have historically attracted less investment than other types of gas or liquid fed fuel cells. However, volatility in gas and oil commodity prices and the increasing concern about the environmental impact of burning heavy fossil fuels for power generation has led to DCFCs gaining more attention within the global study community. A DCFC converts the chemical energy in solid carbon directly into electricity through its direct electrochemical oxidation. The fuel utilization can be almost 100% as the fuel feed and product gases are distinct phases and thus can be easily separated. This is not the case with other fuel cell types for which the fuel utilization within the cell is typically limited to below 85%. The theoretical efficiency is also high, around 100%. The combination of these two factors, lead to the projected electric efficiency of DCFC approaching 80% - approximately twice the efficiency of current generation coal fired power plants, thus leading to a 50% reduction in greenhouse gas emissions. The amount of CO2 for storage/sequestration is also halved. Moreover, the exit gas is an almost pure CO2 stream, requiring little or no gas separation before compression for sequestration. Therefore, the energy and cost penalties to capture the CO2 will also be significantly less than for other technologies. Furthermore, a variety of abundant fuels such as coal, coke, tar, biomass and organic waste can be used. Despite these advantages, the technology is at an early stage of development requiring solutions to many complex challenges related to materials degradation, fuel delivery, reaction kinetics, stack fabrication and system design, before it can be considered for commercialization. This paper, following a brief introduction to other fuel cells, reviews in detail the current status of the direct carbon fuel cell technology, recent progress, technical challenges and discusses the future of the technology.


Author(s):  
Supramanian Srinivasan ◽  
Lakshmi Krishnan ◽  
Andrew B. Bocarsly ◽  
Kan-Lin Hsueh ◽  
Chiou-Chu Lai ◽  
...  

Investments of over $1 B have been made for Fuel Cell R&D over the past five decades, for space and terrestrial applications; the latter includes military, residential power and heating, transportation and remote and portable power. The types of fuel cells investigated for these applications are PEMFCs (proton exchange membrane fuel cells), AFCs (alkaline fuel cells), DMFCs (direct methanol fuel cells), PAFCs (phosphoric acid fuel cells), MCFCs (molten carbon fuel cells), SOFCs (solid oxide fuel cells). Cell structure, operating principles, and characteristics of each type of fuel cell is briefly compared. The performances of fuel cells vs. competing technologies are analyzed. The key issues are which of these energy conversion systems are technologically advanced and economically favorable and can meet the lifetime, reliability and safety requirements. This paper reviews fuel cells vs. competing technologies in each application category from a scientific and engineering point of view.


2006 ◽  
Vol 3 (4) ◽  
pp. 492-494 ◽  
Author(s):  
Sari Tasa ◽  
Teppo Aapro

Mobile device manufacturers would like to provide totally wireless solutions—including charging. Future multimedia devices need to have longer operation times as simultaneously they require more power. Device miniaturization leaves less volumetric space available also for the energy source. The energy density of the Li-ion batteries is high, and continuously developed, but not at the same speed as the demand from devices. Fuel cells can be one possible solution to power mobile devices without connection to the mains grid, but they will not fit to all use cases. The fuel cell system includes a core unit, fuel system, controls, and battery to level out peaks. The total energy efficiency is the sum of the performance of the whole system. The environmental performance of the fuel cell system cannot be determined yet. Regulatory and standardization work is on-going and driving the fuel cell technology development. The main target is in safety, which is very important aspect for energy technologies. The outcomes will also have an effect on efficiency, cost, design, and environmental performance. Proper water, thermal, airflow, and fuel management of the fuel cell system combined with mechanical durability and reliability are the crucial enablers for stable operation required from the integrated power source of a mobile device. Reliability must be on the same level as the reliability of the device the energy source is powering; this means years of continuous operation time. Typically, the end-users are not interested of the enabling technologies nor understand the usage limits. They are looking for easy to use devices to enhance their daily life. Fuel cell technology looks promising but there are many practical issues to be solved.


Author(s):  
C. W. Hong ◽  
C. H. Cheng ◽  
K. Fei

This paper describes the fundamental theory, algorithm and computation methods to predict the performance of proton exchange membrane fuel cells (PEMFC) and direct methanol fuel cells (DMFC) using a simplified computational fluid dynamics (CFD) approach. Based on the common transport phenomenon inside both fuel cells, the mass, momentum, energy and species equations were derived. Darcy laws were employed to simplify the momentum equation and also to linearize the species equation. The mathematical model was solved in various flow channel designs and some membrane electrode assembly (MEA) options. The major concern is mainly on the cathode side, in the PEMFC case, that dominates the performance deterioration due to potential loss in the flow field. In the case of DMFCs, both anode and cathode sides are simulated. The methanol crossover effect is also included. This virtual performance test bench plays an important role in the prototype fuel cell design. The computer aided design tool is proved to be useful in configuration designs. Additionally, it provides the detailed transport phenomenon inside the fuel cell stack.


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