Optimization of Relaxor Single Crystals for Bending Mode Applications
Rhombohedral relaxor single crystals are a class of materials that includes PZN-PT and PMN-PT in a certain range of compositions. This work presents an approach to predicting the physical properties of relaxor single crystals with an engineered domain state. A model based on properties of crystal variants and volume averaging indicates large piezoelectric coefficient d31 (690 pC/N) and d32 (−1670 pC/N) for the <110> cuts and a value over 4000 pC/N for d15 and the existence of d16 with a value as large as −2300 pC/N in <111> orientation cuts. The predictive capability of the approach results in a computational tool for the design of engineered domain states with properties optimized for specific applications. This has resulted in the identification of a crystal cut optimized for actuator and sensor applications that utilizes the transverse mode piezoelectric coupling coefficients (d31 and d32).