Evaluation of Effective Active Site on Pd Methane Oxidation Catalyst in Exhaust Gas of Lean Burn Gas Engine

2019 ◽  
Author(s):  
Yoshifuru Nitta ◽  
Yudai Yamasaki
Keyword(s):  
Active Sites ◽  
Oxidation Process ◽  
Estimation Method ◽  
Oxidation Catalyst ◽  
Pd Catalyst ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Ch4 Oxidation ◽  
Lean Burn ◽  
Exhaust Gas Temperature

Abstract Lean-burn gas engines have recently attracted attentions in the maritime industry, because they can reduce NOx, SOx and CO2 emissions. However, since methane (CH4) is the main component of natural gas, the slipped methane which is the unburned methane emitted from the lean-burn gas engines likely contributes to global warming. It is thus important to make progress on exhaust aftertreatment technologies for lean-burn gas engines. A Palladium (Pd) catalyst for CH4 oxidation is expected to provide a countermeasure for slipped methane, because it can activate at lower exhaust gas temperature. However, a deactivation in higher water (H2O) concentration should be overcome, because H2O inhibits CH4 oxidation. This study was performed investigates the effects of exhaust gas temperature or gas composition on active Pd catalyst sites to clarify CH4 oxidation performance in the exhaust gas of lean-burn gas engines. The authors developed the method of estimating effective active sites for the Pd catalyst at various exhaust gas temperature. The estimation method is based on the assumption that active sites used for CH4 oxidation process can be shared with the active sites used for Carbon mono-oxide (CO) oxidation. The molecular of chemisorbed CO on the active sites of the Pd catalyst can provide effective active sites for CH4 oxidation process. To clarify the effects of exhaust gas temperature and compositions on active Pd catalyst sites, the authors developed an experimental system for the new estimation method. This paper introduces experimental results and verifications of the new method, showing that chemisorbed CO volume on a Pd/Al2O3 catalyst is increased with increasing Pd loading in 250–450 °C, simulated as a typical exhaust gas temperature range of lean-burn gas engines. The results provide a part of the criteria for the application of Pd catalysts to the reduction of slipped methane in exhaust gas of lean-burn gas engines.

Dynamic Estimation Method of Effective Active Site on Palladium Methane Oxidation Catalyst in Exhaust Gas of Marine Lean Burn Gas Engine

2020 ◽  
Vol 142 (12) ◽  
Author(s):  
Yoshifuru Nitta ◽  
Yudai Yamasaki
Keyword(s):  
Active Sites ◽  
Oxidation Process ◽  
Estimation Method ◽  
Oxidation Catalyst ◽  
Pd Catalyst ◽  
Exhaust Gas ◽  
Maritime Industry ◽  
Ch4 Oxidation ◽  
Lean Burn ◽  
Exhaust Temperature

Abstract Lean-burn gas engines have recently attracted attention in the maritime industry, because they can reduce NOx, SOx, and CO2 emissions. However, since methane (CH4) is the main component of natural gas, the slipped methane, which is the unburned methane, likely contributes to global warming. It is thus important to make progress on exhaust after-treatment technologies for lean-burn gas engines. A Palladium (Pd) catalyst for CH4 oxidation is expected to provide a countermeasure for the slipped methane, because it can activate at lower exhaust temperature comparing with platinum. However, a de-activation in higher water (H2O) concentration should be overcome because H2O inhibits CH4 oxidation. This study was performed to investigate the effects of exhaust temperature or gas composition on active Pd catalyst sites to clarify CH4 oxidation performance in the exhaust gas of lean-burn gas engines. The authors developed the method of estimating effective active sites for the Pd catalyst at various exhaust temperatures. The estimation method is based on the assumption that active sites used for CH4 oxidation process can be shared with the active sites used for carbon mono-oxide (CO) oxidation. The molecular of chemisorbed CO on the active sites of the Pd catalyst can provide effective active sites for CH4 oxidation process. This paper introduces experimental results and verifications of the new method, showing that chemisorbed CO volume on a Pd/Al2O3 catalyst is increased with increasing Pd loading in 250–450 °C, simulated as a typical exhaust temperature range of lean-burn gas engines.

Effect of Support Materials on Pd Methane Oxidation Catalyst Using Dynamic Estimation Method

2020 ◽  
Author(s):  
Yoshifuru Nitta ◽  
Yudai Yamasaki
Keyword(s):  
Active Sites ◽  
Estimation Method ◽  
Pd Catalyst ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Ch4 Oxidation ◽  
Lean Burn ◽  
Support Materials ◽  
Dynamic Estimation ◽  
Oxidation Performance

Abstract In the maritime industry, lean burn gas engines have been expected to reduce emissions such as NOx, SOx and CO2. On the other hand, the slipped methane, which is the unburned methane (CH4) emitted from lean burn gas engines have a concern for impact on global warming. It is therefore important to make a progress on the exhaust aftertreatment technologies for lean burn gas engines. As a countermeasure for the slipped methane, Palladium (Pd) catalyst for CH4 oxidation can be expected to provide one of the most feasible methods because Palladium (Pd) catalyst for CH4 oxidation can activate in the lower temperature. However, recent studies have shown that the reversible adsorption by water vapor (H2O) inhibits CH4 oxidation on the catalyst and deactivates its CH4 oxidation capacity. It can be known that the CH4 oxidation performance is influenced by active sites on the Pd catalyst. However, measuring methods for active sites on Pd catalyst under exhaust gas conditions could not be found. Authors thus proposed a dynamic estimation method for the quantity of effective active sites on Pd catalyst in exhaust gas temperature using water-gas shift reaction between the saturated chemisorbed CO and the pulse induced H2O. The previous study clarified the relationship between adsorbed CO volume and Pd loading in gas engine exhaust gas temperature and revealed the effects of flow conditions on the estimation of adsorbed CO volume. However, in order to improve CH4 oxidation performance on Pd catalyst under exhaust gas conditions, it is important that effects of support materials on active sites should clarify. This paper introduced experimental results of estimation of absorbed CO volume on different support materials of Pd catalysts by using the dynamic evaluation method. Experimental results show that chemisorbed CO volume on Pd/Al2O3 catalyst exhibits higher chemisorbed CO volume than that of Pd/SiO2 and Pd/Al2O3-SiO2 catalyst in 250–450 °C. These results can provide a part of the criteria for the application of Pd catalyst for reducing the slipped methane in exhaust gas of lean burn gas engines.

A Parametric Study of Diesel Oxidation Catalyst Performance on CO Reduction in Diesel Dual Fuel Engine Exhaust

2015 ◽  
Vol 656-657 ◽  
pp. 538-543 ◽  
Author(s):  
Sirichai Jirawongnuson ◽  
Worathep Wachirapan ◽  
Tul Suthiprasert ◽  
Ekathai Wirojsakunchai
Keyword(s):  
Diesel Oxidation Catalyst ◽  
Oxidation Catalyst ◽  
Dual Fuel ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Engine Exhaust ◽  
Gas System ◽  
Diesel Oxidation ◽  
Co Reduction ◽  
Exhaust Gas Temperature

In this research study, a synthetic exhaust gas system is employed to simulate various exhaust conditions similar to those from conventional diesel and Dual Fuel-Premixed Charge Compression Ignition (DF-PCCI) combustion. OEM DOC is tested to compare the effectiveness of reducing CO from both exhaust characteristics. Variations of the temperature and the concentration of CO, THC, and O2 are done to investigate DOC performance on CO reductions according to Design of Experiment (DOE) concept. The results showed that in DF-PCCI exhaust conditions, DOC requires higher exhaust gas temperature as well as O2 concentration to reduce CO emissions.

scholarly journals Soot Oxidation in Diesel Exhaust on Silver Catalyst Supported by Alumina, Titanium and Zirconium

2021 ◽  
Vol 302 ◽  
pp. 01008
Author(s):  
Punya Promhuad ◽  
Boonlue Sawatmongkhon
Keyword(s):  
Titanium Oxide ◽  
Zirconium Oxide ◽  
Soot Oxidation ◽  
Oxidation Catalyst ◽  
Particulate Filter ◽  
Exhaust Gas ◽  
Silver Catalyst ◽  
Gas Temperature ◽  
Oxidation Activity ◽  
Exhaust Gas Temperature

Diesel Particulate Filter (DPF) is used to limit the emission of particulate matter (PM). The operation of DPF has two consecutive functions which are filtration of PM and regeneration. Performance of DPF is reduced by clogging of the filter. This problem is improved by soot oxidation in the regeneration process. The soot is completely oxidized by oxygen when temperature is higher than 600 °C. However, the exhaust gas temperature in normal operating of the diesel engine is lower than the temperature of soot complete oxidation. The problem of low temperature in soot oxidation is improved by oxidation catalyst because the oxidation catalyst is used to reduce light of temperature in soot oxidation. The study’s purpose is to compare the oxidation activity of silver catalyst supported on alumina (Al2O3), Titanium oxide (TiO2), and Zirconium oxide (ZrO2). The compression of soot oxidation on silver catalyst loaded on several support which showed silver base on alumina was the best of soot oxidation compared with titanium oxide and zirconium oxide. The behaviour of soot oxidation in silver base on titanium oxide and zirconium oxide were similar activity.

Advanced Thermal Management for Modern Diesel Engines: Optimized Synergy Between Engine Hardware and Software Intelligence

2012 ◽  
Author(s):  
Thomas Körfer ◽  
Hartwig Busch ◽  
Andreas Kolbeck ◽  
Christopher Severin ◽  
Thorsten Schnorbus ◽  
...  
Keyword(s):  
Thermal Management ◽  
Diesel Engines ◽  
The Other ◽  
Valve Train ◽  
Oxidation Catalyst ◽  
Temperature Management ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Conversion Rates ◽  
Exhaust Gas Temperature

Both, the continuous tightening of the exhaust emission standards and the global efforts for a significant lowering of CO2 output in public traffic display significant developments for future diesel engines. These engines will utilize not only the mandatory Diesel oxidation catalyst (DOC) and particulate trap (DPF), but also a DeNOx aftertreatment system as well — at least for heavier vehicles. The DOC as well as actually available sophisticated DeNOx aftertreatment technologies, i.e. LNT and SCR, depends on proper exhaust gas temperatures to achieve a high conversion rates. This aspect becomes continuously critical due to intensified measures for CO2 reduction, which will conclude in a drop of exhaust gas temperatures. Furthermore, this trend has to be taken into account regarding future electrification and hybridization scenarios. In order to ensure the high NOx conversion rates in the EAS intelligent temperature management strategies will be required, not only based on conventional calibration measures, but also a further upgrade of the engine hardware. Advanced split-cooling and similar thermal management technologies offer the merit to lower CO2 emissions on one hand and increase exhaust gas temperature at cold start and warm-up simultaneously on the other hand. Besides this, also variable valve train functionalities deliver a substantial potential of active thermal management. In the context of this paper various concepts for exhaust gas temperature management are investigated and compared. The final judgment will focus on the effectiveness concerning real exhaust temperature increase vs. corresponding fuel economy penalty. Further factors, like operational robustness, consequences on operational strategies and related software algorithms as well as cost are assessed. The utilized reference engine in this advanced program is represented by a refined I-4 research engine to achieve best combustion efficiency at minimal engine-out emissions. The detailed studies were performed with an injection strategy, featuring one pilot injection and one main injection event, and an active, advanced closed-loop combustion control. The engine used in this study allows fulfillment of Euro 6 and Tier 2 Bin 5 emissions standards, while offering high power densities above 80 kW/ltr. As a résumé, it can be stated, that with all accomplished variations a significant increase in temperature downstream low pressure turbine can be achieved. The PI and PoI quantities define dominant parameters for emission formation under cold and warm conditions. By using an exhaust cam-phaser CO-, HC- and NOx emissions can be significantly lowered, separating VVT functions from the other investigated strategies.

An Exhaust Gas Temperature Increase Technique Using EGR Device for the Application of Waste Heat Recovery Technology on a Lean Burn Gas Engine

2018 ◽  
Author(s):  
Yasuhisa Ichikawa ◽  
Hidenori Sekiguchi ◽  
Oleksiy Bondarenko ◽  
Koichi Hirata
Keyword(s):  
Temperature Increase ◽  
Heat Recovery ◽  
Waste Heat Recovery ◽  
Waste Heat ◽  
Combustion Efficiency ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Lean Burn ◽  
Gas Engine ◽  
Exhaust Gas Temperature

This study aims to develop an exhaust gas temperature increase technique of a lean burn gas engine, to improve the performance of the waste heat recovery devices that potentially can be installed in the future. This paper shows the exhaust gas temperature increase technique using an EGR device. In our experiments, the lean burn gas engine has the rated power output of 400 kW with spark-ignition and pre-chamber systems. The EGR device was developed and installed to the gas engine. The experimental results showed that the exhaust gas temperature was increased to +30 °C at the EGR rate of 15 % with maintained NOx emission and CA MFB 50% by decreasing the relative air/fuel ratio (Λ) and advancing the ignition timing (θig). In addition, the gross generation efficiency was slightly increased with increasing the EGR rate. This result was explained using three factors; the internal engine efficiency, the combustion efficiency, and the recirculated energy rate.

Lime kiln conversion from coke to natural gas operation – an option in direction of sustainable energy

2020 ◽  
pp. 431-434
Author(s):  
Oliver Arndt
Keyword(s):  
Natural Gas ◽  
New Technology ◽  
Exhaust Gas ◽  
Gas Temperature ◽  
Gaseous Fuels ◽  
Lime Kiln ◽  
Lime Kilns ◽  
Co2 Balance ◽  
Exhaust Gas Temperature

This paper deals with the conversion of coke fired lime kilns to gas and the conclusions drawn from the completed projects. The paper presents (1) the decision process associated with the adoption of the new technology, (2) the necessary steps of the conversion, (3) the experiences and issues which occurred during the first campaign, (4) the impacts on the beet sugar factory (i.e. on the CO2 balance and exhaust gas temperature), (5) the long term impressions and capabilities of several campaigns of operation, (6) the details of available technologies and (7) additional benefits that would justify a conversion from coke to natural gas operation on existing lime kilns. (8) Forecast view to develop systems usable for alternative gaseous fuels (e.g. biogas).

scholarly journals Exhaust Gas Temperature Measurements in Diagnostics of Turbocharged Marine Internal Combustion Engines Part I Standard Measurements

2015 ◽  
Vol 22 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Zbigniew Korczewski
Keyword(s):  
Internal Combustion Engines ◽  
Internal Combustion ◽  
Technical Condition ◽  
Temperature Measurements ◽  
Injection System ◽  
Exhaust Gas ◽  
Combustion Engines ◽  
Gas Temperature ◽  
Measuring Signal ◽  
Exhaust Gas Temperature

Abstract The article discusses the problem of diagnostic informativeness of exhaust gas temperature measurements in turbocharged marine internal combustion engines. Theoretical principles of the process of exhaust gas flow in turbocharger inlet channels are analysed in its dynamic and energetic aspects. Diagnostic parameters are defined which enable to formulate general evaluation of technical condition of the engine based on standard online measurements of the exhaust gas temperature. A proposal is made to extend the parametric methods of diagnosing workspaces in turbocharged marine engines by analysing time-histories of enthalpy changes of the exhaust gas flowing to the turbocompressor turbine. Such a time-history can be worked out based on dynamic measurements of the exhaust gas temperature, performed using a specially designed sheathed thermocouple. The first part of the article discusses possibilities to perform diagnostic inference about technical condition of a marine engine with pulse turbocharging system based on standard measurements of exhaust gas temperature in characteristic control cross-sections of its thermal and flow system. Selected metrological issues of online exhaust gas temperature measurements in those engines are discusses in detail, with special attention being focused on the observed disturbances and thermodynamic interpretation of the recorded measuring signal. Diagnostic informativeness of the exhaust gas temperature measurements performed in steady-state conditions of engine operation is analysed in the context of possible evaluations of technical condition of the engine workspaces, the injection system, and the fuel delivery process.

Energetic Based Organic Fluid Selection for a Solid Oxide Fuel Cell-Organic Rankine Cycle Combined System

2012 ◽  
Vol 622-623 ◽  
pp. 1162-1167
Author(s):  
Han Fei Tuo
Keyword(s):  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Heat Recovery ◽  
Waste Heat ◽  
Solid Oxide ◽  
Exhaust Gas ◽  
Oxide Fuel ◽  
Gas Temperature ◽  
Selection For ◽  
Exhaust Gas Temperature

In this study, energetic based fluid selection for a solid oxide fuel cell-organic rankine combined power system is investigated. 9 dry organic fluids with varied critical temperatures are chosen and their corresponding ORC cycle performances are evaluated at different turbine inlet temperatures and exhaust gas temperature (waste heat source) from the upper cycle. It is found that actual ORC cycle efficiency for each fluid strongly depends on the waste heat recovery performance of the heat recovery vapor generator. Exhaust gas temperature determines the optimal fluid which yields the highest efficiency.

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