Thermal Properties of Microcrystalline Cellulose Derived Carbons

2007 ◽  
Author(s):  
Yo-Rhin Rhim ◽  
Dajie Zhang ◽  
Dennis C. Nagle ◽  
Michael Rooney ◽  
Cila Herman
Keyword(s):  
Thermal Conductivity ◽  
Heat Treatment ◽  
Thermal Diffusivity ◽  
Specific Heat ◽  
Microcrystalline Cellulose ◽  
Heat Treatment Temperature ◽  
Structural Characteristics ◽  
Treatment Temperature ◽  
Carbon Clusters ◽  
Flash Method

The thermal transport properties were studied for carbons produced by the carbonization of microcrystalline cellulose. Thermal diffusivity, specific heat, and thermal conductivity were measured via flash method for cellulose derived carbons prepared at various heat treatment temperatures ranging from 250°C to 1000°C. The thermal diffusivity as a function of increasing heat treatment temperature was observed to have four distinct linear regions, which could be related directly to the microstructures of the materials generated by the specific heat treatment temperature. Specific heat values indicated the coexistence of polar and non-polar phases in both partially carbonized materials obtained at lower heat treatment temperatures and fully carbonized materials formed at higher heat treatment temperatures. For partially carbonized materials, the polar groups consisting of residual hydroxyl and carboxyl were still present. For fully carbonized materials, the polar phases have largely been volatilized and conductive nano-carbon clusters were nucleated and observed to grow in an amorphous carbon bed until percolation effects were observed. Such structural characteristics are well supported by FT-IR characterizations. Lastly, a linear relationship between testing temperature and thermal conductivity indicates boundary scattering between highly conductive carbon clusters as the main mechanism for heat conduction.

Thermal Characterization of Carbon-Carbon Composites

2011 ◽  
Author(s):  
Messiha Saad ◽  
Darryl Baker ◽  
Rhys Reaves
Keyword(s):  
Thermal Conductivity ◽  
Thermal Properties ◽  
Thermal Diffusivity ◽  
Specific Heat ◽  
Critical Role ◽  
Carbon Composite ◽  
Flash Method ◽  
Carbon Composites ◽  
Energy Storage Devices ◽  
Graphitized Carbon

Thermal properties of materials such as specific heat, thermal diffusivity, and thermal conductivity are very important in the engineering design process and analysis of aerospace vehicles as well as space systems. These properties are also important in power generation, transportation, and energy storage devices including fuel cells and solar cells. Thermal conductivity plays a critical role in the performance of materials in high temperature applications. Thermal conductivity is the property that determines the working temperature levels of the material, and it is an important parameter in problems involving heat transfer and thermal structures. The objective of this research is to develop thermal properties data base for carbon-carbon and graphitized carbon-carbon composite materials. The carbon-carbon composites tested were produced by the Resin Transfer Molding (RTM) process using T300 2-D carbon fabric and Primaset PT-30 cyanate ester. The graphitized carbon-carbon composite was heat treated to 2500°C. The flash method was used to measure the thermal diffusivity of the materials; this method is based on America Society for Testing and Materials, ASTM E1461 standard. In addition, the differential scanning calorimeter was used in accordance with the ASTM E1269 standard to determine the specific heat. The thermal conductivity was determined using the measured values of their thermal diffusivity, specific heat, and the density of the materials.

Thermal Properties of Carbon and Graphite Foams

2012 ◽  
Author(s):  
Melanie Patrick ◽  
Amber Vital ◽  
Darian Bridges ◽  
Messiha Saad
Keyword(s):  
Thermal Conductivity ◽  
Thermal Properties ◽  
Thermal Diffusivity ◽  
Specific Heat ◽  
Critical Role ◽  
Flash Method ◽  
Petroleum Pitch ◽  
Energy Storage Devices ◽  
Carbon And Graphite ◽  
Temperature Levels

Thermal properties such as specific heat, thermal diffusivity, and thermal conductivity of carbon and graphite foams are very important in the engineering design process and analysis of aerospace vehicles as well as space systems. These properties are also important in power generation, transportation, and energy storage devices including fuel cells. Thermal conductivity is the property that determines the working temperature levels of the material; it plays a critical role in the performance of materials in high temperature applications and it is an important parameter in problems involving heat transfer and thermal structures. The objective of this paper is to develop a thermal properties data base for carbon and graphite foams. Carbon foams are commercially produced from urethane, petroleum pitch-based and coal-based processes, and they typically have large pores (> 350 μm) and low density (< 1.0 g/cm3). Petroleum pitch-base and coal-base carbon/graphite foams can be tailored to be thermally conductive or thermally insulating. The thermophysical properties of carbon and graphite foams have been investigated using experimental methods. The flash method was used to measure the thermal diffusivity of the foams; this method is based on America Society for Testing and Materials standard (ASTM E1461). In addition, the Differential Scanning Calorimeter was used in accordance with the ASTM E1269 standard to measure the specific heat. The measured thermal diffusivity, specific heat, and density data were used to compute the thermal conductivity of the foams.

Thermal Properties Measurement of Particulate Fouling Samples of Air-Cooled Heat Exchangers Using Laser Flash Method

2020 ◽  
Author(s):  
Arjun Sharma ◽  
M. D. Islam ◽  
Ebrahim Al Hajri
Keyword(s):  
Thermal Conductivity ◽  
Thermal Diffusivity ◽  
Middle East ◽  
Specific Heat ◽  
Thermophysical Properties ◽  
Heat Exchangers ◽  
Laser Flash ◽  
Flash Method ◽  
Particulate Fouling ◽  
Major Factors

Abstract Fouling is one of the major factors that drastically affects heat exchanger performance. Especially in Middle East where most of the heat exchangers are air cooled due to scarcity of water. As these heat exchangers are placed in a harsh climate, they are at high risk of low performance due to dusty/sticky particulate fouling. In order to identify possible active/passive methods to control or ideally eliminate particulate fouling, it is desirable to know exact thermophysical properties of such particulate fouling. This study presents thermophysical property characterization of selected fouling samples from eight different fin fan heat exchangers installed in an oil & gas facility in the Middle East. Laser flash Analysis (LFA) method is a well-known technique for measurement of the thermophysical properties: thermal diffusivity, specific heat and thermal conductivity of materials. A new technique was developed to prepare powder particulate fouling samples to make them as disc shaped samples while maintaining the range of ± 12 mm diameter and ± 2 mm thickness. The LFA measurements was conducted using LFA 447 Nano Flash Netzsch over the temperature range from 25 °C to 125°C. The thermal diffusivity was measured with an accuracy of ± 3% and the specific heat capacity with an accuracy of ± 5%. As the thermal conductivity is a product of these two measured values, is calculated with an accuracy of ± 5.8% and the measurement repeatability was within 2%.

Thermal Characterization of IM7/8552-1 Carbon-Epoxy Composites

2014 ◽  
Author(s):  
Messiha T. Saad ◽  
Sandi G. Miller ◽  
Torrence Marunda
Keyword(s):  
Thermal Conductivity ◽  
Thermal Properties ◽  
Thermal Diffusivity ◽  
Carbon Fiber ◽  
Specific Heat ◽  
High Performance ◽  
Critical Role ◽  
Flash Method ◽  
Handling Characteristics ◽  
Wide Range

Thermal properties of composite materials such as, thermal conductivity, diffusivity, and specific heat are very important in engineering design process and analysis of aerospace vehicles as well as space systems. These properties are also important in power generation, transportation, and energy storage devices including fuel cells. Thermal conductivity is the property that determines the working temperature levels of the material; it plays a critical role in the performance of materials in high temperature applications, and it is an important parameter in problems involving heat transfer and thermal structures. The objective of this paper is to develop a thermal properties data base for the carbon fiber-epoxy (IM7/8552-1) composite. The IM7 carbon fiber is a continuous, high performance, intermediate modulus, PAN based fiber. This fiber has been surface treated and can be sized to improve its interlaminar shear properties, handling characteristics, and structural properties. The 8552 is a high performance tough epoxy matrix for use in primary aerospace structures. It exhibits good impact resistance and damage tolerance for a wide range of applications. The IM7/8552-1 is an amine cured unidirectional prepreg. The manufacturer recommended cure cycle for this material was followed, which includes consolidation under vacuum and autoclave pressure. The composite has a service temperature up to 121°C (250°F). The thermal properties of IM7/8552-1 carbon-epoxy have been investigated using experimental methods. The flash method was used to measure the thermal diffusivity of the composite. This method is based on the American Society for Testing and Materials standard, ASTM E1461. In addition, the Differential Scanning Calorimeter was used in accordance with the ASTM E1269 standard to measure the specific heat. The measured thermal diffusivity, specific heat, and density data were used to compute the thermal conductivity of the IM7/8552-1 carbon-epoxy composite.

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