Combustion of Natural Gas, Hydrogen and Bio-Fuels at Ultra-Wet Conditions

2011 ◽  
Author(s):  
Sebastian Go¨ke ◽  
Steffen Terhaar ◽  
Sebastian Schimek ◽  
Katharina Go¨ckeler ◽  
Christian O. Paschereit
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Combustion Process ◽  
Pure Hydrogen ◽  
Nox Emissions ◽  
Steam Content ◽  
Wide Range ◽  
Air Mixing ◽  
Flame Flashback

Humidified Gas Turbines promise a significant increase in efficiency compared to the dry gas turbine cycle. In single cycle applications, efficiencies up to 60% seem possible with humidified turbines. Additionally, the steam effectively inhibits the formation of NOx emissions and also allows for operating the gas turbine on hydrogen-rich fuels. The current study is conducted within the European Advanced Grant Research Project GREENEST. The premixed combustion at ultra wet conditions is investigated for natural gas, hydrogen, and mixtures of both fuels, covering lower heating values between 27 MJ/kg and 120 MJ/kg. In addition to the experiments, the combustion process is also examined numerically. The flow field and the fuel-air mixing of the burner were investigated in a water tunnel using Particle Image Velocimetry and Laser Induced Fluorescence. Gas-fired tests were conducted at atmospheric pressure, inlet temperatures between 200°C and 370°C, and degrees of humidity from 0% to 50%. Steam efficiently inhibits the formation of NOx emissions. For all tested fuels, both NOx and CO emissions of below 10 ppm were measured up to near-stoichiometric gas composition at wet conditions. Operation on pure hydrogen is possible up to very high degrees of humidity, but even a relatively low steam content prevents flame flashback. Increasing hydrogen content leads to a more compact flame, which is anchored closer to the burner outlet, while increasing steam content moves the flame downstream and increases the flame volume. In addition to the experiments, the combustion process was modeled using a reactor network. The predicted NOx and CO emission levels agree well with the experimental results over a wide range of temperatures, steam content, and fuel composition.

Passive Control of Combustion Instability in a Low Emissions Aeroderivative Gas Turbine

2004 ◽  
Author(s):  
Tomas Scarinci ◽  
Christopher Freeman ◽  
Ivor Day
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Laboratory Testing ◽  
Passive Control ◽  
Pressure Ratio ◽  
Combustion Process ◽  
Field Trials ◽  
Low Noise ◽  
Wide Range ◽  
Air Mixing

This paper describes the conceptual ideas, the theoretical validation, the laboratory testing and the field trials of a recently patented fuel-air mixing device for use in high-pressure ratio, low emissions, gaseous-fueled gas turbines. By making the fuel-air mixing process insensitive to pressure fluctuations in the combustion chamber, it is possible to avoid the common problem of positive feedback between mixture strength and the unsteady combustion process. More specifically, a mixing duct has been designed such that fuel-air ratio fluctuations over a wide range of frequencies can be damped out by passive design means. By scaling the design in such a way that the range of damped frequencies covers the frequency spectrum of the acoustic modes in the combustor, the instability mechanism can be removed. After systematic development, this design philosophy was successfully applied to a 35:1 pressure ratio aeroderivative gas turbine yielding very low noise levels and very competitive NOx and CO measurements. The development of the new premixer is described from conceptual origins through analytic and CFD evaluation to laboratory testing and final field trials. Also included in this paper are comments about the practical issues of mixing, flashback resistance and autoignition.

First Assessment of Biogas Co-Firing on the GE MS9001FA Gas Turbine Using CFD

2003 ◽  
Author(s):  
J. A. Lycklama a` Nijeholt ◽  
E. M. J. Komen ◽  
A. J. L. Verhage ◽  
M. C. van Beek
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Combustion Process ◽  
Geometrical Model ◽  
Electricity Production ◽  
Power Station ◽  
Complete Combustion ◽  
Air Mixing ◽  
The Impact

Replacement of fossil fuel by biomass-derived fuel is currently under study in the Netherlands within the context of CO2 -neutral electricity production. In view of this, co-firing biogas in the natural-gas fired Eems gas turbine power plant is being considered. This would entail extension of the power station with a biomass gasification plant for the production of biogas. The main unit of the Electrabel Eemshaven Power Station consists of five GE MS9001FA-gas turbines. A target is to replace up to 13% of natural gas consumption by biogas. The objective of the current project was to determine the impact of co-firing on the flame behavior. Therefore various options for biogas co-firing using combinations of pilot and premix burners have been studied. Computational Fluid Dynamics (CFD) simulations of the combustion process using a geometrical model of the complete combustion chamber have been performed. The flow conditions at the premix burner outlets were determined with a separate, detailed CFD model of the burner, simulating the fuel-air mixing with the required high accuracy. Advanced combustion modeling with help of the detailed GRI 3.0-reaction mechanism was used, as well as simpler models for fast chemical kinetics. A method was devised for calibrating the applied combustion models. Various firing strategies involving the premix and pilot burners were analyzed. Safe ranges for biogas co-firing have been determined in this first feasibility study.

Comparison of Numerical Combustion Models for Hydrogen and Hydrogen-Rich Syngas Applied for Dry-Low-NOx-Micromix-Combustion

2016 ◽  
Author(s):  
H. H.-W. Funke ◽  
N. Beckmann ◽  
J. Keinz ◽  
S. Abanteriba
Keyword(s):  
Reaction Mechanism ◽  
Gas Turbines ◽  
Combustion Process ◽  
Computational Effort ◽  
Hydrogen Combustion ◽  
Combustion Stability ◽  
Research Approach ◽  
Pure Hydrogen ◽  
Nox Emissions ◽  
Combustion Models

The Dry-Low-NOx (DLN) Micromix combustion technology has been developed as low emission combustion principle for industrial gas turbines fueled with hydrogen or syngas. The combustion process is based on the phenomenon of jet-in-crossflow-mixing. Fuel is injected perpendicular into the air-cross-flow and burned in a multitude of miniaturized, diffusion-like flames. The miniaturization of the flames leads to a significant reduction of NOx emissions due to the very short residence time of reactants in the flame. In the Micromix research approach, CFD analyses are validated towards experimental results. The combination of numerical and experimental methods allows an efficient design and optimization of DLN Micromix combustors concerning combustion stability and low NOx emissions. The paper presents a comparison of several numerical combustion models for hydrogen and hydrogen-rich syngas. They differ in the complexity of the underlying reaction mechanism and the associated computational effort. For pure hydrogen combustion a one-step global reaction is applied using a hybrid Eddy-Break-up model that incorporates finite rate kinetics. The model is evaluated and compared to a detailed hydrogen combustion mechanism derived by Li et al. including 9 species and 19 reversible elementary reactions. Based on this mechanism, reduction of the computational effort is achieved by applying the Flamelet Generated Manifolds (FGM) method while the accuracy of the detailed reaction scheme is maintained. For hydrogen-rich syngas combustion (H2-CO) numerical analyses based on a skeletal H2/CO reaction mechanism derived by Hawkes et al. and a detailed reaction mechanism provided by Ranzi et al. are performed. The comparison between combustion models and the validation of numerical results is based on exhaust gas compositions available from experimental investigation on DLN Micromix combustors. The conducted evaluation confirms that the applied detailed combustion mechanisms are able to predict the general physics of the DLN-Micromix combustion process accurately. The Flamelet Generated Manifolds method proved to be generally suitable to reduce the computational effort while maintaining the accuracy of detailed chemistry. Especially for reaction mechanisms with a high number of species accuracy and computational effort can be balanced using the FGM model.

NOx Emissions Reduction in an Innovative Industrial Gas Turbine Combustor (GE10 Machine): A Numerical Study of the Benefits of a New Pilot-System on Flame Structure and Emissions

2005 ◽  
Author(s):  
Antonio Andreini ◽  
Bruno Facchini ◽  
Luca Mangani ◽  
Antonio Asti ◽  
Gianni Ceccherini ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Numerical Study ◽  
Flame Structure ◽  
Combustion Model ◽  
Emissions Reduction ◽  
Minimal Amount ◽  
Nox Emissions ◽  
Ambient Temperatures ◽  
Wide Range

One of the driving requirements in gas turbine design is emissions reduction. In the mature markets (especially the North America), permits to install new gas turbines are granted provided emissions meet more and more restrictive requirements, in a wide range of ambient temperatures and loads. To meet such requirements, design techniques have to take advantage also of the most recent CFD tools. As a successful example of this, this paper reports the results of a reactive 3D numerical study of a single-can combustor for the GE10 machine, recently updated by GE-Energy. This work aims to evaluate the benefits on the flame shape and on NOx emissions of a new pilot-system located on the upper part of the liner. The former GE10 combustor is equipped with fuel-injecting-holes realizing purely diffusive pilot-flames. To reduce NOx emissions from the current 25 ppmvd@15%O2 to less than 15 ppmvd@15%O2 (in the ambient temperature range from −28.9°C to +37.8°C and in the load range from 50% and 100%), the new version of the combustor is equipped with 4 swirler-burners realizing lean-premixed pilot flames; these flames in turn are stabilized by a minimal amount of lean-diffusive sub-pilot-fuel. The overall goal of this new configuration is the reduction of the fraction of fuel burnt in diffusive flames, lowering peak temperatures and therefore NOx emissions. To analyse the new flame structure and to check the emissions reduction, a reactive RANS study was performed using STAR-CD™ package. A user-defined combustion model was used, while to estimate NOx emissions a specific scheme was also developed. Three different ambient temperatures (ISO, −28.9°C and 37.8°C) were simulated. Results were then compared with experimental measurements (taken both from the engine and from the rig), resulting in reasonable agreement. Finally, an additional simulation with an advanced combustion model, based on the laminar flamelet approach, was performed. The model is based on the G-Equation scheme but was modified to study partially premixed flames. A geometric procedure to solve G-Equation was implemented as add-on in STAR-CD™.

Study of a Rich/Lean Staged Combustion Concept for Hydrogen at Gas Turbine Relevant Conditions

2013 ◽  
Author(s):  
Felipe Bolaños ◽  
Dieter Winkler ◽  
Felipe Piringer ◽  
Timothy Griffin ◽  
Rolf Bombach ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Carbon Capture ◽  
Flame Temperature ◽  
Nox Emissions ◽  
Hydrogen Fuel ◽  
Auto Ignition ◽  
Wide Range ◽  
The Rich

The combustion of hydrogen-rich fuels (> 80 % vol. H2), relevant for gas turbine cycles with “pre-combustion” carbon capture, creates great challenges in the application of standard lean premix combustion technology. The significant higher flame speed and drastically reduced auto-ignition delay time of hydrogen compared to those of natural gas, which is normally burned in gas turbines, increase the risk of higher NOX emissions and material damage due to flashback. Combustion concepts for gas turbines operating on hydrogen fuel need to be adapted to assure safe and low-emission combustion. A rich/lean (R/L) combustion concept with integrated heat transfer that addresses the challenges of hydrogen combustion has been investigated. A sub-scale, staged burner with full optical access has been designed and tested at gas turbine relevant conditions (flame temperature of 1750 K, preheat temperature of 400 °C and a pressure of 8 bar). Results of the burner tests have confirmed the capability of the rich/lean staged concept to reduce the NOx emissions for undiluted hydrogen fuel. The NOx emissions were reduced from 165 ppm measured without staging (fuel pre-conversion) to 23 ppm for an R/L design having a fuel-rich hydrogen pre-conversion of 50 % at a constant power of 8.7 kW. In the realized R/L concept the products of the first rich stage, which is ignited by a Pt/Pd catalyst (under a laminar flow, Re ≈ 1900) are combusted in a diffusion-flame-like lean stage (turbulent flow Re ≈ 18500) without any flashback risk. The optical accessibility of the reactor has allowed insight into the combustion processes of both stages. Applying OH-LIF and OH*-chemiluminescence optical techniques, it was shown that mainly homogeneous reactions at rich conditions take place in the first stage, questioning the importance of a catalyst in the system, and opening a wide range of optimization possibilities. The promising results obtained in this study suggest that such a rich/lean staged burner with integrated heat transfer could help to develop a new generation of gas turbine burners for safe and clean combustion of H2-rich fuels.

CFD Analysis of Turbec T100 Combustor at Part Load by Varying Fuels

2015 ◽  
Author(s):  
Raffaela Calabria ◽  
Fabio Chiariello ◽  
Patrizio Massoli ◽  
Fabrizio Reale
Keyword(s):  
Natural Gas ◽  
Gas Turbines ◽  
Combustion Process ◽  
Calorific Value ◽  
Operating Conditions ◽  
Liquid Fuels ◽  
Cfd Analysis ◽  
Part Load ◽  
Gaseous Fuels ◽  
Wide Range

In recent years an increasing interest is focused on the study of micro gas turbines (MGT) behavior at part load by varying fuel, in order to determine their versatility. The interest in using MGT is related to the possibility of feeding with a wide range of fuels and to realize efficient cogenerative cycles by recovering heat from exhaust gases at higher temperatures. In this context, the studies on micro gas turbines are focused on the analysis of the machine versatility and flexibility, when operating conditions and fuels are significantly varied. In line of principle, in case of gaseous fuels with similar Wobbe Index no modifications to the combustion chamber should be required. The adoption of fuels whose properties differ greatly from those of design can require relevant modifications of the combustor, besides the proper adaptation of the feeding system. Thus, at low loads or low calorific value fuels, the combustor becomes a critical component of the entire MGT, as regards stability and emissions of the combustion process. Focus of the paper is a 3D CFD analysis of the combustor behavior of a Turbec T100P fueled at different loads and fuels. Differences between combustors designed for natural gas and liquid fuels are also highlighted. In case of natural gas, inlet combustor temperature and pressure were taken from experimental data; in case of different fuels, such data were inferred by using a thermodynamic model which takes into account rotating components behavior through operating maps of compressor and turbine. Specific aim of the work is to underline potentialities and critical issues of the combustor under study in case of adoption of fuels far from the design one and to suggest possible solutions.

scholarly journals Prediction of Auto-Ignition Temperatures and Delays for Gas Turbine Applications

2015 ◽  
Vol 138 (2) ◽  
Author(s):  
Roda Bounaceur ◽  
Pierre-Alexandre Glaude ◽  
Baptiste Sirjean ◽  
René Fournet ◽  
Pierre Montagne ◽  
...  
Keyword(s):  
High Temperature ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Equivalence Ratio ◽  
Process Conditions ◽  
Piping System ◽  
Gaseous Fuels ◽  
Auto Ignition ◽  
Wide Range

Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations, variable gas/air mixtures are involved in the gas piping system. In order to predict the risk of auto-ignition events and ensure a safe operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon–air mixtures at elevated pressures are scarce and often not applicable in specific industrial conditions. Auto-ignition temperature (AIT) data correspond to temperature ranges in which fuels display an incipient reactivity, with timescales amounting in seconds or even in minutes instead of milliseconds in flames. In these conditions, the critical reactions are most often different from the ones governing the reactivity in a flame or in high temperature ignition. Some of the critical paths for AIT are similar to those encountered in slow oxidation. Therefore, the main available kinetic models that have been developed for fast combustion are unfortunately unable to represent properly these low temperature processes. A numerical approach addressing the influence of process conditions on the minimum AIT of different fuel/air mixtures has been developed. Several chemical models available in the literature have been tested, in order to identify the most robust ones. Based on previous works of our group, a model has been developed, which offers a fair reconciliation between experimental and calculated AIT data through a wide range of fuel compositions. This model has been validated against experimental auto-ignition delay times corresponding to high temperature in order to ensure its relevance not only for AIT aspects but also for the reactivity of gaseous fuels over the wide range of gas turbine operation conditions. In addition, the AITs of methane, of pure light alkanes, and of various blends representative of several natural gas and process-derived fuels were extensively covered. In particular, among alternative gas turbine fuels, hydrogen-rich gases are called to play an increasing part in the future so that their ignition characteristics have been addressed with particular care. Natural gas enriched with hydrogen, and different syngas fuels have been studied. AIT values have been evaluated in function of the equivalence ratio and pressure. All the results obtained have been fitted by means of a practical mathematical expression. The overall study leads to a simple correlation of AIT versus equivalence ratio/pressure.

scholarly journals High Efficiency-Coal and Gas (HE-C&G): An Advanced Hybrid Power Plant Concept With Sequential Combustion Gas Turbines GT24/GT26

1997 ◽  
Author(s):  
Mircea Fetescu
Keyword(s):  
Power Plant ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
High Efficiency ◽  
Combustion Gas ◽  
Hybrid Power ◽  
Wide Range ◽  
Hybrid Power Plant ◽  
Very High

The High Efficiency-Coal and Gas (HE-C&G) is a hybrid power plant concept integrating Conventional Steam Power Plants (CSPP) and gas turbine / combined cycle plants. The gas turbine exhaust gas energy is recovered in the HRSG providing partial condensate and feedwater preheating and generating steam corresponding to the main boiler live steam conditions (second steam source for the ST). The concept, exhibiting very high design flexibility, integrates the high performance Sequential Combustion gas turbines GT24/GT26 technology into a wide range of existing or new CSPP. Although HE-C&G refers to coal as the most abundant fossil fuel resource, oil or natural gas fired steam plants could be also designed or converted following the same principle. The HE-C&G provides very high marginal efficiencies on natural gas, up to and above 60%, very high operating and dispatching flexibility and on-line optimization of fuel and O&M costs at low capital investment. This paper emphasizes the operating flexibility and resulting benefits, recommending the HE-C&G as one of the most profitable options for generating power especially for conversion of existing CSPP with gas turbines.

Flameholding Tendencies of Natural Gas and Hydrogen Flames at Gas Turbine Premixer Conditions

2014 ◽  
Author(s):  
Elliot Sullivan-Lewis ◽  
Vincent McDonell
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
High Efficiency ◽  
High Reliability ◽  
Elevated Pressure ◽  
Inlet Temperature ◽  
Increased Risk ◽  
Wide Range ◽  
Lean Premixed

Ground based gas turbines are responsible for generating a significant amount of electric power as well as providing mechanical power for a variety of applications. This is due to their high efficiency, high power density, high reliability, and ability to operate on a wide range of fuels. Due to increasingly stringent air quality requirements, stationary power gas turbines have moved to lean-premixed operation. Lean-premixed operation maintains low combustion temperatures for a given turbine inlet temperature, resulting in low NOx emissions while minimizing emissions of CO and hydrocarbons. In addition, to increase overall cycle efficiency, engines are being operated at higher pressure ratios and/or higher combustor inlet temperatures. Increasing combustor inlet temperatures and pressures in combination with lean-premixed operation leads to increased reactivity of the fuel/air mixture, leading to increased risk of potentially damaging flashback. Curtailing flashback on engines operated on hydrocarbon fuels requires care in design of the premixer. Curtailing flashback becomes more challenging when fuels with reactive components such as hydrogen are considered. Such fuels are gaining interest because they can be generated from both conventional and renewable sources and can be blended with natural gas as a means for storage of renewably generated hydrogen. The two main approaches for coping with flashback are either to design a combustor that is resistant to flashback, or to design one that will not anchor a flame if a flashback occurs. An experiment was constructed to determine the flameholding tendencies of various fuels on typical features found in premixer passage ways (spokes, steps, etc.) at conditions representative of a gas turbine premixer passage way. In the present work tests were conducted for natural gas and hydrogen between 3 and 9 atm, between 530 K and 650K, and free stream velocities from 40 to 100 m/s. Features considered in the present study include a spoke in the center of the channel and a step at the wall. The results are used in conjunction with existing blowoff correlations to evaluate flameholding propensity of these physical features over the range of conditions studied. The results illustrate that correlations that collapse data obtained at atmospheric pressure do not capture trends observed for spoke and wall step features at elevated pressure conditions. Also, a notable fuel compositional effect is observed.

A Comparative Analysis of Single Nozzle and Multiple Nozzles Arrangements for Syngas Combustion in Heavy Duty Gas Turbine

2016 ◽  
Vol 139 (2) ◽  
Author(s):  
Shi Liu ◽  
Hong Yin ◽  
Yan Xiong ◽  
Xiaoqing Xiao
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Combined Cycle ◽  
Heavy Duty ◽  
Gas Turbine Combustor ◽  
Integrated Gasification Combined Cycle ◽  
Wide Range ◽  
Heavy Duty Gas Turbine ◽  
Integrated Gasification

Heavy duty gas turbines are the core components in the integrated gasification combined cycle (IGCC) system. Different from the conventional fuel for gas turbine such as natural gas and light diesel, the combustible component acquired from the IGCC system is hydrogen-rich syngas fuel. It is important to modify the original gas turbine combustor or redesign a new combustor for syngas application since the fuel properties are featured with the wide range hydrogen and carbon monoxide mixture. First, one heavy duty gas turbine combustor which adopts natural gas and light diesel was selected as the original type. The redesign work mainly focused on the combustor head and nozzle arrangements. This paper investigated two feasible combustor arrangements for the syngas utilization including single nozzle and multiple nozzles. Numerical simulations are conducted to compare the flow field, temperature field, composition distributions, and overall performance of the two schemes. The obtained results show that the flow structure of the multiple nozzles scheme is better and the temperature distribution inside the combustor is more uniform, and the total pressure recovery is higher than the single nozzle scheme. Through the full scale test rig verification, the combustor redesign with multiple nozzles scheme is acceptable under middle and high pressure combustion test conditions. Besides, the numerical computations generally match with the experimental results.

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