Profiles and TEQ Concentrations of PAHs Emission From Fluidized Bed Coal Gasification

2005 ◽  
Author(s):  
Hongcang Zhou ◽  
Baosheng Jin ◽  
Zhaoping Zhong ◽  
Rui Xiao ◽  
Yaji Huang
Keyword(s):  
Fluidized Bed ◽  
High Performance ◽  
Coal Gasification ◽  
Steam Gasification ◽  
Test Facility ◽  
Fuel Gas ◽  
Coal Fuel ◽  
Polycyclic Aromatic ◽  
Coal Slag ◽  
Us Epa

More growing particular attentions are being paid to polycyclic aromatic hydrocarbons (PAHs) generated from coal gasification due to their high mutagenic and carcinogenic. Fluidized bed air and steam gasification of three different rank coals were studied in a bench-scale atmospheric fluidized bed test facility. An extraction and high performance liquid chromatography (HPLC) technique was used to analyze the concentrations of the 16 PAHs specified by US EPA in raw coal, slag, bag house char, cyclone char and fuel gas. The profiles and TEQ concentrations of PAHs emission from fluidized bed coal gasification were discussed. The results indicated that there were mainly three- and four-ringed PAHs in raw coal and fuel gas, but the total PAHs in bag house char and cyclone char were dominated by three-, four- and five-ringed PAHs. The concentrations of three-ringed PAHs in fuel gas were higher than those of four-ringed PAHs, but a reverse phenomenon occurred in bag house char and cyclone char. No PAHs were measured in slag during coal gasification. The total TEQ concentration of five-ringed PAHs mainly dominated in raw coal, fuel gas, bag house char, and cyclone char, and their percentages were about 75–96% by weight. Benzo(a)pyrene (BaP) was the main contributor of TEQ concentration in raw coal and gasified products. In addition, the concentration of PAHs in raw coal increased with the rise of coal rank, and there was not an obvious variation about the concentration of PAHs in gasified products.

Development of Gas Steam and Power Multi-Generation System

2005 ◽  
Author(s):  
Mengxiang Fang ◽  
Qinghui Wang ◽  
Chunjiang Yu ◽  
Zhenglun Shi ◽  
Zhongyang Luo ◽  
...  
Keyword(s):  
Fluidized Bed ◽  
Coal Gasification ◽  
Cool System ◽  
Test Facility ◽  
Circulation Rate ◽  
Generation System ◽  
Fuel Gas ◽  
Heating Value ◽  
Bed Temperature ◽  
High Efficient

A new system using combined coal gasification and combustion has been developed for clean and high efficient utilization of coal. The coal is first gasified by air/steam or recycle gas and the produced fuel gas is then used for industrial purpose or as a fuel for gas turbine. The char residue from the gasifier is burned in a circulating fluidized bed combustor to generate steam for power generation. A 1MW pilot plant test facility has been erected, which consists of a fluidized bed gasifier, a CFB combustor, flue gas and fuel gas clean and cool system, data acqisition and control system. The primary results show that the system can produce 12–14MJ/Nm3 middle heating value gas by using recycle gas or steam as gasification mediaand bed temperature and solid circulation rate are main parameters. On bases of this, a 25 MW gas steam and power multi-generation system has been designed. In this system, a fluidized bed gasifiers are combined with a 130t/h circulating bed boiler to realize gas and steam cogeneration. The system can produce 7800 M3/h gas with heating value 10–14 Mj/Nm3 and 25 MW Power.

scholarly journals Effect of Pressure on Second-Generation Pressurized Fluidized Bed Combustion Plants

1994 ◽  
Vol 116 (2) ◽  
pp. 345-351 ◽  
Author(s):  
A. Robertson ◽  
D. Bonk
Keyword(s):  
Gas Turbine ◽  
Fluidized Bed ◽  
Coal Gasification ◽  
Second Generation ◽  
Electrical Power ◽  
Fluidized Bed Combustion ◽  
Fuel Gas ◽  
Combustion Gas ◽  
New Type ◽  
Pressurized Fluidized Bed Combustion

In the search for a more efficient, less costly, and more environmentally responsible method for generating electrical power from coal, research and development has turned to advanced pressurized fluidized bed combustion (PFBC) and coal gasification technologies. A logical extension of this work is the second-generation PFBC plant, which incorporates key components of each of these technologies. In this new type of plant, coal is devolatilized/carbonized before it is injected into the PFB combustor bed, and the low-Btu fuel gas produced by this process is burned in a gas turbine topping combustor. By integrating coal carbonization with PFB coal/char combustion, gas turbine inlet temperatures higher than 1149°C (2100°F) can be achieved. The carbonizer, PFB combustor, and particulate-capturing hot gas cleanup systems operate at 871°C (1600°F), permitting sulfur capture by time-based sorbents and minimizing the release of coal contaminants to the gases. This paper presents the performance and economics of this new type of plant and provides a brief overview of the pilot plant test programs being conducted to support its development.

scholarly journals Effect of Pressure on Second-Generation Pressurized Fluidized Bed Combustion Plants

1993 ◽  
Author(s):  
Archie Robertson ◽  
Donald Bonk
Keyword(s):  
Gas Turbine ◽  
Fluidized Bed ◽  
Coal Gasification ◽  
Second Generation ◽  
Electrical Power ◽  
Fluidized Bed Combustion ◽  
Fuel Gas ◽  
Combustion Gas ◽  
New Type ◽  
Pressurized Fluidized Bed Combustion

In the search for a more efficient, less costly, and more environmentally responsible method for generating electrical power from coal, research and development has turned to advanced pressurized fluidized bed combustion (PFBC) and coal gasification technologies. A logical extension of this work is the second-generation PFBC plant, which incorporates key components of each of these technologies. In this new type of plant, coal is devolatilized/carbonized before it is injected into the PFB combustor bed, and the low-Btu fuel gas produced by this process is burned in a gas turbine topping combustor. By integrating coal carbonization with PFB coal/char combustion, gas turbine inlet temperatures higher than 1149°C (2100°F) can be achieved. The carbonizer, PFB combustor, and particulate-capturing hot gas cleanup systems operate at 871°C (1600°F), permitting sulfur capture by lime-based sorbents and minimizing the release of coal contaminants to the gases. This paper presents the performance and economics of this new type of plant and provides a brief overview of the pilot plant test programs being conducted to support its development.

scholarly journals Reduction of Polycyclic Aromatic Hydrocarbons (PAHs) in Sesame Oil Using Cellulosic Aerogel

Foods ◽  
2021 ◽  
Vol 10 (3) ◽  
pp. 644
Author(s):  
Do-Yeong Kim ◽  
Boram Kim ◽  
Han-Seung Shin
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
High Performance ◽  
Oil Quality ◽  
Acid Value ◽  
Quality Parameters ◽  
Sesame Oil ◽  
Miscanthus Sinensis ◽  
Polycyclic Aromatic ◽  
And Control

The effect of cellulosic aerogel treatments used for adsorption of four polycyclic aromatic hydrocarbons (PAHs)—benzo[a]anthracene, chrysene, benzo[b]fluoranthene, and benzo[a]pyrene [BaP])—generated during the manufacture of sesame oil was evaluated. In this study, eulalia (Miscanthus sinensis var. purpurascens)-based cellulosic aerogel (adsorbent) was prepared and used high performance liquid chromatography with fluorescence detection for determination of PAHs in sesame oil. In addition, changes in the sesame oil quality parameters (acid value, peroxide value, color, and fatty acid composition) following cellulosic aerogel treatment were also evaluated. The four PAHs and their total levels decreased in sesame oil samples roasted under different conditions (p < 0.05) following treatment with cellulosic aerogel. In particular, highly carcinogenic BaP was not detected after treatment with cellulosic aerogel. Moreover, there were no noticeable quality changes in the quality parameters between treated and control samples. It was concluded that eulalia-based cellulosic aerogel proved suitable for the reduction of PAHs from sesame oil and can be used as an eco-friendly adsorbent.

QuEChERS with ultrasound-assisted extraction combined with high-performance liquid chromatography for the determination of 16 polycyclic aromatic hydrocarbons in sediment

2021 ◽  
Author(s):  
Ling Wu ◽  
Qiurong He ◽  
Jing Zhang ◽  
Yongxin Li ◽  
Weiqing Yang ◽  
...  
Keyword(s):  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
Aromatic Hydrocarbons ◽  
High Performance ◽  
Ultrasound Assisted Extraction ◽  
Sediment Samples ◽  
Assisted Extraction ◽  
Polycyclic Aromatic ◽  
Ultrasound Assisted

Abstract Background Polycyclic aromatic hydrocarbons (PAHs) have attracted worldwide attention due to their carcinogenic, teratogenic and mutagenic effects, environmental persistence and bioaccumulation characteristics. Therefore, the sensitive, reliable and rapid detection of PAHs in sediment is of great importance. Objective To develop a high-performance liquid chromatography (HPLC) with fluorescence and ultraviolet detection after QuEChERS treatment for simultaneous determination of 16 U.S. Environmental Protection Agency priority PAHs in sediment samples. Methods The samples were ultrasonically extracted with acetone and then the supernatant was purified with a modified QuEChERS method. After centrifugation, the supernatant was injected into the HPLC system for analysis. The separation was accomplished on a ZORBAX Eclipse PAH column (150 × 4.6 mm, 3.5 μm) and the column temperature was set at 30 °C. The flow rate of the mobile phase consisting of water and acetonitrile in gradient elution mode was fixed at 0.9 mL/min. Detection was conducted on an ultraviolet detector and a fluorescence detector simultaneously. The qualitative analysis was based on retention time and the quantification was based on standard curves. Results Under the optimal conditions, this method showed good linearities in the range of 10–200 μg/L with correlation coefficients greater than 0.9993. The method had the limits of detection (LODs) ranging from 0.00108 to 0.314 ng/g. The mean recoveries ranged from 78.4 to 117% with the intra-day and inter-day relative standard deviations (RSDs) of 0.592–10.7 and 1.01–13.0%, respectively. The proposed method was successfully applied to the detection of 16 PAHs in sediment samples collected from the Funan River in Chengdu, China with the total contents of 431 to 2143 ng/g·dw. Conclusions The established method is simple, rapid, environment-friendly and cost- effective. It can be applied to the analysis of 16 PAHs in sediment samples. Highlights A method of QuEChERS with ultrasound-assisted extraction combined with HPLC has been established for the analysis of 16 PAHs in sediment samples and the proposed method has been successfully applied to the analysis PAHs in real sediment samples.

scholarly journals Grill Workers Exposure to Polycyclic Aromatic Hydrocarbons: Levels and Excretion Profiles of the Urinary Biomarkers

2020 ◽  
Vol 18 (1) ◽  
pp. 230
Author(s):  
Marta Oliveira ◽  
Sílvia Capelas ◽  
Cristina Delerue-Matos ◽  
Simone Morais
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
High Performance ◽  
Principal Component ◽  
Fold Increase ◽  
Urinary Biomarkers ◽  
Analysis Model ◽  
Exposed Workers ◽  
Polycyclic Aromatic ◽  
The Impact

Grilling activities release large amounts of hazardous pollutants, but information on restaurant grill workers’ exposure to polycyclic aromatic hydrocarbons (PAHs) is almost inexistent. This study assessed the impact of grilling emissions on total workers’ exposure to PAHs by evaluating the concentrations of six urinary biomarkers of exposure (OHPAHs): naphthalene, acenaphthene, fluorene, phenanthrene, pyrene, and benzo(a)pyrene. Individual levels and excretion profiles of urinary OHPAHs were determined during working and nonworking periods. Urinary OHPAHs were quantified by high-performance liquid-chromatography with fluorescence detection. Levels of total OHPAHs (∑OHPAHs) were significantly increased (about nine times; p ≤ 0.001) during working comparatively with nonworking days. Urinary 1-hydroxynaphthalene + 1-hydroxyacenapthene and 2-hydroxyfluorene presented the highest increments (ca. 23- and 6-fold increase, respectively), followed by 1-hydroxyphenanthrene (ca. 2.3 times) and 1-hydroxypyrene (ca. 1.8 times). Additionally, 1-hydroxypyrene levels were higher than the benchmark, 0.5 µmol/mol creatinine, in 5% of exposed workers. Moreover, 3-hydroxybenzo(a)pyrene, biomarker of exposure to carcinogenic PAHs, was detected in 13% of exposed workers. Individual excretion profiles showed a cumulative increase in ∑OHPAHs during consecutive working days. A principal component analysis model partially discriminated workers’ exposure during working and nonworking periods showing the impact of grilling activities. Urinary OHPAHs were increased in grill workers during working days.

scholarly journals Simultaneous Monitoring of Particle-Bound PAHs Inside a Low-Energy School Building and Outdoors over Two Weeks in France

Atmosphere ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 108
Author(s):  
Céline Liaud ◽  
Sarah Chouvenc ◽  
Stéphane Le Calvé
Keyword(s):  
Particle Size ◽  
Air Quality ◽  
High Performance ◽  
Sampling Period ◽  
Temporal Variations ◽  
Ventilation Rate ◽  
Low Energy ◽  
Total Particle ◽  
Polycyclic Aromatic ◽  
Individual Pahs

The emergence of new super-insulated buildings to reduce energy consumption can lead to a degradation of the indoor air quality. While some studies were carried out to assess the air quality in these super-insulated buildings, they were usually focused on the measurement of gas phase pollutants such as carbon dioxide and volatile organic compounds. This work reports the first measurements of Polycyclic Aromatic Hydrocarbons (PAHs) associated with particles as a function of time and particle size in a low-energy building. The airborne particles were collected indoors and outdoors over three to four days of sampling using two three-stage cascade impactors allowing to sample simultaneously particles with aerodynamic diameter Dae > 10 µm, 2.5 µm < Dae < 10 µm, 1 µm < Dae < 2.5 µm, and Dae < 1 µm. The 16 US-EPA priority PAHs were then extracted and quantified by high-performance liquid chromatography (HPLC) coupled to fluorescence detection. The resulting total particle concentrations were low, in the ranges 3.73 to 9.66 and 0.60 to 8.83 µg m-3 for indoors and outdoors, respectively. Thirteen PAHs were always detected in all the samples. The total PAH concentrations varied between 290 and 415 pg m−3 depending on the particle size, the environment (indoors or outdoors) and the sampling period considered. More interestingly, the temporal variations of individual PAHs highlighted that high molecular weight PAHs were mainly associated to the finest particles and some of them exhibited similar temporal behaviors, suggesting a common emission source. The indoor-to-outdoor concentration ratios of individual PAH were usually found close to or less than 1, except during the event combining rainy conditions and limited indoor ventilation rate.

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