Corrosion resistant metal-ceramic composite coatings for tribological applications

2021 ◽  
pp. 1-34
Author(s):  
Peter Renner ◽  
Swarn Jha ◽  
Yan Chen ◽  
Tariq Chagouri ◽  
Serge Kazadi ◽  
...  
Keyword(s):  
Ceramic Composite ◽  
Low Cost ◽  
Composite Coatings ◽  
Salt Spray ◽  
Extreme Environments ◽  
Safe Procedure ◽  
Corrosion Resistant ◽  
Wide Range ◽  
Metal Ceramic ◽  
Corrosion Resistant Coatings

Abstract Effective design of corrosion-resistant coatings is critical for the protection of metals and alloys. Many state-of-the-art corrosion-resistant coatings are unable to satisfy the challenges in extreme environments for tribological applications, such as elevated or cryogenic temperatures, high mechanical loads and impacts, severe wear, chemical attack, or a combination of these. The nature of challenging conditions demands that coatings have high corrosion and wear resistance, sustained friction control, and maintain surface integrity. In this research, multi-performance metal-ceramic composite coatings were developed for applications in harsh environments. These coatings were developed with an easy to fabricate, low-cost, and safe procedure. The coating consisted of boron nitride, graphite, silicon carbide, and transition metals such as chromium or nickel using epoxy as vehicle and bonding agent. Salt spray corrosion tests showed that 1010 carbon steel (1/4 hard temper) substrates lost 20-100× more mass than the coatings. The potentiodynamic polarization study showed better performance of the coatings by seven orders of magnitude in terms of corrosion relative to the substrate. Additionally, the corrosion rates of the coatings with Ni as an additive were five orders of magnitude lower than reported. The coefficient of friction of coatings was as low as 0.1, five to six times lower than that of epoxy and lower than a wide range of epoxy resin-based coatings found in literature. Coatings developed here exhibited potential in applications in challenging environments for tribological applications.

A Study on Mechanical and Tribological Properties of Hot Pressed Al2O3/ZrO2/h-BN/TiO2 Composites

2011 ◽  
Vol 695 ◽  
pp. 417-420 ◽  
Author(s):  
Hyun Hwi Lee ◽  
Seung Ho Kim ◽  
Bhupendra Joshi ◽  
Soo Wohn Lee
Keyword(s):  
Tribological Properties ◽  
Ceramic Composite ◽  
Elevated Temperatures ◽  
Cutting Tools ◽  
High Hardness ◽  
High Melting Point ◽  
Corrosion Resistant ◽  
Mechanical And Tribological Properties ◽  
Chemical Inertness ◽  
Corrosion Resistant Coatings

Oxide ceramics such as alumina and zirconia are industrially utilized as cutting tools, a variety of bearings, biomaterials, and thermal and corrosion-resistant coatings due to their high hardness, chemical inertness, high melting point, and ability to retain mechanical strength at elevated temperatures. In this research, the effect of other ceramic additives (TiO2) and h-BN within alumina(α-Al2O3) and yttria-stabilized tetragonal (Y-TZP) composite was studied with respect to the mechanical and tribological properties. The lowest coefficient of frction of 0.45 was observed for the ZTA ceramic composite with hBN-TiO2. The highest hardness, fracture toughness and flexural strength were obtained as 15.7GPa, 5.2MPam-1/2, 712MPa, respectively.

Development of Metal-Ceramic-Lubricant Composite Coatings Obtained by Cold Spray for Tribological Applications in the Automotive Industry

2021 ◽  
Author(s):  
G. Garcin ◽  
F. Delloro ◽  
M. Jeandin ◽  
J-F. Hochepied ◽  
C. Grente ◽  
...  
Keyword(s):  
Automotive Industry ◽  
Composite Coatings ◽  
Solid Lubricants ◽  
Friction Reduction ◽  
Hard Particles ◽  
Wide Range ◽  
Metal Ceramic ◽  
Coating Microstructure ◽  
Steel Substrates ◽  
The Relationship

Abstract One of the main levers to reduce CO2 emissions in cars and trucks is mass and friction reduction, which is often achieved through the use of special coatings. The aim of the present work was to develop metal-ceramic-lubricant composite coatings with the best combination of wear, seizure, fatigue, and thermal resistance. Metal-based coatings incorporating hard particles and solid lubricants were cold sprayed onto steel substrates and the relationship between coating microstructure and tribology was studied. To meet the demanding tribological requirements of heavily loaded engines, the interfaces between the different components were optimized by selecting appropriate feedstock powders and assessing a wide range of process parameters. Alumina-reinforced bronze composite coatings were made from powders with different morphologies. Aggregated ceramic powders were found to be more beneficial in terms of wear than massive powders, and graphite was found to be effective for reducing seizure.

Corrosion Resistant Coatings Based on Zinc Nanoparticles, Epoxy and Silicone Resins

2020 ◽  
Vol 20 (10) ◽  
pp. 6389-6395 ◽  
Author(s):  
Chuan-Chun Li ◽  
Tang-Yu Lai ◽  
Te-Hua Fang
Keyword(s):  
Electron Microscope ◽  
Epoxy Resin ◽  
Steel Substrate ◽  
Composite Coatings ◽  
Salt Spray ◽  
Nano Composites ◽  
Silicone Resin ◽  
Nano Composite ◽  
Corrosion Resistant ◽  
Zn Nanoparticles

In this study, corrosion-resistant composite coatings were produced by incorporating zinc (Zn) nanoparticles in an epoxy resin and a hybrid silicone resin. While performing sodium chloride saltspray tests, the corrosion performance of the nano-composite coatings was evaluated by applying these corrosion-resistant composite coatings on a carbon steel substrate. The nano-composite coatings on the substrates were characterized by an adhesion test, scanning electron microscope (SEM), and transmission electron microscope (TEM) with energy-dispersive X-ray spectroscopy (EDX). The results of the salt-spray tests showed that the Zn nanoparticles in the epoxy and hybrid silicone resins could react with permeated oxygen, thereby improving the anticorrosion properties of the Zn nano-composites. The corroded area of the epoxy resin samples decreased from more than 80% without Zn doping to less than 5% in a 3000-ppm Zn-doped sample after a 500-h saltspray test. An evaluation of the bactericidal properties showed that the Zn/epoxy and Zn/hybrid silicone resin nano-composites with at least 360 ppm of Zn nanoparticles exhibited bactericidal ability, which remarkably increased with the Zn nanoparticles content. The corrosion-resistant properties improved with the addition of Zn nano-composites coatings.

scholarly journals Study on Corrosion Resistance and Wear Resistance of Zn–Al–Mg/ZnO Composite Coating Prepared by Cold Spraying

Coatings ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 505
Author(s):  
Xinqiang Lu ◽  
Shouren Wang ◽  
Tianying Xiong ◽  
Daosheng Wen ◽  
Gaoqi Wang ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Composite Coatings ◽  
Salt Spray ◽  
Cold Spraying ◽  
Neutral Salt ◽  
Corrosion Resistant ◽  
Electrochemical Tests ◽  
Long Term Stability ◽  
Spray Technique

Two composite coatings, Zn65Al15Mg5ZnO15 and Zn45Al35Mg5ZnO15, were prepared by the cold spray technique and were found to be compact, with no pits or cracks, based on scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDS) investigations. The results of the neutral salt spray (NSS) and electrochemical tests showed that the two composite coatings possess a suitable corrosion performance. However, the Zn45Al35Mg5ZnO15 composite coatings were more corrosion resistant and allowed a better long-term stability. In addition, they were found to exhibit the best wear resistance and photocatalytic degradation efficiency.

On the Elaboration of Metal-Ceramic Composite Coatings by Laser Cladding

2016 ◽  
Vol 879 ◽  
pp. 1288-1293 ◽  
Author(s):  
Anne Mertens ◽  
Thibaut L’Hoest ◽  
Julien Magnien ◽  
Raoul Carrus ◽  
Jacqueline Lecomte-Beckers
Keyword(s):  
Mechanical Properties ◽  
Laser Cladding ◽  
Ceramic Composite ◽  
Composite Coatings ◽  
Preliminary Investigation ◽  
Metallic Matrix ◽  
Stainless Steel 316L ◽  
Additive Process ◽  
Silicon Carbides ◽  
Metal Ceramic

This paper reports on a preliminary investigation into the elaboration, by the additive process known as laser cladding, of composite coatings with a matrix of stainless steel 316L reinforced with varying contents of tungsten (WC) or silicon carbides (SiC) particles. Laser cladding is characterised by ultra-fast solidification and cooling rates, thus giving rise to ultra-fine out-of-equilibrium microstructures and potentially enhanced mechanical properties. Both types of composite coatings – i.e. with SiC or WC ‒ are compared in terms of their microstructures and hardness. Special attention is given to the dissolution of the carbides particles and to interfacial reactions taking place between the particles and the metallic matrix.

Preparation of Metal-Gr Composite Coatings via Electro-Plating for High Performances: A Review

MRS Advances ◽  
2019 ◽  
Vol 4 (35) ◽  
pp. 1913-1928
Author(s):  
Sishi Li ◽  
Yanpeng Yang ◽  
Gongsheng Song ◽  
Qiang Fu ◽  
Chunxu Pan
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Large Scale ◽  
Low Cost ◽  
Composite Coatings ◽  
Scale Production ◽  
Electro Deposition ◽  
Wide Range ◽  
Set Up ◽  
Wear And Corrosion Resistance

ABSTRACTDeveloping metal-based composite coatings with improved mechanical properties and good corrosion resistance has been an attractive research topic in recent years. Graphene (Gr), as a new type of two-dimensional (2D) carbon nanomaterial with excellent physical, chemical and mechanical properties, can be used as a reinforcement to improve hardness, tensile strength, wear and corrosion resistance of metal-based composites. There have been substantial efforts focused on the fabrication of metal-Gr composite coatings via various approaches. Electro-deposition is an effective electrochemical method with wide range of advantages, such as a fast deposition rate, simple set-up with large scale production and relatively low cost. This overview covers the previous research and development studies on metal-Gr composite coatings using electro-deposition method and the resulting properties. In addition, recent work in this area which provides a developed process with industrial production perspective, is discussed.

Hot Corrosion of NiCrAlY/(ZrO2-CeO2-Y2O3) Composite Coatings in NaCl-Na2SO4 Molten Salt

2010 ◽  
Vol 658 ◽  
pp. 228-231 ◽  
Author(s):  
Jae Ho Lee ◽  
Dong Bok Lee
Keyword(s):  
Corrosion Resistance ◽  
Molten Salt ◽  
Hot Corrosion ◽  
Ceramic Composite ◽  
Composite Coatings ◽  
Air Plasma Spray ◽  
Air Plasma ◽  
Coating Surface ◽  
Metal Ceramic ◽  
Sprayed Coatings

The metal/ceramic composite coatings that consisted of (Ni-22Cr-10Al-1Y) and (ZrO2-25CeO2-2.5Y2O3) were prepared by the air plasma spray (APS) method. The as-sprayed coatings consisted of metal-rich and ceramic-rich regions, between which the -Al2O3 oxide stringers existed owing to the oxidation of Al in (Ni-22Cr-10Al-1Y) during APS. The composite coatings were hot corroded at 800 and 900 oC for up to 50 h in 75%NaCl-25%Na2SO4 molten salt. The corrosion products that formed on the coating surface during hot corrosion were mostly dissolved off into the molten salt. The scales that remained on the coating surface consisted primarily of Cr2O3, and a lesser amount of NiO and Al2O3. The corrosion resistance decreased, as not only the test temperature and time but also the amount of metal in the coating increased.

Developing technology of fabrication of functional nanostructured coatings on wear- and corrosion-resistant alloy based on the Cu–Ni system

2019 ◽  
pp. 70-75
Author(s):  
A. M. Makarov ◽  
A. V. Kosulnikova ◽  
T. I. Bobkova ◽  
A. F. Vasiliev ◽  
D. A. Geraschenkov ◽  
...  
Keyword(s):  
Steel Substrate ◽  
Alloy System ◽  
Corrosion Resistant ◽  
Wear And Corrosion ◽  
Wide Range ◽  
Corrosion Resistant Alloy ◽  
Resistance To Stress ◽  
Corrosion Resistant Coatings ◽  
Substrate Steel ◽  
Deposition Techniques

The paper presents complex studies of nanostructured powder of Cu-Hf-BN alloy system and functional wear and corrosion-resistant coatings based on It are presented. A technology for applying a composite nanostructured coating of the Cu-Ni-Zr-Cr-Hf-BN system onto a steel substrate (steel Kh18Yu5S) was developed using supersonic cold and microplasma deposition techniques. The coatings have elevated level of microhardness (up to 32 GPa), adhesive strength (more than13 MPa), resistance to stress-corrosion crackingand a wide range of operating temperatures from 850 to –196°C.

In situ formation of metal-ceramic composite coatings by detonation spraying of titanium

2014 ◽  
Author(s):  
V. Yu. Ulianitsky ◽  
D. V. Dudina ◽  
I. S. Batraev ◽  
N. V. Bulina ◽  
A. I. Kovalenko ◽  
...  
Keyword(s):  
Ceramic Composite ◽  
Composite Coatings ◽  
Detonation Spraying ◽  
Metal Ceramic ◽  
In Situ Formation
Sign in / Sign up

Export Citation Format

Share Document