Aging and Fatigue of Aerosol Jet-Printed Nano-Ag Traces on Flexible Substrate

2020 ◽  
Vol 143 (2) ◽  
Author(s):  
Arun Raj ◽  
Rajesh Sharma Sivasubramony ◽  
Manu Yadav ◽  
Sanoop Thekkut ◽  
Gurvinder Singh Khinda ◽  
...  
Keyword(s):  
Fatigue Resistance ◽  
Selection Process ◽  
Flexible Substrate ◽  
Accelerated Aging ◽  
Organic Matrix ◽  
Subsequent Aging ◽  
Long Term Storage ◽  
Order Of Magnitude ◽  
Sintering Conditions ◽  
The Stability

Abstract Conducting traces on a flexible substrate often have to survive significant and repeated deformation, making their fatigue resistance and the stability of it during long-term storage and use a potential concern. The question of stability is obvious in the case of, for example, screen or ink jet-printed traces where the organic matrix remains a critical part of the structure. We show it also to be important for nano-Ag traces that are sintered to ensure metallic bonding between the particles while eliminating most of the organics. We also show conventional accelerated aging tests to be potentially confusing or misleading for such traces, depending among other on practical limitations on sintering conditions. Examples are presented of how the fatigue resistance of application relevant aerosol jet-printed nano-Ag traces may degrade relatively rapidly at moderate temperatures. Even after “optimized” sintering at a much higher temperature subsequent aging at 75 °C for only 100 h led to an order of magnitude reduction in the fatigue life in subsequent mild cycling. The rate of degradation is certain to vary with the design and the ink used as well as with sintering conditions, making it important to account for it all in materials selection, process optimization, and assessments of practical life.

Electrical Failure and Damage Analysis of Multi-Layer Metal Films on Flexible Substrate during Cyclic Bending Deformation

2011 ◽  
Author(s):  
Byoung-Joon Kim ◽  
Hae-A-Seul Shin ◽  
In-Suk Choi ◽  
Young-Chang Joo
Keyword(s):  
Fatigue Resistance ◽  
Electrical Resistance ◽  
Metal Film ◽  
Flexible Substrate ◽  
Resistance Change ◽  
Cyclic Bending ◽  
Capping Layer ◽  
Bending Strain ◽  
Cu Film ◽  
Electrical Resistance Change

Abstract The electrical resistance Cu film on flexible substrate was investigated in cyclic bending deformation. The electrical resistance of 1 µm thick Cu film on flexible substrate increased up to 120 % after 500,000 cycles in 1.1 % tensile bending strain. Crack and extrusion were observed due to the fatigue damage of metal film. Low bending strain did not cause any damage on metal film but higher bending strain resulted in severe electrical and mechanical damage. Thinner film showed higher fatigue resistance because of the better mechanical property of thin film. Cu film with NiCr under-layer showed poorer fatigue resistance in tensile bending mode. Ni capping layer did not improve the fatigue resistance of Cu film, but Al capping layer suppressed crack formation and lowered electrical resistance change. The NiCr under layer, Ni capping layer, and Al capping layer effect on electrical resistance change of Cu film was compared with Cu only sample.

Electrolysis soy protein isolate-based oleogels prepared with an emulsion-templated approach

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Dianyu Yu ◽  
Yan Chen ◽  
Xing Chen ◽  
Yunyan Huang ◽  
Liqi Wang ◽  
...  
Keyword(s):  
Soy Protein ◽  
Xanthan Gum ◽  
Binding Capacity ◽  
Soy Protein Isolate ◽  
Single Layer ◽  
Protein Isolate ◽  
Regulatory Limits ◽  
Order Of Magnitude ◽  
The Stability ◽  
Oil Binding

Abstract This research focuses on the use of protein-polyphenol complex and protein-polyphenol: polysaccharide complexes to prepare oleogels through an emulsion-templated approach. Electrolysis soy protein isolate (ESPI) could be effectively adsorbed on the surface of a single-layer emulsion to increase the particle size. The order of the negative charges of the emulsion after adding polysaccharides was xanthan gum (XG)> pectin> carboxymethyl cellulose (CMC). Rheological behavior showed that the stability of the double-layer emulsions increased, and the viscoelasticity increased around one order of magnitude with the addition of polysaccharides. The oil binding capacity (OBC) of the oleogel prepared by adding polysaccharides increased to more than 97%. The peroxide value (PV) and anisidine value (AV) of XG oleogel were the minimum values in all samples. The AV and POV were within the regulatory limits of China after storage for 21 days. This provides a reference to design of ESPI-based oleogel for different applications.

scholarly journals Stability of Glucose Concentrations in Frozen Plasma

2020 ◽  
pp. 193229682096365
Author(s):  
Stefan Pleus ◽  
Guido Freckmann ◽  
Annette Baumstark ◽  
Cornelia Haug
Keyword(s):  
Venous Blood ◽  
Relative Difference ◽  
Plasma Samples ◽  
Conflicting Information ◽  
Long Term Storage ◽  
The Stability ◽  
Relative Differences ◽  
Frozen Plasma ◽  
Laboratory Analyzer

Background: Conflicting information is available regarding the stability of glucose concentrations in frozen plasma samples. Clinical trials could benefit from such long-term storage because it would allow usage of a central laboratory with higher-quality laboratory analyzers in contrast to mobile analyzers in a decentralized setting. Methods: In this study, venous blood samples were collected in lithium-heparin gel tubes. Plasma was separated immediately after blood was drawn, and from each of the 21 plasma samples, 6 aliquots were prepared for measurement at 6 time points: immediately and after 2, 4, 6, 8, and 12 weeks. Between sampling and measurement, aliquots were stored at less than −20°C. Transport on dry ice was simulated by placing aliquots in a −80°C freezer for 5 days between weeks 8 and 12. Measurements were performed on a hexokinase-based laboratory analyzer. Average relative differences and corresponding 99% confidence intervals (CIs) were calculated between the stored aliquots’ and the immediately measured aliquots’ glucose concentrations. Glucose concentrations were deemed stable as long as average relative differences were ≤±2.5%. Results: Over the whole 12-weeks duration, the largest average relative difference was −1.82% (99% CI: –2.25% to −1.39%). Shorter storage durations tended to lead to less bias. Conclusion: In this study, the stability of glucose concentrations in frozen plasma samples obtained with lithium-heparin gel tubes could be shown for up to 12 weeks. Future studies should be performed to assess whether this is independent of the glucose analyzer and the type of sampling tube used.

scholarly journals Regulation of accretion by its outflow in a symbiotic star: the 2016 outflow fast state of MWC 560

2020 ◽  
Vol 492 (3) ◽  
pp. 3107-3127 ◽  
Author(s):  
Adrian B Lucy ◽  
J L Sokoloski ◽  
U Munari ◽  
Nirupam Roy ◽  
N Paul M Kuin ◽  
...  
Keyword(s):  
Symbiotic Star ◽  
Fast State ◽  
Low Velocity ◽  
X Ray ◽  
Broad Absorption Line ◽  
Multi Wavelength ◽  
Order Of Magnitude ◽  
The Stability ◽  
Ultraviolet Observations ◽  
Optical Flux

ABSTRACT How are accretion discs affected by their outflows? To address this question for white dwarfs accreting from cool giants, we performed optical, radio, X-ray, and ultraviolet observations of the outflow-driving symbiotic star MWC 560 (≡V694 Mon) during its 2016 optical high state. We tracked multi-wavelength changes that signalled an abrupt increase in outflow power at the initiation of a months-long outflow fast state, just as the optical flux peaked: (1) an abrupt doubling of Balmer absorption velocities; (2) the onset of a 20 μJy per month increase in radio flux; and (3) an order-of-magnitude increase in soft X-ray flux. Juxtaposing to prior X-ray observations and their coeval optical spectra, we infer that both high-velocity and low-velocity optical outflow components must be simultaneously present to yield a large soft X-ray flux, which may originate in shocks where these fast and slow absorbers collide. Our optical and ultraviolet spectra indicate that the broad absorption-line gas was fast, stable, and dense (≳106.5  cm−3) throughout the 2016 outflow fast state, steadily feeding a lower density (≲105.5 cm−3) region of radio-emitting gas. Persistent optical and ultraviolet flickering indicate that the accretion disc remained intact. The stability of these properties in 2016 contrasts to their instability during MWC 560’s 1990 outburst, even though the disc reached a similar accretion rate. We propose that the self-regulatory effect of a steady fast outflow from the disc in 2016 prevented a catastrophic ejection of the inner disc. This behaviour in a symbiotic binary resembles disc/outflow relationships governing accretion state changes in X-ray binaries.

scholarly journals Effect of H2O on the Pressure-Induced Amorphization of Hydrated AlPO4-17

Molecules ◽  
2019 ◽  
Vol 24 (16) ◽  
pp. 2864 ◽  
Author(s):  
Frederico G. Alabarse ◽  
Boby Joseph ◽  
Andrea Lausi ◽  
Julien Haines
Keyword(s):  
Pressure Range ◽  
Silicone Oil ◽  
Structural Response ◽  
Microporous Material ◽  
X Ray ◽  
Guest Species ◽  
Order Of Magnitude ◽  
Diamond Anvil ◽  
The Stability

The incorporation of guest species in zeolites has been found to strongly modify their mechanical behavior and their stability with respect to amorphization at high pressure (HP). Here we report the strong effect of H2O on the pressure-induced amorphization (PIA) in hydrated AlPO4-17. The material was investigated in-situ at HP by synchrotron X-ray powder diffraction in diamond anvil cells by using non- and penetrating pressure transmitting media (PTM), respectively, silicone oil and H2O. Surprisingly, in non-penetrating PTM, its structural response to pressure was similar to its anhydrous phase at lower pressures up to ~1.4 GPa, when the amorphization was observed to start. Compression of the structure of AlPO4-17 is reduced by an order of magnitude when the material is compressed in H2O, in which amorphization begins in a similar pressure range as in non-penetrating PTM. The complete and irreversible amorphization was observed at ~9.0 and ~18.7 GPa, respectively, in non- and penetrating PTM. The present results show that the insertion of guest species can be used to strongly modify the stability of microporous material with respect to PIA, by up to an order of magnitude.

Formulation of “Stability Equations” and Derivation of New Constructions with Complete Systems of Design-formulae for Variable-speed Control Mechanisms

1953 ◽  
Vol 167 (1) ◽  
pp. 319-339
Author(s):  
M. S. Frenkel
Keyword(s):  
Nuclear Physics ◽  
Characteristic Curve ◽  
Mathematical Formulation ◽  
Control Mechanisms ◽  
Variable Speed ◽  
Speed Governor ◽  
Minimum Number ◽  
Order Of Magnitude ◽  
The Stability ◽  
Stable Characteristic

Requirements for stability are formulated mathematically and, through the “transformatory operations of mathematics”, yield a series of “stability equations” of ascending order which are generally applicable, for example to control mechanisms, electronics†, nuclear physics, etc. From these stability equations, the equation of the stable characteristic curve of a governor, and the differential equations of the oscillations of a governor-engine system, are derived. It emerges that the first part of the new oscillatory equation is identical with the whole of the differential equation in the literature to date (unchanged since Maxwell 1868)‡, while the important second part, which consists of terms of the same order of magnitude as the first part and which is the only one containing the equation of the stable characteristic curve, is lacking in literature. The stability equations classify all possible constructions of variable-speed governor according to “order of stability”, which signifies important operating properties. This classification accounts for the known shortcomings of conventional types. The stability equations, combined with the mathematical formulation of practical requirements (speed-adjustment with only one actuating motion, etc.), lead to new basic types of variable-speed governor, with complete systems of design equations. In addition to determining all unknown dimensions, this set of equations is important because it derives constructions of which the complexity increases with order of stability and, furthermore, a simple construction which provides any required high order of stability with the minimum number of adjustable components.

Stabilizing effect of surrounding gas flow on a plane liquid sheet

2011 ◽  
Vol 672 ◽  
pp. 5-32 ◽  
Author(s):  
OUTI TAMMISOLA ◽  
ATSUSHI SASAKI ◽  
FREDRIK LUNDELL ◽  
MASAHARU MATSUBARA ◽  
L. DANIEL SÖDERBERG
Keyword(s):  
Growth Rate ◽  
Gas Flow ◽  
Liquid Velocity ◽  
Air Flow ◽  
Liquid Sheet ◽  
Mean Velocity ◽  
Order Of Magnitude ◽  
The Stability ◽  
The Waves ◽  
Half Thickness

The stability of a plane liquid sheet is studied experimentally and theoretically, with an emphasis on the effect of the surrounding gas. Co-blowing with a gas velocity of the same order of magnitude as the liquid velocity is studied, in order to quantify its effect on the stability of the sheet. Experimental results are obtained for a water sheet in air at Reynolds number Rel = 3000 and Weber number We = 300, based on the half-thickness of the sheet at the inlet, water mean velocity at the inlet, the surface tension between water and air and water density and viscosity. The sheet is excited with different frequencies at the inlet and the growth of the waves in the streamwise direction is measured. The growth rate curves of the disturbances for all air flow velocities under study are found to be within 20% of the values obtained from a local spatial stability analysis, where water and air viscosities are taken into account, while previous results from literature assuming inviscid air overpredict the most unstable wavelength with a factor 3 and the growth rate with a factor 2. The effect of the air flow on the stability of the sheet is scrutinized numerically and it is concluded that the predicted disturbance growth scales with (i) the absolute velocity difference between water and air (inviscid effect) and (ii) the square root of the shear from air on the water surface (viscous effect).

Stability and epimerisation behaviour of ergot alkaloids in various solvents

2008 ◽  
Vol 1 (1) ◽  
pp. 67-78 ◽  
Author(s):  
M. Hafner ◽  
M. Sulyok ◽  
R. Schuhmacher ◽  
C. Crews ◽  
R. Krska
Keyword(s):  
Degradation Products ◽  
Ergot Alkaloids ◽  
Carbonate Buffer ◽  
Long Term Storage ◽  
No Formation ◽  
Temperature Levels ◽  
The Stability ◽  
Extraction Mixture ◽  
Term Storage

In this paper the stability and degree of epimerisation of six major ergot alkaloids at three different temperature levels (-20 °C, +4 °C and +20 °C) over periods of 18 hours and six weeks is reported for the first time. The behaviour of ergometrine, ergocornine, ergocristine, α-ergocryptine, ergosine and ergotamine was thoroughly studied in seven solvents which are employed for the preparation of calibrants and extraction mixtures, respectively. Moreover, the stability of the ergot alkaloids was tested in different cereal extracts (rye, wheat, barley, oats) for 1, 2 and 6 days. Of the toxins tested, the ergopeptide-type toxins ergosine, ergotamine, ergocornine, α-ergocryptine and ergocristine showed similar behaviour patterns. The simple lysergic acid derivative ergometrine was more stable and showed hardly any epimerisation to ergometrinine, with the sum of both epimers remaining constant in all seven solvents. The ergopeptides tested show variable epimerisation tendencies, and were also less stable during six weeks at 20 °C. Ergosine showed the highest degree of epimerisation (43% after 6 weeks at 20 °C). In general, the order of epimerisation promotion was methanol/dichloromethane > acetonitrile/buffer > extraction mix > stabilising solution > acetonitrile >> chloroform. Long-term storage at room temperature can only be carried out in chloroform, which showed no epimerisation for all toxins even at 20 °C and also kept the sum of R and S forms constant, which indicates no formation of aci-epimers or other degradation products. Long-term storage of ergot alkaloids in acetonitrile, the most convenient solvent with respect to HPLC analysis, should be carried out at temperatures of -20 °C or below. The constant epimer ratio of all ergot alkaloids in the extraction mixture acetonitrile/ammonium carbonate buffer (200 mg/l; 92:8, v/v) during an HPLC run (18 hours) demonstrates the stability of the toxins in this extraction mixture.

The Carbonate-Hardening Lime Construction Material Properties Formation during their Long-Term Storage and Use under Normal Conditions

2019 ◽  
Vol 974 ◽  
pp. 187-194 ◽  
Author(s):  
Nikolay V. Lyubomirskiy ◽  
Tamara A. Bakhtina ◽  
Alexander S. Bakhtin ◽  
Sergey I. Fedorkin
Keyword(s):  
Construction Material ◽  
Construction Materials ◽  
Materials Properties ◽  
Long Term Storage ◽  
Efficiency Assessment ◽  
The Stability ◽  
Term Storage ◽  
Long Storage ◽  
Quality Construction

This paper presents the lime binding forced carbonate-hardening materials properties formation study and determins the stability of these properties during long-term storage and use under normal conditions. The tests showed these materials stability properties over time, confirming the strength and density growth of the test samples after long storage due to the calcium hydroxide recrystallization completion into calcium carbonate processes. Also, the results of the samples carbonate hardening study under natural conditions during 18 months are presented. An efficiency assessment of forced carbonate hardening as one of the methods of recycling technogenic CO2 in order to reduce its emissions in the atmosphere, and, in the result, to obtain high-quality construction materials has been made.

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