Development of Low-Drift Nickel-Based Thermocouples for High-Temperature Applications

Author(s):  
Michele Scervini

Recent progress on the new nickel-based thermocouples for high-temperature applications developed at the Department of Materials Science and Metallurgy in the University of Cambridge is described in this paper. Isothermal drift at temperatures above 1000 °C as a function of the thermocouple diameter has been studied for both conventional nickel-based thermocouples and the new nickel-based thermocouple. The new nickel-based thermocouple experiences a much reduced drift compared to conventional sensors. Tests in thermal cyclic conditions have been undertaken on conventional and new nickel-based thermocouples, showing a clear improvement for the new sensors at temperatures both higher and lower than 1000 °C. The improvements achievable with the new nickel-based thermocouple in both isothermal and thermal cycling conditions suggest that the new sensor can be used at high temperatures, where current conventional sensors are not reliable, as well as at temperatures lower than 1000 °C with improved performance compared to the conventional sensors.

Author(s):  
Michele Scervini

Recent progresses on the new Nickel based thermocouples for high temperature applications developed at the Department of Materials Science and Metallurgy of the University of Cambridge are described in this paper. Isothermal drift at temperatures above 1000°C as a function of the thermocouple diameter has been studied for both conventional Nickel based thermocouples and the new Nickel based thermocouple. The new Nickel based thermocouple experiences a much reduced drift compared to conventional sensors. Tests in thermal cyclic conditions have been undertaken on conventional and new Nickel based thermocouples, showing a clear improvement for the new sensors at temperatures both higher and lower than 1000°C. The improvements achievable with the new Nickel based thermocouple in both isothermal and thermal cycling conditions suggest that the new sensor can be used at high temperatures, where current conventional sensors are not reliable, as well as at temperatures lower than 1000°C with improved performance compared to conventional sensors.


Author(s):  
Michele Scervini ◽  
Catherine Rae

A new Nickel based thermocouple for high temperature applications in gas turbines has been devised at the Department of Material Science and Metallurgy of the University of Cambridge. This paper describes the new features of the thermocouple, the drift tests on the first prototype and compares the behaviour of the new sensor with conventional mineral insulated metal sheathed Type K thermocouples: the new thermocouple has a significant improvement in terms of drift and temperature capabilities. Metallurgical analysis has been undertaken on selected sections of the thermocouples exposed at high temperatures which rationalises the reduced drift of the new sensor. A second prototype will be tested in follow-on research, from which further improvements in drift and temperature capabilities are expected.


2009 ◽  
Vol 81 (2) ◽  
pp. 299-338 ◽  
Author(s):  
Giovanni Balducci ◽  
Andrea Ciccioli ◽  
Giovanni de Maria ◽  
Fiqiri Hoda ◽  
Gerd M. Rosenblatt

Over the last four to five decades, high-temperature materials chemistry (HTMC) has become a flourishing area of scientific and applied research, spurred by both a growing demand for new inorganic materials (e.g., oxide and non-oxide modern multifunctional ceramics, intermetallics, and oxidation-resistant alloys) able to withstand extreme thermal and chemical environments and by the recognition that chemical and physical behavior at high temperatures differs from, and cannot be extrapolated from, behavior at temperatures near room temperature. Despite the important role played by HTMC in modern advanced technology and the fundamental differences in behavior encountered at high temperatures, HTMC topics are rarely covered in chemistry and materials science programs at the university level because of a lack of readily accessible resource material - no textbook exists specifically devoted to HTMC topics. IUPAC's Inorganic Chemistry Division sponsored a project to address this gap, resulting in the present report. The report includes an introduction and seven sections covering historical background, chemical behavior of condensed-phase/gas-phase systems at high temperature, basic concepts of materials thermodynamics, experimental techniques, use of thermodynamic data and modeling, vaporization, and decomposition processes, and gas-solid reactions. The ninth section covers more specific topics, primarily concerning applications of high-temperature materials and processes. Each recommended topic is accompanied by a bibliography of helpful references, a short introduction or explanation including the areas of application, and some relevant teaching suggestions. An extensive annotated resource bibliography is an Appendix to the report available as supplementary material.


2014 ◽  
Vol 25 (2) ◽  
pp. 253
Author(s):  
Neil R. Avery ◽  
W. Roy Jackson ◽  
Thomas H. Spurling

John Anderson was born in Sydney on 5 March 1928 and died in Melbourne on 26 February 2007. He was educated at Sydney Boys' High School, Sydney Technical College, the New South Wales University of Technology (now the University of New South Wales) and the University of Cambridge. He was at Queens University Belfast as a Ramsay Memorial Fellow, 1954–5, was a Lecturer in Chemistry at the New South Wales University of Technology, a Reader in Chemistry at the University of Melbourne and Foundation Professor of Chemistry at Flinders University in South Australia. In 1969 he was appointed Chief of the CSIRO Division of Tribophysics and managed the Division's transition to become the Division of Materials Science. He was a Professor of Chemistry at Monash University, Melbourne, from 1987 until his retirement in 1993. He will be remembered for his contributions to the understanding of gas–solid interactions with particular emphasis on fundamental heterogeneous catalysis on metals, but also embracing other adsorption and oxidation processes.


2010 ◽  
Vol 436 ◽  
pp. 13-25 ◽  
Author(s):  
Carsten Schwandt ◽  
Greg R. Doughty ◽  
Derek J. Fray

The FFC-Cambridge process is a molten salt electrochemical deoxidation method that was invented at the Department of Materials Science and Metallurgy of the University of Cambridge one decade ago. It is a generic technology that allows the direct conversion of metal oxides into the corresponding metals through cathodic polarisation of the oxide in a molten salt electrolyte based on calcium chloride. The process is rather universal in its applicability, and numerous studies on metals, semimetals, alloys and intermetallics have since been performed at the place of its invention and worldwide. The electro-winning of titanium metal is a particularly rewarding target because of the disadvantages of the existing extraction methods. This article summarises the research work performed on the FFC-Cambridge process at the University of Cambridge and its industrial partners with a focus on the electro-winning of titanium metal from titanium dioxide. Topics addressed encompass the invention of the process, early proof-of-concept work, the identification of the reaction pathway, and the investigation and optimisation of the key process parameters. Also discussed are aspects of technology transfer and some of the development work undertaken to date.


Author(s):  
Changyi Hu ◽  
Yan Wei ◽  
Hongzhong Cai ◽  
Li Chen ◽  
Xian Wang ◽  
...  

Pt-based alloys are being developed for high-temperature applications with the aim of replacing some of the currently used Ni-based superalloys (NBSAs) and benchmark alloy, PM2000. The Pt-based superalloys have a similar structure to the NBSAs and can potentially be used at higher temperatures and in more aggressive environments because Pt is more chemically inert and has a higher melting point. In this paper, the recent progress in research and development of Pt-based superalloys is overviewed. Firstly, the composition optimization and structural design of Pt-base superalloys are introduced. The structural characteristics, mechanical properties, oxidation resistance and corrosion behavior of Pt-Al ternary, quaternary and multiple superalloys are summarized. Finally, directions for further research and application of Pt-base superalloys are analyzed and prospected.


2020 ◽  
Vol 76 (4) ◽  
pp. 313-325
Author(s):  
Kasim Sader ◽  
Rishi Matadeen ◽  
Pablo Castro Hartmann ◽  
Tor Halsan ◽  
Chris Schlichten

Cryo-electron microscopy (cryo-EM) has rapidly expanded with the introduction of direct electron detectors, improved image-processing software and automated image acquisition. Its recent adoption by industry, particularly in structure-based drug design, creates new requirements in terms of reliability, reproducibility and throughput. In 2016, Thermo Fisher Scientific (then FEI) partnered with the Medical Research Council Laboratory of Molecular Biology, the University of Cambridge Nanoscience Centre and five pharmaceutical companies [Astex Pharmaceuticals, AstraZeneca, GSK, Sosei Heptares and Union Chimique Belge (UCB)] to form the Cambridge Pharmaceutical Cryo-EM Consortium to share the risks of exploring cryo-EM for early-stage drug discovery. The Consortium expanded with a second Themo Scientific Krios Cryo-EM at the University of Cambridge Department of Materials Science and Metallurgy. Several Consortium members have set up in-house facilities, and a full service cryo-EM facility with Krios and Glacios has been created with the Electron Bio-Imaging Centre for Industry (eBIC for Industry) at Diamond Light Source (DLS), UK. This paper will cover the lessons learned during the setting up of these facilities, including two Consortium Krios microscopes and preparation laboratories, several Glacios microscopes at Consortium member sites, and a Krios and Glacios at eBIC for Industry, regarding site evaluation and selection for high-resolution cryo-EM microscopes, the installation process, scheduling, the operation and maintenance of the microscopes and preparation laboratories, and image processing.


Author(s):  
Michele Scervini ◽  
Catherine Rae

A new nickel based thermocouple for high temperature applications in gas turbines has been devised at the Department of Material Science and Metallurgy of the University of Cambridge. This paper describes the new features of the thermocouple, the drift tests on the first prototype, and compares the behavior of the new sensor with conventional mineral insulated metal sheathed Type K thermocouples: the new thermocouple has a significant improvement in terms of drift and temperature capabilities. Metallurgical analysis has been undertaken on selected sections of the thermocouples exposed at high temperatures, which rationalizes the reduced drift of the new sensor. A second prototype will be tested in subsequent research, from which further improvements in drift and temperature capabilities are expected.


2007 ◽  
Vol 79 (10) ◽  
pp. iv
Author(s):  
Adolf Mikula ◽  
Herbert Ipser

The 12th International Conference on High Temperature Materials Chemistry (HTMC-XII) took place at the Vienna University of Technology, Austria, 17-22 September 2006. Previous conferences were held in 2000 in Juelich (Germany), and in 2003 in Tokyo (Japan).The conference was sponsored by IUPAC and organized by the Department of Inorganic Chemistry/Materials Chemistry of the University of Vienna together with the Austrian Chemical Society (GÖCH) and the Department of Materials Chemistry of the Vienna University of Technology. The local organizing committee was chaired by Profs. Adolf Mikula and Herbert Ipser of the University of Vienna. Special patronage was granted by the Austrian Federal Minister for Education, Science and Culture and by the mayor of Vienna.More than 150 participants from 25 countries worldwide came to Vienna to present their research in the field of high temperature materials chemistry and to interact with each other in a lively scientific discussion. A considerable number of scientists, especially from Russia and some Eastern European countries, had the chance to come to this conference for the very first time, partly due to partial financial support by the local organizers, for example, by reduced or waived registration fees. It was also a pleasure to see many young scientists who made new contacts with each other and with their senior colleagues from all over the world.The program contained nine plenary lectures, corresponding to the main topics, but also included two special lectures on topics of more general interest, such as "Do universities prepare for industrial careers" (by Knuth Consemüller, chairman of the Austrian Council for Science and Technology Development), and "The arts: What use to materials science" (by Mark Miodownik). The plenary lectures, with the exception of the lecture by Dr. Consemüller, are published in this issue.In addition, there were 51 oral presentations and 100 posters that were on display for the entire week.For this conference, IUPAC sponsored three poster awards, and the winners received a two-year subscription of Chemistry International, a copy of the IUPAC "Gold Book" as well as a certificate signed by the IUPAC president. The winners, as selected by an international jury, were Dario Manara of Italy ("The uranium-oxygen phase diagram at high temperature: Recent advances"), Yuriy Plevachuk of Ukraine ("Density and electrical conductivity of liquid Al-Fe and Al-Ni binary alloys"), and Jiři Popovic of the Czech Republic ("Thermodynamic optimization of the Ni-Al-W system").The social program included a reception in the City Hall of Vienna, sponsored by the mayor of Vienna, as well as a conference excursion to the easternmost Austrian province, Burgenland, with visits to the small town of Rust on the shore of Lake Neusiedl and a guided tour through the Esterhazy Palace in Eisenstadt, the capital of Burgenland. This was followed by a string quartet concert with music by the Austrian composers Joseph Haydn (who had lived and worked in this particular palace for many years) and Wolfgang Amadeus Mozart (whose 250th birthday was celebrated in 2006). The excursion ended with a conference banquet in the state rooms of the palace.Judging from the comments of the participants, HTMC-XII was a big success, and many of the scientists promised to come back to the next meeting, HTMC-XIII. Most probably this will be held in 2009 in California, USA, organized by Prof. Alexandra Navrotsky of the University of California at Davis.Adolf Mikula and Herbert IpserConference Editors


Sign in / Sign up

Export Citation Format

Share Document