Accelerated Degradation for Hardware in the Loop Simulation of Fuel Cell-Gas Turbine Hybrid System

2015 ◽  
Vol 12 (2) ◽  
Author(s):  
Maria A. Abreu-Sepulveda ◽  
Nor Farida Harun ◽  
Gregory Hackett ◽  
Anke Hagen ◽  
David Tucker

The U.S. Department of Energy (DOE)-National Energy Technology Laboratory (NETL) in Morgantown, WV has developed the hybrid performance (HyPer) project in which a solid oxide fuel cell (SOFC) one-dimensional (1D), real-time operating model is coupled to a gas turbine hardware system by utilizing hardware-in-the-loop simulation. To assess the long-term stability of the SOFC part of the system, electrochemical degradation due to operating conditions such as current density and fuel utilization have been incorporated into the SOFC model and successfully recreated in real time. The mathematical expression for degradation rate was obtained through the analysis of empirical voltage versus time plots for different current densities and fuel utilizations.

Author(s):  
Maria Abreu-Sepulveda ◽  
David Tucker ◽  
Nor Farida Harun ◽  
Gregory Hackett ◽  
Anke Hagen

Solid oxide fuel cells (SOFCs) are a promising technology for clean power generation, however their implementation has been limited by several degradation mechanisms, which significantly reduce its lifetime under constant output power and inhibits the technology for commercialization in the near future. With the purpose of harnessing the capabilities offered by SOFCs, the U.S. DOE-National Energy Technology Laboratory (NETL) in Morgantown, WV has developed the Hybrid Performance (HyPer) project in which a SOFC 1D, real-time operating model is coupled to a gas turbine hardware system by utilizing hardware-in-the-loop simulation (HiLS). More recently, in order to assess the long-term stability of the SOFC part of the system, electrochemical degradation due to operating conditions such as current density and fuel utilization have been incorporated into the SOFC model and successfully recreated in real time for standalone and hybrid operation. The mathematical expression for degradation rate was obtained through the analysis of empirical voltage versus time plots for different current densities and fuel utilizations at 750, 800, and 850°C. Simulation results well reflected the behavior of SOFC degradation rates from which the long-term stability of the cell under various conditions was assessed. Distributed fuel cell parameters are presented for both standalone and hybrid configurations. The incorporation of the electrochemical degradation rate into the SOFC model provides a framework to study more realistically Fuel Cell-hybrid systems and set forth a mechanism to improve the long-term stability of SOFCs through the hybridization of such technology.


Author(s):  
Valentina Zaccaria ◽  
Alberto Traverso ◽  
David Tucker

The theoretical efficiencies of gas turbine fuel cell hybrid systems make them an ideal technology for the future. Hybrid systems focus on maximizing the utilization of existing energy technologies by combining them. However, one pervasive limitation that prevents the commercialization of such systems is the relatively short lifetime of fuel cells, which is due in part to several degradation mechanisms. In order to improve the lifetime of hybrid systems and to examine long-term stability, a study was conducted to analyze the effects of electrochemical degradation in a solid oxide fuel cell (SOFC) model. The SOFC model was developed for hardware-in-the-loop simulation with the constraint of real-time operation for coupling with turbomachinery and other system components. To minimize the computational burden, algebraic functions were fit to empirical relationships between degradation and key process variables: current density, fuel utilization, and temperature. Previous simulations showed that the coupling of gas turbines and SOFCs could reduce the impact of degradation as a result of lower fuel utilization and more flexible current demands. To improve the analytical capability of the model, degradation was incorporated on a distributed basis to identify localized effects and more accurately assess potential failure mechanisms. For syngas fueled systems, the results showed that current density shifted to underutilized sections of the fuel cell as degradation progressed. Over-all, the time to failure was increased, but the temperature difference along cell was increased to unacceptable levels, which could not be determined from the previous approach.


Author(s):  
Alberto Traverso ◽  
David Tucker ◽  
Comas L. Haynes

A newly developed integrated gasification fuel cell (IGFC) hybrid system concept has been tested using the Hybrid Performance (Hyper) project hardware-based simulation facility at the U.S. Department of Energy, National Energy Technology Laboratory. The cathode-loop hardware facility, previously connected to the real-time fuel cell model, was integrated with a real-time model of a gasifier of solid (biomass and fossil) fuel. The fuel cells are operated at the compressor delivery pressure, and they are fueled by an updraft atmospheric gasifier, through the syngas conditioning train for tar removal and syngas compression. The system was brought to steady state; then several perturbations in open loop (variable speed) and closed loop (constant speed) were performed in order to characterize the IGFC behavior. Coupled experiments and computations have shown the feasibility of relatively fast control of the plant as well as a possible mitigation strategy to reduce the thermal stress on the fuel cells as a consequence of load variation and change in gasifier operating conditions. Results also provided an insight into the different features of variable versus constant speed operation of the gas turbine section.


Author(s):  
Alberto Traverso ◽  
David Tucker ◽  
Comas L. Haynes

A newly developed Integrated Gasification Fuel Cell (IGFC) hybrid system concept has been tested using the Hybrid Performance (Hyper) project hardware-based simulation facility at the U.S. Department of Energy, National Energy Technology Laboratory. The cathode-loop hardware facility, previously connected to the real-time fuel cell model, was expanded by the inclusion of a real-time model of a gasifier of solid fuels, in this case biomass fuel. The fuel cell is operated at the compressor delivery pressure, and it is fuelled by an updraft atmospheric gasifier, through the syngas conditioning train for tar removal and syngas compression. The system was brought to steady-state; then, several perturbations in open loop (variable speed) and closed loop (constant speed) were performed in order to characterize the IGFC behavior. Experiments have shown the feasibility of relatively fast control of the plant as well as a possible mitigation strategy to reduce the thermal stress on the fuel cell as a consequence of load variation and change in gasifier operating conditions. Results also provided an insight into the different features of variable vs constant speed operation of the gas turbine section.


Author(s):  
Nana Zhou ◽  
Chen Yang ◽  
David Tucker

Thermal management in the fuel cell component of a direct fired solid oxide fuel cell gas turbine (SOFC/GT) hybrid power system, especially during an imposed load transient, can be improved by effective management and control of the cathode air mass flow. The response of gas turbine hardware system and the fuel cell stack to the cathode air mass flow transient was evaluated using a hardware-based simulation facility designed and built by the U.S. Department of Energy, National Energy Technology Laboratory (NETL). The disturbances of the cathode air mass flow were accomplished by diverting air around the fuel cell system through the manipulation of a hot-air bypass valve in open loop experiments. The dynamic responses of the SOFC/GT hybrid system were studied in this paper. The evaluation included distributed temperatures, current densities, heat generation and losses along the fuel cell over the course of the transient along with localized temperature gradients. The reduction of cathode air mass flow resulted in a sharp decrease and partial recovery of the thermal effluent from the fuel cell system in the first 10 seconds. In contrast, the turbine rotational speed did not exhibit a similar trend. The collection of distributed fuel cell and turbine trends obtained will be used in the development of controls to mitigate failure and extend life during operational transients.


Author(s):  
John Fagley ◽  
Jason Conley ◽  
David Masten

In recent years, there has been an increasing amount of PEM (proton exchange membrane) fuel cell-related research conducted and subsequently published by universities and public institutions. While a good deal of this research has been useful for understanding the underlying fundamental aspects of fuel cell components and operation, much of it is not as useful for a group working on automotive applications as it could be. The reason for this is that in order to be put to practical use in an automotive application, the system being studied must meet certain constraints; satisfying targets for projected system costs, system efficiency, volumetric and gravimetric power densities (packaging), and operating conditions. For example, numerous recent publications show studies with PEM fuel cells designed and built such that limiting current density is achieved at 0.9 A/cm2 or lower, and voltages of 600 mV can only be achieved at current densities less than 0.6 A/cm2. This type of performance is sufficiently below what is required for commercial application, that any conclusions drawn from these works are difficult to extrapolate to a system of commercial automotive interest. The purpose of this article is to show, through use of engineering calculations and cost projections, what operating conditions and performance are required in a commercial automotive fuel cell application. In addition, best known (public domain) performance and corresponding conditions are given, along with Department of Energy Freedom Car targets, which can be used for state-of-the-art benchmarking. Also, reference is made to a university publication where performance (500 mV at 1.5 A/cm2) close to automotive application targets was achieved, and important aspects of their components and flow field geometry are highlighted. It is our hope that through this publication, further PEM fuel-cell related research can be directed toward the region of greatest interest for commercial, automotive application.


Author(s):  
David Tucker ◽  
Larry Lawson ◽  
Randy Gemmen

The dynamic interdependencies created during the integration of fuel cell and a gas turbine in a hybrid power generation system are not well understood. Because these systems are new, there are risks that unexpected complications might arise during both steady state operation and transient events. A 250kW experimental fuel cell gas turbine simulation facility has been constructed at the National Energy Technology Laboratory (NETL), U.S. Department of Energy to examine the effects of transient events on the dynamics of these systems. A natural gas burner controlled by a real-time fuel cell model is used in the facility to simulate the thermal output of a solid oxide fuel cell during transient events. Pressure vessels are used for simulating the cathode and post combustion volumes, and are integrated into the system with a modified turbine and the fuel cell simulator. Preliminary results of system characterization are presented and discussed in context of the test scenarios proposed for experimental evaluation of thermal and mechanical transient impact on fuel cell and the gas turbine systems.


Author(s):  
Alessio Abrassi ◽  
Alberto Traverso ◽  
David Tucker ◽  
Eric Liese

Abstract A dynamic model is developed for a Micro Gas Turbine (MGT), characterized by an intrinsic free-spool configuration, coupled to large volumes. This is inspired by an experimental facility at the National Energy Technology Laboratory (NETL) called Hyper, which emulates a hybrid MGT and Fuel Cell system. The experiment and model can simulate stable and unstable operating conditions. The model is used to investigate the effects of different volumes on surge events, and to test possible strategies to safely avoid or recover from unstable compressor working conditions. The modelling approach started from the Greitzer lumped parameter approach, and it has been improved with integration of empirical methods and simulated components to better match the real Hyper plant layout and performance. Pressure, flow rate, and frequency plots are shown for the surge behavior comparing two different volume sizes, for cases where gas turbine shaft speed is uncontrolled (open loop) and controlled (closed loop). The ability to recover from a surge event is also demonstrated.


Author(s):  
Aristide F. Massardo ◽  
Loredana Magistri

The aim of this work is to investigate the performance of Internal Reforming Solid Oxide Fuel Cell (IRSOFC) and Gas Turbine (GT) combined cycles. A mathematical model of the IRSOFC steady-state operation was presented in Part A of this work (Massardo and Lubelli, 1998), coupled to the thermodynamic analysis of a number of proposed IRSOFC-GT combined cycles, taking into account the influence of several technological constraints. In the second part of this work, both an exergy and a thermoeconomic analysis of the proposed cycles have been carried out using the TEMP code developed by the Author (Agazzani and Massardo, 1997). A suitable equation for IRSOFC cost evaluation based on cell geometry and performance has been proposed and employed to evaluate the electricity generation cost of the proposed combined systems. The results are presented and the influence of several parameters is discussed: external reformer operating conditions, fuel to air ratio, cell current density, compressor pressure ratio, etc. Diagrams proposed by the Author (Massardo and Scialo’, 2000) for cost vs. efficiency, cost vs. specific work, and cost vs. system pressure are also presented and discussed.


Sign in / Sign up

Export Citation Format

Share Document