Influence of Dispersion and Alignment of Nanotubes on the Strength and Elasticity of Carbon Nanotubes Reinforced Composites

Author(s):  
Unnati A. Joshi ◽  
Satish C. Sharma ◽  
S. P. Harsha

In this paper, the effective strength and elastic properties of carbon nanotube reinforced composites are evaluated using a representative volume element with a number of carbon nanotubes embedded in the matrix. This concept is used to predict the mechanical properties of multiple, unidirectional, aligned, and also randomly dispersed carbon nanotube reinforced composites. To characterize these nanocomposites, a continuum model has been developed for large-scale analysis. The effective Young’s and shear moduli of the composites are determined using finite element analysis under the effect of elastic deformation. The role of design parameters like length and volume fraction of carbon nanotubes, tensile and shear strength as well as type of loading conditions are analyzed for multiple carbon nanotubes based composites. The discontinuous and continuous types of carbon nanotubes, with aligned and random distribution, are evaluated. The results show that the continuous and aligned carbon nanotubes produce the largest tensile modulus, compared to the discontinuous and aligned as well as discontinuous and randomly oriented carbon nanotubes along the longitudinal direction.

Author(s):  
Mohamad Shafiee Motahar ◽  
Mohammad Taghi Ahmadian

Characterization and simulation of carbon nanotube-reinforced composites at large scale have been a concern of researchers in the past decade. This is due to the computational complication of considering many embedded carbon nanotubes (CNTs). However a simple meshing of organized CNT distribution in the matrix can ease this obstacle. In this study, a finite element approach is employed to investigate the elastodynamic behavior of a wavy CNT-reinforced composite structure. A three dimensional structure with up to 6400 uniformly distributed wavy CNTs is embedded in a polymer matrix. Each wavy nanotube is represented by a set of beam elements. The effect of nanotube waviness and volume fraction on the effective modulus of nanocomposite is evaluated and verified by previous studies. The results demonstrate that waviness tends to decrease the effective modulus of the structure. Furthermore, the natural frequencies of a nano structure at different boundary conditions are examined. The results reveal that the natural frequencies increase with volume fraction of CNT, while a nominal increase of CNT waviness decreases the natural frequencies sharply.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4143
Author(s):  
Youzheng Cui ◽  
Shenrou Gao ◽  
Fengjuan Wang ◽  
Qingming Hu ◽  
Cheng Xu ◽  
...  

Compared with other materials, high-volume fraction aluminum-based silicon carbide composites (hereinafter referred to as SiCp/Al) have many advantages, including high strength, small change in the expansion coefficient due to temperature, high wear resistance, high corrosion resistance, high fatigue resistance, low density, good dimensional stability, and thermal conductivity. SiCp/Al composites have been widely used in aerospace, ordnance, transportation service, precision instruments, and in many other fields. In this study, the ABAQUS/explicit large-scale finite element analysis platform was used to simulate the milling process of SiCp/Al composites. By changing the parameters of the tool angle, milling depth, and milling speed, the influence of these parameters on the cutting force, cutting temperature, cutting stress, and cutting chips was studied. Optimization of the parameters was based on the above change rules to obtain the best processing combination of parameters. Then, the causes of surface machining defects, such as deep pits, shallow pits, and bulges, were simulated and discussed. Finally, the best cutting parameters obtained through simulation analysis was the tool rake angle γ0 = 5°, tool clearance angle α0 = 5°, corner radius r = 0.4 mm, milling depth ap = 50 mm, and milling speed vc= 300 m/min. The optimal combination of milling parameters provides a theoretical basis for subsequent cutting.


Mathematics ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 990
Author(s):  
Yasser Zare ◽  
Kyongyop Rhee

This study focuses on the simultaneous stiffening and percolating characteristics of the interphase section in polymer carbon nanotubes (CNTs) systems (PCNTs) using two advanced models of tensile modulus and strength. The interphase, as a third part around the nanoparticles, influences the mechanical features of such systems. The forecasts agree well with the tentative results, thus validating the advanced models. A CNT radius of >40 nm and CNT length of <5 μm marginally improve the modulus by 70%, while the highest modulus development of 350% is achieved with the thinnest nanoparticles. Furthermore, the highest improvement in nanocomposite’s strength (350%) is achieved with the CNT length of 12 μm and interfacial shear strength of 8 MPa. Generally, the highest ranges of the CNT length, interphase thickness, interphase modulus and interfacial shear strength lead to the most desirable mechanical features.


Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 2023
Author(s):  
Megha Chitranshi ◽  
Anuptha Pujari ◽  
Vianessa Ng ◽  
Daniel Chen ◽  
Devika Chauhan ◽  
...  

Decades of extensive research have matured the development of carbon nanotubes (CNTs). Still, the properties of macroscale assemblages, such as sheets of carbon nanotubes, are not good enough to satisfy many applications. This paper gives an overview of different approaches to synthesize CNTs and then focuses on the floating catalyst method to form CNT sheets. A method is also described in this paper to modify the properties of macroscale carbon nanotube sheets produced by the floating catalyst method. The CNT sheet is modified to form a carbon nanotube hybrid (CNTH) sheet by incorporating metal, ceramic, or other types of nanoparticles into the high-temperature synthesis process to improve and customize the properties of the traditional nanotube sheet. This paper also discusses manufacturing obstacles and the possible commercial applications of the CNT sheet and CNTH sheet. Manufacturing problems include the difficulty of injecting dry nanoparticles uniformly, increasing the output of the process to reduce cost, and safely handling the hydrogen gas generated in the process. Applications for CNT sheet include air and water filtering, energy storage applications, and compositing CNTH sheets to produce apparel with anti-microbial properties to protect the population from infectious diseases. The paper also provides an outlook towards large scale commercialization of CNT material.


2018 ◽  
Vol 30 (3) ◽  
pp. 463-478 ◽  
Author(s):  
MK Hassanzadeh-Aghdam ◽  
MJ Mahmoodi ◽  
R Ansari ◽  
A Darvizeh

The effects of interphase characteristics on the elastic behavior of randomly dispersed carbon nanotube–reinforced shape memory polymer nanocomposites are investigated using a three-dimensional unit cell–based micromechanical method. The interphase region is formed due to non-bonded van der Waals interaction between a carbon nanotube and a shape memory polymer. The influences of temperature, diameter, volume fraction, and arrangement type of carbon nanotubes within the matrix as well as two interphase factors, including adhesion exponent and thickness on the carbon nanotube/shape memory polymer nanocomposite’s longitudinal and transverse elastic moduli, are explored extensively. Moreover, the results are presented for the shape memory polymer nanocomposites containing randomly oriented carbon nanotubes. The obtained results clearly demonstrate that the interphase region plays a crucial role in the modeling of the carbon nanotube/shape memory polymer nanocomposite’s elastic moduli. It is observed that the nanocomposite’s elastic moduli remarkably increase with increasing interphase thickness or decreasing adhesion exponent. It is found that when the interphase is considered in the micromechanical simulation, the shape memory polymer nanocomposite’s elastic moduli non-linearly increase as the carbon nanotube diameter decreases. The predictions of the present micromechanical model are compared with those of other analytical methods and available experiments.


Author(s):  
T. El-Aguizy ◽  
Sang-Gook Kim

The scale decomposition of a multi-scale system into small-scale order domains will reduce the complexity of the system and will subsequently ensure a success in nanomanufacturing. A novel method of assembling individual carbon nanotube has been developed based on the concept of scale decomposition. Current technologies for organized growth of carbon nanotubes are limited to very small-scale order. The nanopelleting concept is to overcome this limitation by embedding carbon nanotubes into micro-scale pellets that enable large-scale assembly as required. Manufacturing processes have been developed to produce nanopellets, which are then transplanted to locations where the functionalization of carbon nanotubes are required.


Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 233 ◽  
Author(s):  
Yasser Zare ◽  
Kyong Yop Rhee

In this paper, we consider the interphase regions surrounding the dispersed and networked carbon nanotubes (CNT) to develop and simplify the expanded Takayanagi model for tensile modulus of polymer CNT nanocomposites (PCNT). The moduli and volume fractions of dispersed and networked CNT and the surrounding interphase regions are considered. Since the modulus of interphase region around the dispersed CNT insignificantly changes the modulus of nanocomposites, this parameter is removed from the developed model. The developed model shows acceptable agreement with the experimental results of several samples. “ER” as nanocomposite modulus per the modulus of neat matrix changes from 1.4 to 7.7 at dissimilar levels of “f” (CNT fraction in the network) and network modulus. Moreover, the lowest relative modulus of 2.2 is observed at the smallest levels of interphase volume fraction ( ϕ i < 0.017), while the highest “ ϕ i ” as 0.07 obtains the highest relative modulus of 11.8. Also, the variation of CNT size (radius and length) significantly changes the relative modulus from 2 to 20.


2004 ◽  
Vol 126 (3) ◽  
pp. 250-257 ◽  
Author(s):  
Dong-Li Shi ◽  
Xi-Qiao Feng ◽  
Yonggang Y. Huang ◽  
Keh-Chih Hwang ◽  
Huajian Gao

Owing to their superior mechanical and physical properties, carbon nanotubes seem to hold a great promise as an ideal reinforcing material for composites of high-strength and low-density. In most of the experimental results up to date, however, only modest improvements in the strength and stiffness have been achieved by incorporating carbon nanotubes in polymers. In the present paper, the stiffening effect of carbon nanotubes is quantitatively investigated by micromechanics methods. Especially, the effects of the extensively observed waviness and agglomeration of carbon nanotubes are examined theoretically. The Mori-Tanaka effective-field method is first employed to calculate the effective elastic moduli of composites with aligned or randomly oriented straight nanotubes. Then, a novel micromechanics model is developed to consider the waviness or curviness effect of nanotubes, which are assumed to have a helical shape. Finally, the influence of nanotube agglomeration on the effective stiffness is analyzed. Analytical expressions are derived for the effective elastic stiffness of carbon nanotube-reinforced composites with the effects of waviness and agglomeration. It is found that these two mechanisms may reduce the stiffening effect of nanotubes significantly. The present study not only provides the relationship between the effective properties and the morphology of carbon nanotube-reinforced composites, but also may be useful for improving and tailoring the mechanical properties of nanotube composites.


2016 ◽  
Vol 685 ◽  
pp. 569-573
Author(s):  
Sergey M. Lebedev ◽  
Olga S. Gefle ◽  
Ernar T. Amitov ◽  
Mikhail R. Predtechensky ◽  
Alexander E. Bezrodny

Novel electrically conductive SWCNT-reinforced composites were studied in this work. Incorporating SWCNT into CB/polymer composites provides lowering the percolation threshold. Adding a small quantity of single-walled carbon nanotubes into CB/polymer composites allows reducing CB content in electrically conductive composites and improving rheological and processing properties.


Sign in / Sign up

Export Citation Format

Share Document