Effective Light Harvesting of Tandem Polymer Solar Cell

2010 ◽  
Vol 132 (2) ◽  
Author(s):  
Yi-Chun Chen ◽  
Chao-Ying Yu ◽  
Chih-Ping Chen ◽  
Shu-Hua Chan ◽  
Ching Ting
Keyword(s):  
Solar Cell ◽  
Molecular Orbital ◽  
Open Circuit Voltage ◽  
Polymer Solar Cell ◽  
Short Circuit ◽  
Active Material ◽  
Weight Ratio ◽  
Acid Methyl Ester ◽  
Open Circuit ◽  
Ito Glass

A novel soluble conjugated polymers, P2, with coplanar thiophene-phenylene-thiophene unit is designed and synthesized as suitable active material used in tandem cells to compensate the poly(3-hexylthiophene) (P3HT)/[6,6]-phenyl-C71 butyric acid methyl ester (PC71BM) bulk-heterojunction cell in this paper. P2 polymer bears advantages in both low optical bandgap (1.7 eV) and high hole mobility properties (3.4×10−3 cm2/V-s from field-effect transistor measurement). Furthermore, the electrochemical studies of P2 indicate desirable highest occupied molecular orbital/lowest unoccupied molecular orbital (HOMO/LUMO) band structure that enables a high open circuit voltage when pairing with PCBM acceptor. The best power conversion efficiency of this polymer solar cell thus far based on P2/PC71BM system with a weight ratio of 1:3 reached 4.4% with a short circuit current density (Jsc) of 10.2 mA/cm2, an open circuit voltage (Voc) of 0.81 V, and a fill factor (FF) of 0.53 under air mass (AM) 1.5 G (100 mW/cm2). The preliminary data of the tandem cell with indium tin oxide (ITO) glass/PEDOT:PSS/P2:PC71BM/TiOx/PEDOT:PSS/P3HT:PC71BM/TiOx/Al configuration has reached Jsc of 6.2 mA/cm2, Voc of 1.33 V, FF of 0.56 and an overall efficiency of 4.6% under AM 1.5 G (100 mW/cm2).

Inkjet Printing Technology for Dye-Sensitized Solar Cells

2012 ◽  
Vol 476-478 ◽  
pp. 1767-1770
Author(s):  
Yu Li Lin ◽  
Cheng Yi Hsu ◽  
Chang Lun Tai
Keyword(s):  
Open Circuit Voltage ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Dye Sensitized ◽  
Tio2 Particles ◽  
Ito Glass ◽  
Sensitized Solar Cells ◽  
Pet Substrate

The task of this study is to prepare the TiO2 film electrode for dye-sensitized solar cells (DSSC) on ITO PET substrate using a general jet-printer. The results were compared with that obtained using ITO glass substrate. In this study, the dispersion of TiO2 slurry was manipulated by changing the pH value of the solution to avoid agglomeration of TiO2 particles. The average TiO2 particles used in this study were measured about 130nm. The experimental results show that it has the best performance when the thickness of the TiO2 film was about 10μm. In ITO glass substrate, the measured short circuit current was about 5.03mA, the open circuit voltage was measured to be 0.65V. In ITO-PET substrate, the measured short circuit current was about 2.73mA, the open circuit voltage was measured to be 0.68V.

IODINE/IODIDE-FREE AND POLYMER HETEROJUNCTION-SENSITIZED HYBRID SOLAR CELL

2012 ◽  
Vol 05 (02) ◽  
pp. 1260004 ◽  
Author(s):  
GENTIAN YUE ◽  
JIHUAI WU ◽  
YUNFANG HUANG ◽  
YAOMING XIAOMING XIAO ◽  
ZHANG LAN
Keyword(s):  
Solar Cell ◽  
Short Circuit ◽  
Electric Energy ◽  
Acid Methyl Ester ◽  
Short Circuit Current ◽  
Energy Conversion Efficiency ◽  
Open Circuit ◽  
Hybrid Solar Cell ◽  
Light Transport ◽  
Simulated Solar Light

An iodine/iodide-free and polymer heterojunction-sensitized hybrid solar cell is fabricated by using 6,6-phenyl- C61 -butyric acid methyl ester (PCBM) as electronic acceptor, poly(3-hexylthiophene) (P3HT) as donor and TiO2 film as substrate. The PCBM–P3HT heterojunction can harvest ultraviolet-visible light, transport charge carriers, replacing the dyes and electrolytes in dye-sensitized solar cell. The cell with a PCBM/P3HT ratio of 1:2 shows a short circuit current of 5.47 mA⋅cm-2, an open circuit voltage of 0.849 V, a fill factor of 0.640 and a light-to-electric energy conversion efficiency of 2.97% under a simulated solar light irradiation of 100 mW⋅cm-2.

Modeling of Abnormal Hysteresis in CsPbBr3 based Perovskite Solar Cells

2021 ◽  
Vol 34 (1) ◽  
pp. 01-08
Author(s):  
B GopalKrishna ◽  
Sanjay Tiwari
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Simulation Study ◽  
Open Circuit Voltage ◽  
Layer Structure ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Open Circuit ◽  
Perovskite Layer

Perovskite solar cells are emerging photovoltaic devices with PCE of above 25%. Perovskite are suitable light absorber materials in solar cells with excellent properties like appropriate band gap energy, long carrier lifetime and diffusion length, and high extinction coefficient. Simulation study is an important technique to understand working mechanisms of perovskites solar cells. The study would help develop efficient, stable PSCs experimentally. In this study, modeling of perovskite solar cell was carried out through Setfos software. The optimization of different parameters of layer structure of solar cell would help to achieve maximum light absorption in the perovskite layer of solar cell. Simulation study is based drift-diffusion model to study the different parameters of perovskite solar cell. Hysteresis is one of the factors in the perovskite solar cell which may influence the device performance. The measurement of abnormal hysteresis can be done by current-voltage curve during backward scan during simulation study. In backward scan, the measurement starts from biasing voltage higher than open circuit voltage and sweep to voltage below zero. The numerical simulation used to study the various parameters like open circuit voltage, short circuit current, fill factor, power conversion efficiency and hysteresis. The simulation results would help to understand the photophysics of solar cell physics which would help to fabricate highly efficient and stable perovskite solar cells experimentally.

scholarly journals Investigations on the Outdoor Performance Characteristics of Multicrystalline Silicon Solar Cell and Module

2013 ◽  
Vol 2013 ◽  
pp. 1-4
Author(s):  
Sivakumar Parthasarathy ◽  
P. Neelamegam ◽  
P. Thilakan ◽  
N. Tamilselvan
Keyword(s):  
Solar Cell ◽  
Silicon Solar Cell ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Critical Value ◽  
Standard Test ◽  
Open Circuit ◽  
Multicrystalline Silicon ◽  
In Series

Multicrystalline silicon solar cell and its module with 18 cells connected in series were mounted on an inclined rack tilted 12° South positioned at latitude of 12.0107° and longitude of 79.856°. Corresponding solar irradiance was measured using an optical Pyranometer. Measured irradiance, open circuit voltage (), and short circuit current () values were analyzed. values of both the cell and module were found saturated at above the critical value of illuminations which were different from each other. The integrated daily efficiency for the cell and module were ~10.25% and ~9.39%, respectively, that were less than their respective standard test condition’s value. The reasons for this drop in efficiencies were investigated and reported.

Deposition of P-Type Nanocrystalline Silicon Using High Pressure in a VHF-PECVD Single Chamber System

2011 ◽  
Vol 1321 ◽  
Author(s):  
Xiaodan Zhang ◽  
Guanghong Wang ◽  
Xinxia Zheng ◽  
Shengzhi Xu ◽  
Changchun Wei ◽  
...  
Keyword(s):  
High Pressure ◽  
Solar Cells ◽  
Solar Cell ◽  
Conversion Efficiency ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Nanocrystalline Silicon ◽  
Open Circuit ◽  
Single Chamber ◽  
P Type

ABSTRACTIn this article, we present a study of boron-doped hydrogenated nanocrystalline silicon (nc-Si: H) films by very high frequency-plasma enhanced chemical vapor deposition (VHF-PECVD) using high deposition pressure. Electrical, structural and optical properties of the films were investigated. Dark conductivity as high as 2.75S/cm of p-type nc-Si: H prepared at 2.5Torr pressure has been achieved at a deposition rate of 1.75Å/s for 25nm thin film. By controlling boron and phosphorus contamination, single junction nc-Si: H solar cells incorporated p-layers prepared under high pressure and low pressure, respectively, were deposited. It has been proven that nanocrystalline silicon solar cells with incorporation of p layer prepared at high pressure has resulted in enhanced open circuit voltage, short circuit current density and subsequently high conversion efficiency. Through the optimization of the bottom solar cell and application of ZnO/Al back reflector, 10.59% initial conversion efficiency of micromorph tandem solar cell (1.027cm2) with an open circuit voltage of 1.3864V, has been fabricated, where the bottom solar cell using a high pressure p layer was deposited in a single chamber.

scholarly journals High Open-circuit Voltage and Low Voltage Loss in All-polymer Solar Cell with a Poly(coronenediimide-vinylene) Acceptor

2020 ◽  
Vol 38 (11) ◽  
pp. 1157-1163 ◽  
Author(s):  
Han Han ◽  
Fu-Jin Bai ◽  
Rong Wei ◽  
Han Yu ◽  
Yi-Kun Guo ◽  
...  
Keyword(s):  
Solar Cell ◽  
Open Circuit Voltage ◽  
Polymer Solar Cell ◽  
Low Voltage ◽  
Open Circuit ◽  
Voltage Loss

High-Efficiency HIT Solar Cells for Excellent Power Generating Properties

2008 ◽  
Vol 1123 ◽  
Author(s):  
Toshihiro Kinoshita ◽  
Daisuke Ide ◽  
Yasufumi Tsunomura ◽  
Shigeharu Taira ◽  
Toshiaki Baba ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Conversion Efficiency ◽  
Production Cost ◽  
High Efficiency ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Open Circuit ◽  
Surface Recombination Velocity ◽  
Dominant Factor

AbstractIn order to achieve the widespread use of HIT (Hetero-junction with I etero-Intrinsic T ntrinsic Thin-layer) solar cells, it is important to reduce the power generating cost. There are three main approaches for reducing this cost: raising the conversion efficiency of the HIT cell, using a thinner wafer to reduce the wafer cost, and raising the open circuit voltage to obtain a better temperature coefficient. With the first approach, we have achieved the highest conversion efficiency values of 22.3%, confirmed by AIST, in a HIT solar cell. This cell has an open circuit voltage of 0.725 V, a short circuit current density of 38.9 mA/cm2 and a fill factor of 0.791, with a cell size of 100.5 cm2. The second approach is to use thinner Si wafers. The shortage of Si feedstock and the strong requirement of a lower sales price make it necessary for solar cell manufacturers to reduce their production cost. The wafer cost is an especially dominant factor in the production cost. In order to provide low-priced, high-quality solar cells, we are trying to use thinner wafers. We obtained a conversion efficiency of 21.4% (measured by Sanyo) for a HIT solar cell with a thickness of 85μm. Even better, there was absolutely no sagging in our HIT solar cell because of its symmetrical structure. The third approach is to raise the open circuit voltage. We obtained a remarkably higher Voc of 0.739 V with the thinner cell mentioned above because of its low surface recombination velocity. The high Voc results in good temperature properties, which allow it to generate a large amount of electricity at high temperatures.

A Solar Cell Based on a Hybrid Film of P3HT and Magic Cubic-Like PbS

2012 ◽  
Vol 567 ◽  
pp. 236-239
Author(s):  
Peng Wang ◽  
An Mei Wang ◽  
Zhen Hua Zhang ◽  
Li Bo Fan ◽  
Yan Lei ◽  
...  
Keyword(s):  
Solar Cell ◽  
Near Infrared ◽  
Hybrid Film ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Energy Conversion Efficiency ◽  
Open Circuit ◽  
Special Treatment ◽  
Ito Glass ◽  
Coating Method

Lead sulfide (PbS) magic cubes were prepared by a simple hydrothermal method without any organic solvent. The product was characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and absorption spectrum. A solar cell, with a structure of Al/P3HT:PbS/PEDOT:PSS/ITO/Glass, was made. By a spin coating method, a hybrid film of poly(3-hexylthiophene) (P3HT) and PbS was prepared on the PEDOT:PSS layer. The solar cells are photosensitive in a large spectral range (visible and near infrared regions). The cells, with the area of 0.15 cm2 without any special treatment, have shown the values of open-circuit voltage (Voc) of 242 mV, short circuit current (Jsc) of 0.01 mA/cm2, energy conversion efficiency (η) of 0.01 % and fill factor (FF) of 0.31 under illumination intensity of 100 mW/cm2.

Effect of Assets of Silicon Film Passivation Layer on the Performance of Silicon Nanowire Solar Cells

2014 ◽  
Vol 633-634 ◽  
pp. 509-512
Author(s):  
Ping Yang ◽  
Xiang Bo Zeng ◽  
Xiao Dong Zhang ◽  
Zhan Guo Wang
Keyword(s):  
Solar Cell ◽  
Current Density ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Silicon Film ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Passivation Layer ◽  
Hydrogen Dilution

Silicon film as a surface passivation layer is reported to reduce surface recombination on silicon nanowires (SiNWs) and thus enable to improve SiNW solar cell (SC) performance. A question yet to be answered regards the link between the silicon film assets and the solar cell performances. We investigated the effect of the properties of silicon films on the SiNWs SC performances by adjusting hydrogen dilution. Our results showed that the open-circuit voltage (Voc) and short-circuit current density (Jsc) of SiNWs SC increase until hydrogen dilution 10 and then decrease. An open-circuit voltage of 0.397 V and short-circuit current density of 18.42 mA/cm2 are achieved at optimized hydrogen dilution. Based on the analysis of silicon film properties we proposed that the increase of defect density with hydrogen dilution was the main cause for the deterioration of SiNWs SC performance.

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