Pollutants From Methane Fueled Gas Turbine Combustion

1973 ◽  
Vol 95 (2) ◽  
pp. 97-104
Author(s):  
P. G. Parikh ◽  
R. F. Sawyer ◽  
A. L. London

In view of the greater flexibility of a gas turbine combustion system design as compared to that for a piston engine, control of NOx emissions even while keeping the CO and hydrocarbon emissions at very low levels appears feasible. Factors influencing the production of these pollutants in a methane fueled gas turbine type combustor are studied in this investigation by analyzing the gas samples taken at various locations within the combustor. Increasing the homogeneity of the primary zone gas composition by using gaseous or prevaporized liquid fuels is found to be an effective way to reduced NOx emissions.

Author(s):  
Kenneth O. Smith ◽  
Leonard C. Angello ◽  
F. Richard Kurzynske

The design and initial rig testing of an ultra-low NOx gas turbine combustor primary zone are described. A lean premixed, swirl-stabilized combustor was evaluated over a range of pressures up to 10.7 × 105 Pa (10.6 atm) using natural gas. The program goal of reducing NOx emissions to 10 ppm (at 15% O2) with coincident low CO emissions was achieved at all combustor pressure levels. Appropriate combustor loading for ultra-low NOx operation was determined through emissions sampling within the primary zone. The work described represents a first step in developing an advanced gas turbine combustion system that can yield ultra-low NOx levels without the need for water injection and selective catalytic reduction.


Author(s):  
B. Becker ◽  
P. Berenbrink ◽  
H. Brandner

In the case of the burners employed in KWU gas turbine combustion chambers, the entire primary air is supplied through the swirlers associated with the burners. It is thus relatively easy to add natural gas to this air uniformly before it enters the combustion zone. This results in a particularly low NOx combustion process provided that the air to fuel ratio is being maintained within a certain range. The supplementary equipment to premix the fuel and air does not affect the burner performance when the fuel is supplied in the conventional way by means of gas or oil nozzles. Consequently, the gas turbine will be started up and loaded in the usual manner. In the high load range the burners are then switched over to premixed combustion operation. A small amount of fuel through the central gas nozzle stabilizes the flame in the case of a sudden load decrease. Combustion chambers already in service can be retrofitted with the new premixing equipment to reduce NOx emissions to about one third of the original values. The combustors can be operated with liquid fuels together with steam or water for NOx reduction in the conventional way.


Author(s):  
William D. York ◽  
Bryan W. Romig ◽  
Michael J. Hughes ◽  
Derrick W. Simons ◽  
Joseph V. Citeno

Operators of heavy duty gas turbines desire more flexibility of operation in compliance with increasingly stringent emissions regulations. Delivering low NOx at base load operation, while at the same time meeting aggressive startup, shutdown, and part load requirements for NOx, CO, and unburned hydrocarbons is a challenge that requires novel solutions in the framework of lean premixed combustion systems. The DLN2.6+ combustion system, first offered by the General Electric Company (GE) in 2005 on the 9F series gas turbines for the 50 Hz market, has a proven track record of low emissions, flexibility, and reliability. In 2010, GE launched a program to incorporate the DLN2.6+ into the 7F gas turbine model. The primary driver for the introduction of this combustion system into the 60 Hz market was to enable customers to capitalize on opportunities to use shale gas, which may have a greater Wobbe range and higher reactivity than traditional natural gas. The 7F version of the DLN2.6+ features premixed pilot flames on the five outer swirl-stabilized premixing fuel nozzles (“swozzles”). The premixed pilots have their roots in the multitube mixer technology developed by GE in the US Department of Energy Hydrogen Gas Turbine Program. A fraction of air is extracted prior to entering the combustor and sent to small tubes around the tip of the fuel nozzle centerbody. A dedicated pilot fuel circuit delivers the gas fuel to the pilot tubes, where it is injected into the air stream and given sufficient length to mix. Since the pilot flames are premixed, they contribute lower NOx emissions than a diffusion pilot, but can still provide enhanced main circuit flame stability at low-load conditions. The pilot equivalence ratio can be optimized for the specific operating conditions of the gas turbine. This paper presents the development and validation testing of the premixed pilots, which were tested on E-class and F-class gas turbine combustion system rigs at GE Power & Water’s Gas Turbine Technology Lab. A 25% reduction in NOx emissions at nominal firing temperature was demonstrated over a diffusion flame pilot, translating into more than 80% reduction in CO emissions if increased flame temperature is employed to hold constant NOx. On the new 7F DLN2.6+, the premixed pilots have enabled modifications to the system to reduce base load NOx emissions while maintaining similar gas turbine low-load performance and bringing a significant reduction in the combustor exit temperature at which LBO occurs, highlighting the stability the pilot system brings to the combustor without the NOx penalty of a diffusion pilot. The new combustion system is scheduled to enter commercial operation on GE 7F series gas turbines in 2015.


Energies ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 389
Author(s):  
Jinfu Liu ◽  
Zhenhua Long ◽  
Mingliang Bai ◽  
Linhai Zhu ◽  
Daren Yu

As one of the core components of gas turbines, the combustion system operates in a high-temperature and high-pressure adverse environment, which makes it extremely prone to faults and catastrophic accidents. Therefore, it is necessary to monitor the combustion system to detect in a timely way whether its performance has deteriorated, to improve the safety and economy of gas turbine operation. However, the combustor outlet temperature is so high that conventional sensors cannot work in such a harsh environment for a long time. In practical application, temperature thermocouples distributed at the turbine outlet are used to monitor the exhaust gas temperature (EGT) to indirectly monitor the performance of the combustion system, but, the EGT is not only affected by faults but also influenced by many interference factors, such as ambient conditions, operating conditions, rotation and mixing of uneven hot gas, performance degradation of compressor, etc., which will reduce the sensitivity and reliability of fault detection. For this reason, many scholars have devoted themselves to the research of combustion system fault detection and proposed many excellent methods. However, few studies have compared these methods. This paper will introduce the main methods of combustion system fault detection and select current mainstream methods for analysis. And a circumferential temperature distribution model of gas turbine is established to simulate the EGT profile when a fault is coupled with interference factors, then use the simulation data to compare the detection results of selected methods. Besides, the comparison results are verified by the actual operation data of a gas turbine. Finally, through comparative research and mechanism analysis, the study points out a more suitable method for gas turbine combustion system fault detection and proposes possible development directions.


Author(s):  
K. O. Smith ◽  
A. C. Holsapple ◽  
H. K. Mak ◽  
L. Watkins

The experimental results from the rig testing of an ultra-low NOx, natural gas-fired combustor for an 800 to 1000 kw gas turbine are presented. The combustor employed lean-premixed combustion to reduce NOx emissions and variable geometry to extend the range over which low emissions were obtained. Testing was conducted using natural gas and methanol. Testing at combustor pressures up to 6 atmospheres showed that ultra-low NOx emissions could be achieved from full load down to approximately 70% load through the combination of lean-premixed combustion and variable primary zone airflow.


Author(s):  
Waseem Nazeer ◽  
Kenneth Smith ◽  
Patrick Sheppard ◽  
Robert Cheng ◽  
David Littlejohn

The continued development of a low swirl injector for ultra-low NOx gas turbine applications is described. An injector prototype for natural gas operation has been designed, fabricated and tested. The target application is an annular gas turbine combustion system requiring twelve injectors. High pressure rig test results for a single injector prototype are presented. On natural gas, ultra-low NOx emissions were achieved along with low CO. A turndown of approximately 100°F in flame temperature was possible before CO emissions increased significantly. Subsequently, a set of injectors was evaluated at atmospheric pressure using a production annular combustor. Rig testing again demonstrated the ultra-low NOx capability of the injectors on natural gas. An engine test of the injectors will be required to establish the transient performance of the combustion system and to assess any combustor pressure oscillation issues.


Author(s):  
Jeffrey Price ◽  
Josh Kimmel ◽  
Xiaoqun Chen ◽  
Arun Bhattacharya ◽  
Anthony Fahme ◽  
...  

Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-00CH 11049, is improving the durability of gas turbine combustion systems while reducing life cycle costs. This project is part of the Advanced Materials in Advanced Industrial Gas Turbines program in DOE’s Office of Distributed Energy. The targeted engine is the Mercury™ 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems (ATS) program (DOE contract number DE-FC21-95MC31173). The ultimate goal of the program is to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for 4,000 hours. The program has focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 turbine and future Solar products. For liner and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics were evaluated. An advanced TBC system for the combustor was down-selected for field evaluation. ODS alloys were down-selected for the fuel injector tip application. Preliminary component and sub-scale testing was conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing were used to validate engine performance prior to field evaluation. Field evaluation of ceramic matrix composite liners in the Centaur® 50 gas turbine engine [1–3] which was previously conducted under the DOE sponsored Ceramic Stationary Gas Turbine program (DE-AC02-92CE40960), is continuing under this program. This paper is a status review of the program, detailing the current progress of the development and field evaluations.


Author(s):  
Ralph A. Dalla Betta ◽  
James C. Schlatter ◽  
Sarento G. Nickolas ◽  
Martin B. Cutrone ◽  
Kenneth W. Beebe ◽  
...  

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are either diluent injection in the combustor reaction zone, or lean premixed Dry Low NOx (DLN) combustion. For ultra low emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OOIE gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508 mm diameter catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial non-uniformities which were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design and the results of full-scale testing of the improved combustor at MS9OOIE cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at base load conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.


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