Zero-Emission MATIANT Cycle

1999 ◽  
Vol 121 (1) ◽  
pp. 116-120 ◽  
Author(s):  
P. Mathieu ◽  
R. Nihart

In this paper, a novel technology based on the zero CO2 emission MATIANT (contraction of the names of the two designers MAThieu and IANTovski) cycle is presented. This latter is basically a gas cycle and consists of a supercritical CO2 Rankine-like cycle on top of regenerative CO2 Brayton cycle. CO2 is the working fluid and O2 is the fuel oxidizer in the combustion chambers. The cycle uses the highest temperatures and pressures compatible with the most advanced materials in the steam and gas turbines. In addition, a reheat and a staged compression with intercooling are used. Therefore, the optimized cycle efficiency rises up to around 45 percent when operating on natural gas. A big asset of the system is its ability to remove the CO2 produced in the combustion process in liquid state and at high pressure, making it ready for transportation, for reuse or for final storage. The assets of the cycle are mentioned. The technical issues for the predesign of a prototype plant are reviewed.

Author(s):  
Ph. Mathieu ◽  
R. Nihart

In this paper, a novel technology based on the zero CO2 emission MATIANT (contraction of the names of the 2 designers: MATHIEU and IANTOVSKI) cycle is presented. This latter is basically a gas cycle and consists of a supercritical CO2 Rankine-like cycle on top of regenerative CO2 Brayton cycle. CO2 is the working fluid and O2 is the fuel oxidizer in the combustion chambers. The cycle uses the highest temperatures and pressures compatible with the most advanced materials in the steam and gas turbines. In addition, a reheat and a staged compression with intercooling are used. Therefore the optimized cycle efficiency rises up to around 45% when operating on natural gas. A big asset of the system is its ability to remove the CO2 produced in the combustion process in liquid state and at high pressure, making it ready for transportation, for reuse or for final storage. The assets of the cycle are mentioned. The technical issues for the predesign of a prototype plant are reviewed.


Author(s):  
Chengjie Duan ◽  
Xiaoyong Yang ◽  
Jie Wang ◽  
Suyuan Yu

At present, power cycles used in HTGR are indirect steam Rankine cycle and helium Brayton cycle. Using water or helium as working fluid which transform thermal energy into mechanical energy for HTGR power cycle has many disadvantages. Steam cycle could choose steam system which is similar to conventional coal-fired power plant, but because of the limit of material and equipments, there is big temperature difference between the steam and the helium, that makes big loss of thermal power and lowers the cycle efficiency. Helium can reach a high temperature in HTGR Brayton cycle and it has good stability, but because of helium has big isentropic exponent and low density, it is difficult to compress and makes helium turbine has shorter blades and more stages than normal gas turbine. Carbon dioxide has good thermal stability and physical properties. To avoid the reaction of CO2 with graphite and canning of fuel element at high temperature, it should be used in an indirect cycle as second loop working fluid. CO2 has appropriate critical pressure and temperature (7.38MPa, 304.19K) and can choose three types of cycle: supercritical cycle, subcritical-pressure cycle and trans-critical-pressure cycle (CO2 sometimes works under supercritical pressure, some times under subcritical-pressure). Carbon dioxide cycle works in a high pressure, so it makes pressure loss lower. When CO2 works close to its critical point, its density become larger than other conditions, and not change very much, this permits to reduce compress work. The thermal physical properties of carbon dioxide are totally different from helium due to CO2 works as real gas in the cycle. That causes the calculation of CO2 thermal physical properties, heat transfer and power cycle efficiency become difficult and need to be iterated. A systematic comparison between helium and carbon dioxide as working fluid for HTGR has been carried out. An empirical equation had been selected to estimate the thermal physical properties of carbon dioxide. Three types of carbon dioxide power cycle have been analyzed and the thermal efficiency has been calculated. A detailed introduction to the basic calculation process of the CO2 cycle thermal efficiency had been presented in the paper.


Author(s):  
Giorgio Cau ◽  
Daniele Cocco

The paper is concerned with thermochemical recuperation in semi-closed gas turbine systems. Semi-closed turbines use CO2 as the main working fluid and the combustion process takes place with pure oxygen, allowing the CO2 produced to be easily removed. On the other hand, the exhaust heat recovery through thermochemical recuperation offers interesting capabilities in terms of high conversion efficiency and low polluting emissions. System analysis and performance evaluation of the semi-closed, chemically recuperated gas turbine systems has been conducted and their performance assessed. A comparative analysis of semi-closed and open gas turbine cycles, with and without thermochemical recuperation, has been also carried out. The results of the analysis show that thermochemical recuperation in semi-closed gas turbine systems can allow to remove the CO2 with high cycle efficiency and specific power.


2020 ◽  
Vol 22 (2) ◽  
pp. 593-602 ◽  
Author(s):  
Andrey Rogalev ◽  
Vladimir Kindra ◽  
Alexey Zonov ◽  
Nikolay Rogalev ◽  
Levon Agamirov

AbstractThis study aims to present a method for precooling bleed flow by water injection in the E-MATIANT cycle and to estimate its impact on the overall efficiency. The design parameters of the cycle are set up on the basis of the component technologies of today's state-of-the-art gas turbines with a turbine inlet temperature between 1100 and 1700°C. Several schemes of the E-MATIANT cycle are considered: with one, two and three combustion chambers. The optimal pressure ratio ranges for the considered turbine inlet temperatures are identified and a comparison with existing evaluations is made. For the optimal initial parameters, cycle net efficiency varies from 42.0 to 49.8%. A significant influence of turbine stage cooling model on optimal thermodynamic parameters and cycle efficiency is established. The maximum cycle efficiency is 44.0% considering cooling losses. The performance penalty due to the oxygen production and carbon dioxide capture is 20–22%.


Vestnik IGEU ◽  
2021 ◽  
pp. 14-22
Author(s):  
I.I. Komarov ◽  
D.M. Kharlamova ◽  
A.N. Vegera ◽  
V.Y. Naumov

Studying closed gas turbine cycles on supercritical carbon dioxide is currently a promising issue in the development of power energy sector in terms of increasing energy efficiency and minimizing greenhouse gas emissions into the atmosphere. Combustion of methane with oxygen in the combustion chamber occurs not in the nitrogen environment, but in the environment of carbon dioxide, that is the working fluid of the cycle, which is an inhibitor of chemical reactions. A large mass content of such a diluent of the reaction mixture in the volume of the chamber leads to the risks of significant chemical underburning, efficiency decrease of the combustion chamber and the cycle as a whole. The aim of the research is to study the kinetic parameters of the combustion of methane with oxygen in a supercritical CO2 diluent medium to ensure reliable and stable combustion of fuel by assessing the degree of the inhibitory effect of CO2 and determining its permissible amount in the active combustion zone of the combustion chamber. The research method is a numerical simulation of turbulent-kinetic processes of methane combustion in the combustion chamber using the reduced methane combustion mechanism. Ansys Fluent software package has been used. The authers have studied the impact of CO2 diluent on fuel cоmbustion in methane-oxygen combustion chambers. It is found that the combustor flame stabilization takes place if the content of СО2 diluent supplied to the mixture with oxidizer is 0,46–0,5 of mass fraction; additional СО2 diluent forms local low temperature zones which slow down the combustion process. When this happens, adding cooling СО2 into the flame stabilization zone should be eliminated. The study has found that no more than 20 % of the total carbon dioxide content should be supplied to the combustion chamber; to stabilize the flame and reduce its length, it is necessary to install blades to swirl the fuel and oxidizer mixed with CO2 at the inlet of the combustion chamber; CO2 supply for cooling should be carried out not less than 130 mm away from the burner mouth.


Volume 4 ◽  
2004 ◽  
Author(s):  
Chang H. Oh ◽  
Richard L. Moore

The Idaho National Engineering and Environmental Laboratory (INEEL) has investigated a Brayton cycle efficiency improvement on a high temperature gas-cooled reactor (HTGR) as part of Generation-IV nuclear engineering research initiative. In this study, we are investigating helium Brayton cycles for the secondary side of an indirect energy conversion system. Ultimately we will investigate the improvement of the Brayton cycle using other fluids, such as supercritical carbon dioxide. Prior to the cycle improvement study, we established a number of baseline cases for the helium indirect Brayton cycle. The baseline cases are based on a 250 MW thermal pebble bed HTGR. In this study, we used the HYSYS computer code for optimization of the helium Brayton cycle and the balance of plant (BOP). In addition to the HYSYS process optimization, we performed parametric study to see the effect of important parameters on the cycle efficiency. For these parametric calculations, we also used a cycle efficiency model that was developed using the Visual Basic computer language. The results from this study are applicable to other reactor concepts such as a very high temperature gas-cooled reactor (VHTR), fast gas-cooled reactor (FGR), supercritical water reactor (SWR), and others. As part of this study we are currently investigated single-shaft vs. multiple shaft arrangement for cycle efficiency and comparison, which will be published in the next paper. The ultimate goal of this study is to use supercritical carbon dioxide for the HTGR power conversion loop in order to improve the cycle efficiency to values great than that of the helium Brayton cycle. This paper includes preliminary calculations of the steady state overall Brayton cycle efficiency based on the pebble bed reactor reference design (helium used as the working fluid) and compares those results with an initial calculation of a CO2 Brayton cycle.


1977 ◽  
Vol 99 (2) ◽  
pp. 237-245 ◽  
Author(s):  
C. F. McDonald ◽  
T. Van Hagan ◽  
K. Vepa

The Gas Turbine High Temperature Gas Cooled Reactor (GT-HTGR) power plant combines the existing design HTGR core with a closed-cycle helium gas turbine power conversion system directly in the reactor primary circuit. Unlike open-cycle gas turbines where the recuperative heat exchanger is an optional component, the high cycle efficiency of the nuclear closed-cycle gas turbine is attributable to a high degree to the incorporation of the recuperator (helium-to-helium) and precooler (helium-to-water) exchangers in the power conversion loop. For the integrated plant configuration, a nonintercooled cycle with a high degree of heat recuperation was selected on the basis of performance and economic optimization studies. A recuperator of high effectiveness was chosen because it significantly reduces the optimum pressure ratio (for maximum cycle efficiency), and thus reduces the number of compressor and turbine stages for the low molecular weight, high specific heat, helium working fluid. Heat rejection from the primary system is effected by a helium-to-water precooler, which cools the gas to a low level prior to compression. The fact that the rejection heat is derived from the sensible rather than the latent heat of the cycle working fluid results in dissipation over a wide band of temperature, the high average rejection temperature being advantageous for either direct air cooling or for generation of power in a waste heat cycle. The high heat transfer rates in the recuperator (3100 MWt) and precooler (1895 MWt), combined with the envelope restraints associated with heat exchanger integration in the prestressed concrete reactor vessel, require the use of more compact surface geometries than in contemporary power plant steam generators. Various aspects of surface geometry, flow configuration, mechanical design, fabrication, and integration of the heat exchangers are discussed for a plant in the 1100 MWe class. The influence of cycle parameters on the relative sizes of the recuperator and precooler are also presented. While the preliminary designs included are not meant to represent final solutions, they do embody features that satisfy many of the performance, structural, safety, and economic requirements.


2020 ◽  
Vol 22 (2) ◽  
pp. 585-592
Author(s):  
Jiri Polansky

AbstractThis paper deals with the thermo-hydraulic aspect of gas cooled fast 4 generation reactor. The paper is focused on the comparison of direct and indirect strategy of thermodynamics cycle of helium cooled reactor from the thermodynamics and turbomachinary point of view. The analyses respect pressure looses at all major part of the equipment - reactor, heat exchanger, pipe lines, etc. The compressor and gas turbines efficiency are includes in calculation as well. The working fluid in primary circuit is helium. In the secondary circuit a mixture of helium and nitrogen is considered. The Cycle characteristic point and efficiency calculation reflects mixture properties of the real gas. Calculation point out the influence of mixture composition on the basic structural parameters of the turbines, compressor and heat exchangers. Thermodynamics cycle efficiency, specific heat input/output, heat flux and cycle work will be presented as characteristic parameters.


Author(s):  
R. C. Wilcock ◽  
J. B. Young ◽  
J. H. Horlock

Although increasing the turbine inlet temperature has traditionally proved the surest way to increase cycle efficiency, recent work suggests that the performance of future gas turbines may be limited by increased cooling flows and losses. Another limiting scenario concerns the effect on cycle performance of real gas properties at high temperatures. Cycle calculations of uncooled gas turbines show that when gas properties are modelled accurately, the variation of cycle efficiency with turbine inlet temperature at constant pressure ratio exhibits a maximum at temperatures well below the stoichiometric limit. Furthermore, the temperature at the maximum decreases with increasing compressor and turbine polytropic efficiency. This behaviour is examined in the context of a two-component model of the working fluid. The dominant influences come from the change of composition of the combustion products with varying air/fuel ratio (particularly the contribution from the water vapour) together with the temperature variation of the specific heat capacity of air. There are implications for future industrial development programmes, particularly in the context of advanced mixed gas-steam cycles.


Author(s):  
Douglas C. Hofer ◽  
S. Can Gulen

A significant portion of the new electrical generating capacity installed in the past decade has employed heavy-duty gas turbines operating in a combined cycle configuration with a steam turbine bottoming cycle. In these power plants approximately 1/3 of the power is generated by the bottoming cycle. To ensure that the highest possible combined cycle efficiency is realized it is important to optimize the bottoming cycle efficiency and doing so requires a solid understanding of the efficiency entitlement. This paper describes a new technique for calculating the theoretical efficiency entitlement for a bottoming cycle that corresponds to the maximum possible bottoming cycle work and maximized combined cycle work and efficiency. This new method accounts for the decrease in ideal efficiency as the gas turbine exhaust is cooled as it transfers heat energy to the working fluid in the bottoming cycle. The new definition is compared to conventional definitions, including that of Carnot and an Exergy based second law efficiency, and shown to provide a simple and accurate analytical expression for the entitlement efficiency in a bottoming cycle. For representative cycle conditions, the entitlement efficiency for the bottoming cycle is calculated to be ∼45% compared to the Carnot efficiency for the same conditions of ∼67%. Although the new method is applicable to any power cycle obtaining its heat input from the exhaust stream of a topping cycle, special attention is given to the steam bottoming cycle traditionally used in modern gas turbine combined cycle power plants. Comparisons are made between the ideal bottoming cycle and variants of a steam cycle including a single pressure non-reheat and a three pressure reheat cycle. These comparisons explore the unavoidable loss in efficiency associated with constant temperature heat addition that occurs in the steam cycle.


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