Predicting the Performance of System for the Co-production of Fischer-Tropsch Synthetic Liquid and Power from Coal

2008 ◽  
Vol 130 (1) ◽  
Author(s):  
Xun Wang ◽  
Yunhan Xiao ◽  
Song Xu ◽  
Zhigang Guo
Keyword(s):  
Gas Turbine ◽  
Production System ◽  
Operating Conditions ◽  
Methane Yield ◽  
Chain Growth ◽  
Inlet Temperature ◽  
Co2 Removal ◽  
Total Production ◽  
Fischer Tropsch ◽  
Ft Synthesis

A co-production system based on Fischer-Tropsch (FT) synthesis reactor and gas turbine was simulated and analyzed. Syngas from entrained bed coal gasification was used as feedstock of the low-temperature slurry phase Fischer-Tropsch reactor. Raw synthetic liquid produced was fractioned and upgraded to diesel, gasoline, and liquid petrol gas (LPG). Tail gas composed of unconverted syngas and FT light components was fed to the gas turbine. Supplemental fuel (NG, or refinery mine gas) might be necessary, which was dependent on gas turbine capacity, expander through flow capacity, etc. FT yield information was important to the simulation of this co-production system. A correlation model based on Mobil’s two step pilot plant was applied. This model proposed triple chain-length-dependent chain growth factors and set up correlations among reaction temperatures with wax yield, methane yield, and C2–C22 paraffin and olefin yields. Oxygenates in the hydrocarbon, water, and vapor phases were also correlated with methane yield. It was suitable for syngas, iron catalyst, and slurry bed. We can show the effect of temperature on the products’ selectivity and distribution. User models that can predict product yields and cooperate with other units were embedded into Aspen plus simulation. Performance prediction of syngas fired gas turbine was the other key of this system. The increase in mass flow through the turbine affects the match between compressor and turbine operating conditions. The calculation was carried out by GS software developed by Politecnico Di Milano and Princeton University. The simulated performance assumed that the expander operates under choked conditions and turbine inlet temperature equals the NG fired gas turbine. A “F” technology gas turbine was selected to generate power. Various cases were investigated to match the FT synthesis island, power island, and gasification island in co-production systems. Effects of CO2 removal/LPG recovery, co-firing, and CH4 content variation were studied. Simulation results indicated that more than 50% of input energy was converted to electricity and FT products. Total yield of gasoline, diesel, and LPG was 136–155g∕Nm3(CO+H2). At coal feed of 21.9kg∕s, net electricity exported to the grid was higher than 100MW. Total production of diesel and gasoline (and LPG) was 118,000t(134,000t)∕year. Under the economic analysis conditions assumed in this paper, the co-production system was economically feasible. The after tax profits can research 17 million euro. Payback times ranged from 6 to 7 years.

Predicting the Performance of System for the Co-Production of Fischer-Tropsch Synthetic Liquid and Power From Coal

2007 ◽  
Author(s):  
Xun Wang ◽  
Yunhan Xiao
Keyword(s):  
Gas Turbine ◽  
Production System ◽  
Operating Conditions ◽  
Methane Yield ◽  
Chain Growth ◽  
Inlet Temperature ◽  
Co2 Removal ◽  
Total Production ◽  
Fischer Tropsch ◽  
Ft Synthesis

A co-production system based on FT synthesis reactor and gas turbine was simulated and analyzed. Syngas from entrained bed coal gasification was used as feedstock of low temperature slurry phase Fischer-Tropsch reactor. Raw synthetic liquid produced was fractioned and upgraded to diesel, gasoline and LPG. Tail gas composed of unconverted syngas and F-T light component was fed to gas turbine. Supplemental fuel (NG, or refinery mine gas) might be necessary, which was dependent on gas turbine capacity, expander through flow capacity, etc. FT yield information was important to the simulation of this co-production system. A correlation model based on Mobil’s two step pilot plant was applied. This model proposed triple chain-length-dependent chain growth factors and set up correlations among reaction temperature with wax yield, methane yield, and C2-C22 paraffin and olefin yields. Oxygenates in hydrocarbon phase, water phase and vapor phase were also correlated with methane yield. It was suitable for syngas, iron catalyst and slurry bed. It can show the effect of temperature on products’ selectivity and distribution. Deviations of C5+ components yields and distributions with reference data were less than 3%. To light gas components were less than 2%. User models available to predict product yields, distributions, cooperate with other units and do sensitive studies were embedded into Aspen plus simulation. Performance prediction of syngas fired gas turbine was the other key of this system. The increase in mass flow through the turbine affects the match between compressor and turbine operating conditions. The calculation was carried out by GS software developed by Politecnico Di Milano and Princeton University. The simulated performance assumed that the expander operates under choked conditions and turbine inlet temperature equals to NG fired gas turbine. A “F” technology gas turbine was selected to generate power. Various cases were investigated so as to match FT synthesis island, power island and gasification island in co-production systems. Effects of CO2 removal/LPG recovery, co-firing, CH4 content variation were studied. Simulation results indicated that more than 50% of input energy was converted to electricity and FT products. Total yield of gasoline, diesel and LPG was 136g-155g/NM3(CO+H2). At coal feed 21.9kg/s, net electricity exported to grid was higher than 100MW. Total production of diesel and gasoline (and LPG) was 118,000 tons(134,000tons)/Year. Under economic analysis conditions assumed in this paper, co-production system was economic feasible. The after tax profits can research 17 million EURO. Payback times were ranged from 6-7 years.

The Heat Transfer Performance of Porous Gas Turbine Blades

1968 ◽  
Vol 72 (696) ◽  
pp. 1087-1094 ◽  
Author(s):  
F. J. Bayley ◽  
A. B. Turner
Keyword(s):  
Gas Turbine ◽  
Turbine Blades ◽  
Engine Performance ◽  
Operating Conditions ◽  
Maximum Temperature ◽  
Specific Power ◽  
Working Fluid ◽  
Inlet Temperature ◽  
Turbine Inlet ◽  
Compression And Expansion

It is well known that the performance of the practical gas turbine cycle, in which compression and expansion are non-isentropic, is critically dependent upon the maximum temperature of the working fluid. In engines in which shaft-power is produced the thermal efficiency and the specific power output rise steadily as the turbine inlet temperature is increased. In jet engines, in which the gas turbine has so far found its greatest success, similar advantages of high temperature operation accrue, more particularly as aircraft speeds increase to utilise the higher resultant jet velocities. Even in high by-pass ratio engines, designed specifically to reduce jet efflux velocities for application to lower speed aircraft, overall engine performance responds very favourably to increased turbine inlet temperatures, in which, moreover, these more severe operating conditions apply continuously during flight, and not only at maximum power as with more conventional cycles.

Evaluation of GT Outboard Bleed Air on Overall Engine Efficiency and CO2e Emission in Natural Gas Compressor Stations

2013 ◽  
Author(s):  
K. K. Botros ◽  
H. Golshan ◽  
D. Rogers ◽  
B. Sloof
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Heat Rate ◽  
Operating Conditions ◽  
Process Conditions ◽  
Inlet Temperature ◽  
Predictive Tool ◽  
Valve Opening ◽  
Overall Efficiency ◽  
Engine Emission

Gas turbine (GT) engines employed in natural gas compressor stations operate in different modes depending on the power, turbine inlet temperature and shaft speeds. These modes apply different sequencing of bleed valve opening on the air compressor side of the engine. Improper selection of the GT and the driven centrifugal gas compressor operating conditions can lead to larger bleed losses due to wider bleed valve openings. The bleed loss inevitably manifests itself in the form of higher overall heat rate of the GT and greater engine emission. It is therefore imperative to determine and understand the engine and process conditions that drive the GT to operate in these different modes. The ultimate objective is to operate the engine away from the inefficient modes by adjusting the driven gas compressor parameters as well as the overall station operating conditions (i.e. load sharing, control set points, etc.). This paper describes a methodology to couple the operating conditions of the gas compressor to the modes of GT bleed valve opening (and the subsequent air bleed rates) leading to identification of the operating parameters for optimal performance (i.e., best overall efficiency and minimum CO2e emission). A predictive tool is developed to quantify the overall efficiency loss as a result of the different bleed opening modes, and map out the condition on the gas compressor characteristics. One year’s worth of operating data taken from two different compressor stations on TransCanada Pipelines’ Alberta system were used to demonstrate the methodology. The first station employs GE-LM1600 gas turbine driving a Cooper Rolls-RFBB-30 centrifugal compressor. The second station employs GE-LM-2500+ gas turbine driving NP PCL-800/N compressor. The analysis conclusively indicates that there are operating regions on the gas compressor maps where losses due to bleed valves are reduced and hence CO2 emissions are lowered, which presents an opportunity for operation optimization.

Chemical Analysis of Combustion Products From a High-Pressure Gas Turbine Combustor Rig Fueled by Jet A1 Fuel and a Fischer-Tropsch-Based Fuel

2006 ◽  
Author(s):  
Fredrik Hermann ◽  
Jens Klingmann ◽  
Rolf Gabrielsson ◽  
Jo¨rgen R. Pedersen ◽  
Jim O. Olsson ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Gas Turbine ◽  
Combustion Products ◽  
Jet Fuel ◽  
Synthetic Jet ◽  
Operating Conditions ◽  
Gas Chromatography Mass Spectrometry ◽  
Gas Turbine Combustor ◽  
Fischer Tropsch ◽  
Synthetic Fuel

A comparative experimental investigation has been performed, comparing the emissions from a synthetic jet fuel and from Jet A1. In the investigation, the unburned hydrocarbons were analyzed chemically and the regulated emissions of NOx, CO and HC were measured. All combustion tests were performed under elevated pressures in a gas turbine combustor rig. A Swedish company, Oroboros AB, has developed a novel clean synthetic jet fuel, LeanJet®. The fuel is produced synthetically from synthesis gas by a Fischer-Tropsch process. Except for the density, the fuel conforms to the Standard Specification for Aviation Turbine Fuels. The low density is due to the lack of aromatics and polyaromatics. Organic emissions from the gas turbine combustor rig were collected by adsorption sampling and analyzed chemically. Both the fuels and the organic emissions were analyzed by gas chromatography/flame ionization (GC/FID) complemented with gas chromatography/mass spectrometry (GC/MS). Under the operating conditions investigated, no significant differences were found for the regulated emissions, except for emission of CO from the synthetic fuel, which, at leaner conditions, was one-quarter of that measured for Jet A1. Detailed analysis of the organic compounds showed that the emissions from both fuels were dominated by fuel alkanes and a significant amount of naphthalene. It was also found that Jet A1 produced a much higher amount of benzene than the synthetic fuel.

Flashback Propensity of Syngas Flames at High Pressure: Diagnostic and Control

2010 ◽  
Author(s):  
S. Daniele ◽  
P. Jansohn ◽  
K. Boulouchos
Keyword(s):  
Control System ◽  
Gas Turbine ◽  
Turbulent Flame ◽  
Back Propagation ◽  
Combined Cycle ◽  
Operating Conditions ◽  
Inlet Temperature ◽  
Experimental Facility ◽  
Inlet Velocity ◽  
Turbulent Flame Speed

Nowadays, the establishment of IGCC (integrated gasification combined cycle) plants, prompts a growing interest in synthetic fuels for gas turbine based power generation. This interest has as direct consequence the need for understanding of flashback phenomena for premixed systems operated with H2-rich gases. This is due to the different properties of H2 (e.g. reactivity and diffusivity) with respect to CH4 which lead to higher flame speeds in the case of syngases (mixtures of H2-CO). This paper presents the results of experiments at gas turbine like conditions (pressure up to 15 bar, 0.2 < Φ < 0.7, 577K < T0 < 674K) aimed to determine flashback limits and their dependence on the combustion parameters (pressure, inlet temperature and inlet velocity). For the experimental facility used for this work the back propagation of the flame is believed to happen into the boundary layer of the fuel/air duct. Flashback propensity was found to have an appreciable dependence on pressure and inlet temperature while the effects of inlet velocity variations are weak. Explanations for the dependence on these three parameters, based on consideration on laminar and turbulent flame speed data (from modeling and experiments), are proposed. Within the frame of this work, in order to avoid major damages, the experimental facility was equipped with an automatic control system for flashback described in the paper. The control system is able to detect flame propagation into the fuel/air supply, arrest it and restore safe operating conditions by moving the flame out of the fuel/air section without blowing it out. This avoids destruction of components (burner/mixing) and time consuming shut downs of the test rig.

Improved Gas Turbine Efficiency Through Alternative Regenerator Configuration

2002 ◽  
Author(s):  
Paul A. Dellenback
Keyword(s):  
Gas Turbine ◽  
Operating Conditions ◽  
Cycle Performance ◽  
Inlet Temperature ◽  
Optimum Pressure ◽  
Model Calculations ◽  
Turbine Engine ◽  
Combustion Gases ◽  
Wide Range ◽  
Temperature Combustion

An alternative configuration for a regenerative gas turbine engine cycle is presented that yields higher cycle efficiencies than either simple or conventional regenerative cycles operating under the same conditions. The essence of the scheme is to preheat compressor discharge air with high temperature combustion gases before the latter are fully expanded across the turbine. The efficiency is improved because air enters the combustor at a higher temperature, and hence heat addition in the combustor occurs at a higher average temperature. The heat exchanger operating conditions are more demanding than for a conventional regeneration configuration, but well within the capability of modern heat exchangers. Models of cycle performance exhibit several percentage points of improvement relative to either simple cycles or conventional regeneration schemes. The peak efficiencies of the alternative regeneration configuration occur at optimum pressure ratios that are significantly lower than those required for the simple cycle. For example, at a turbine inlet temperature of 1300°C (2370°F), the alternative regeneration scheme results in cycle efficiencies of 50% for overall pressure ratios of 22, whereas simple cycles operating at the same temperature would yield efficiencies of only 43.8% at optimum pressure ratios of 50, which are not feasible with current compressor designs. Model calculations for a wide range of parameters are presented, as are comparisons with simple and conventional regeneration cycles.

Numerical Simulation on Gas Turbine Film Cooling of Curved Surface With Backward Injection

2012 ◽  
Author(s):  
Shashank Shetty ◽  
Xianchang Li ◽  
Ganesh Subbuswamy
Keyword(s):  
Numerical Simulation ◽  
Gas Turbine ◽  
Film Cooling ◽  
Gas Turbines ◽  
Turbine Blades ◽  
Operating Conditions ◽  
Strong Mixing ◽  
Inlet Temperature ◽  
Film Cooling Effectiveness ◽  
Aerodynamic Loss

Due to the unique role of gas turbine engines in power generation and aircraft propulsion, significant effort has been made to improve the gas turbine performance. As a result, the turbine inlet temperature is usually elevated to be higher than the metal melting point. Therefore, effective cooling of gas turbines is a critical task for engines’ efficiency as well as safety and lifetime. Film cooling has been used to cool the turbine blades for many years. The main issues related to film cooling are its poor coverage, aerodynamic loss, and increase of heat transfer coefficient due to strong mixing. To overcome these problems, film cooling with backward injection has been found to produce a more uniform cooling coverage under low pressure and temperature conditions and with simple cylindrical holes. Therefore, the focus of this paper is on the performance of film cooling with backward injection at gas turbine operating conditions. By applying numerical simulation, it is observed that along the centerline on both concave and convex surfaces, the film cooling effectiveness decreases with backward injection. However, cooling along the span is improved, resulting in more uniform cooling.

Gas Turbine Fouling: The Influence of Climate and Part-Load Operating Conditions

2019 ◽  
Author(s):  
Nicola Aldi ◽  
Nicola Casari ◽  
Mirko Morini ◽  
Michele Pinelli ◽  
Pier Ruggero Spina ◽  
...  
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Alternative Fuels ◽  
Environmental Influence ◽  
Electrical Power ◽  
Operating Conditions ◽  
Inlet Temperature ◽  
Continuous Increase ◽  
Part Load

Abstract Energy and climate change policies associated with the continuous increase in natural gas costs pushed governments to invest in renewable energy and alternative fuels. In this perspective, the idea to convert gas turbines from natural gas to syngas from biomass gasification could be a suitable choice. Biogas is a valid alternative to natural gas because of its low costs, high availability and low environmental impact. Syngas is produced with the gasification of plant and animal wastes and then burnt in gas turbine combustor. Although synfuels are cleaned and filtered before entering the turbine combustor, impurities are not completely removed. Therefore, the high temperature reached in the turbine nozzle can lead to the deposition of contaminants onto internal surfaces. This phenomenon leads to the degradation of the hot parts of the gas turbine and consequently to the loss of performance. The amount of the deposited particles depends on mass flow rate, composition and ash content of the fuel and on turbine inlet temperature (TIT). Furthermore, compressor fouling plays a major role in the degradation of the gas turbine. In fact, particles that pass through the inlet filters, enter the compressor and could deposit on the airfoil. In this paper, the comparison between five (5) heavy-duty gas turbines is presented. The five machines cover an electrical power range from 1 MW to 10 MW. Every model has been simulated in six different climate zones and with four different synfuels. The combination of turbine fouling, compressor fouling, and environmental conditions is presented to show how these parameters can affect the performance and degradation of the machines. The results related to environmental influence are shown quantitatively, while those connected to turbine and compressor fouling are reported in a more qualitative manner. Particular attention is given also to part-load conditions. The power units are simulated in two different operating conditions: 100 % and 80 % of power rate. The influence of this variation on the intensity of fouling is also reported.

scholarly journals Kinetic Modelling of the Aqueous-Phase Reforming of Fischer-Tropsch Water over Ceria-Zirconia Supported Nickel-Copper Catalyst

Catalysts ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 936 ◽  
Author(s):  
Irene Coronado ◽  
Aitor Arandia ◽  
Matti Reinikainen ◽  
Reetta Karinen ◽  
Riikka L. Puurunen ◽  
...  
Keyword(s):  
Kinetic Model ◽  
Aqueous Phase ◽  
Copper Catalyst ◽  
Operating Conditions ◽  
Packed Bed Reactor ◽  
Synthesis Process ◽  
Fischer Tropsch ◽  
Aqueous Phase Reforming ◽  
Ft Synthesis ◽  
Nickel Copper

In the Fischer–Tropsch (FT) synthesis, a mixture of CO and H2 is converted into hydrocarbons and water with diluted organics. This water fraction with oxygenated hydrocarbons can be processed through aqueous-phase reforming (APR) to produce H2. Therefore, the APR of FT water may decrease the environmental impact of organic waters and improve the efficiency of the FT process. This work aimed at developing a kinetic model for the APR of FT water. APR experiments were conducted with real FT water in a continuous packed-bed reactor at different operating conditions of temperature (210–240 °C), pressure (3.2–4.5 MPa) and weight hourly space velocity (WHSV) (40–200 h−1) over a nickel-copper catalyst supported on ceria-zirconia. The kinetic model considered C1-C4 alcohols as reactants, H2, CO, CO2 and CH4 as the gaseous products, and acetic acid as the only liquid product. The kinetic model included seven reactions, the reaction rates of which were expressed with power law equations. The kinetic parameters were estimated with variances and confidence intervals that explain the accuracy of the model to estimate the outlet liquid composition resulting from the APR of FT water. The kinetic model developed in this work may facilitate the development of APR to be integrated in a FT synthesis process.

scholarly journals Implementation of Adaptive Neuro-fuzzy Model to Optimize Operational Process of Multiconfiguration Gas-Turbines

2020 ◽  
Vol 2020 ◽  
pp. 1-17
Author(s):  
Chao Deng ◽  
Ahmed N. Abdalla ◽  
Thamir K. Ibrahim ◽  
MingXin Jiang ◽  
Ahmed T. Al-Sammarraie ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Power Output ◽  
Gas Turbines ◽  
Pressure Ratio ◽  
Operating Conditions ◽  
Inlet Temperature ◽  
Turbine Inlet Temperature ◽  
Anfis Model ◽  
Neuro Fuzzy ◽  
Compressor Efficiency

In this article, the adaptive neuro-fuzzy inference system (ANFIS) and multiconfiguration gas-turbines are used to predict the optimal gas-turbine operating parameters. The principle formulations of gas-turbine configurations with various operating conditions are introduced in detail. The effects of different parameters have been analyzed to select the optimum gas-turbine configuration. The adopted ANFIS model has five inputs, namely, isentropic turbine efficiency (Teff), isentropic compressor efficiency (Ceff), ambient temperature (T1), pressure ratio (rp), and turbine inlet temperature (TIT), as well as three outputs, fuel consumption, power output, and thermal efficiency. Both actual reported information, from Baiji Gas-Turbines of Iraq, and simulated data were utilized with the ANFIS model. The results show that, at an isentropic compressor efficiency of 100% and turbine inlet temperature of 1900 K, the peak thermal efficiency amounts to 63% and 375 MW of power resulted, which was the peak value of the power output. Furthermore, at an isentropic compressor efficiency of 100% and a pressure ratio of 30, a peak specific fuel consumption amount of 0.033 kg/kWh was obtained. The predicted results reveal that the proposed model determines the operating conditions that strongly influence the performance of the gas-turbine. In addition, the predicted results of the simulated regenerative gas-turbine (RGT) and ANFIS model were satisfactory compared to that of the foregoing Baiji Gas-Turbines.

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