Analysis of Single PEM Fuel Cell Performances Based on Current Density Distribution Measurement

2005 ◽  
Vol 3 (3) ◽  
pp. 351-357 ◽  
Author(s):  
P. C. Ghosh ◽  
T. Wüster ◽  
H. Dohle ◽  
N. Kimiaie ◽  
J. Mergel ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Density Distribution ◽  
Current Density ◽  
Operating Temperature ◽  
Current Density Distribution ◽  
Polymer Electrolyte Fuel Cells ◽  
Operating Conditions ◽  
Cathode Side ◽  
Gas Pressures

A new in situ measurement method of mapping the current density distribution in polymer electrolyte fuel cells (PEFC) is used to analyze the performance of a fuel cell under different operating conditions. The present method is useful in investigating the current density distribution in a single cell as well as a stack, which carries the information about the local reactant activity over the electrode area. It was found that the current density close to the gas inlets is strongly influenced by the reactants' relative humidity. The performance close to the gas outlets is greatly influenced by the inlet gas pressures and the stoichiometry factors of the reactant gases, mainly on the cathode side. It was also observed that the performance of the fuel cell drops with the increase in operating temperature if the reactant gases are not sufficiently humidified.

Dynamic Behavior and In-Situ Diagnostics of PEFCs

2006 ◽  
Author(s):  
Kaspar Andreas Friedrich ◽  
Till Kaz ◽  
Stefan Scho¨nbauer ◽  
Heinz Sander
Keyword(s):  
Fuel Cell ◽  
Density Distribution ◽  
Current Density ◽  
Single Cells ◽  
Current Density Distribution ◽  
Bipolar Plate ◽  
Life Cycles ◽  
Operating Conditions ◽  
Bipolar Plates

During fuel cell operation the electrochemical activity often is not homogenous over the electrode area. This may be caused by an non-uniform water content in the membrane, an inhomogeneous temperature distribution, and reactant gradients in the cell. Consequently a variation of the current density over the cell area occurs which tends to result in inferior performance. For in situ measurements of the current density distribution in fuel cell stacks a segmented bipolar plate was developed. The segmented bipolar plate was first tested in single cells with stack endplates to verify the function of all components. The tests showed that the measurement tool works very reliable and accurate. The insight in an operating fuel cell stack via current density distribution measurement is very helpful to investigate interactions between cells. Results can be used to validate models and to optimise stack components, e.g. flow field and manifold design, as well as to detect the best stack operating conditions. By applying segmented bipolar plates as sensor plates for stack system controls an improved performance, safe operation and longer life cycles can be achieved. The developed segmented bipolar plates with integrated current sensors were used to assemble a short stack consisting of 3 cells; each of them having an active area of 25cm2 divided into 49 segments. The design of the bipolar plate proofed very suitable for easy assembling of single cells and stacks. First measurement results show that different current distributions can appear in the cells and these can vary from cell to cell, depending on the operating conditions of the stack. Electrical coupling between the cells was investigated and found to be only marginal for the assembly used.

Effect of operating conditions on current density distribution and high frequency resistance in a segmented PEM fuel cell

2012 ◽  
Vol 37 (9) ◽  
pp. 7736-7744 ◽  
Author(s):  
Dietmar Gerteisen ◽  
Nada Zamel ◽  
Christian Sadeler ◽  
Florian Geiger ◽  
Victor Ludwig ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Density Distribution ◽  
Current Density ◽  
High Frequency ◽  
Current Density Distribution ◽  
Pem Fuel Cell ◽  
Operating Conditions

Effects of Operating Parameters on the Current Density Distribution in Proton Exchange Membrane Fuel Cells

2006 ◽  
Vol 3 (4) ◽  
pp. 464-476 ◽  
Author(s):  
Y. Zhang ◽  
A. Mawardi ◽  
R. Pitchumani
Keyword(s):  
Fuel Cell ◽  
Density Distribution ◽  
Current Density ◽  
Proton Exchange Membrane ◽  
Current Density Distribution ◽  
Pem Fuel Cell ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Local Current Density ◽  
Local Current

During the operation of a proton exchange membrane (PEM) fuel cell, significant variation of the local current density could exist across the cell causing sharp temperature and stress gradients in certain points, and affecting the water management, all of which severely impact the cell performance and reliability. The variation of local current density is a critical issue in the performance of PEM fuel cell, and is influenced by the operating conditions. This article presents a model-assisted parametric design with the objective of determining the operating conditions which maximize the fuel cell performance while maintaining a level of uniformity in the current density distribution. A comprehensive two-dimensional model is adopted to simulate the species transport and electrochemical phenomena in a PEM fuel cell. Numerical simulations are performed for over a wide range of operating conditions to analyze the effects of various operating parameters on the variation of local current density of the fuel cell, and to develop design windows which serve as guideline in the design for maximum power density, minimum reactant stoichiometry, and uniform current density distribution.

Direct Measurement of the Local Current Density Under Land-Channel Areas With Partially-Catalyzed MEAs

2012 ◽  
Author(s):  
Shan Jia ◽  
Hongtan Liu
Keyword(s):  
Fuel Cell ◽  
Current Density ◽  
Cell Voltage ◽  
Current Density Distribution ◽  
Cathode Side ◽  
High Cell ◽  
Land Area ◽  
Local Current Density ◽  
Local Current ◽  
Voltage Region

In a PEM fuel cell, local current density can vary drastically under the land and channel areas. The non-uniform current density distribution not only affects the overall performance of the fuel cell, but also leads to the local temperature and concentration differentiation on the MEA, which can cause problems such as membrane dehydration and catalyst degradations at certain locations. In order to investigate the local current performance, the objective of this work is to directly measure the local current density variations across the land and channel at the cathode in a PEM fuel cell with partially-catalyzed MEAs. First, the cathode flow plate is specially designed with a single-serpentine channel structure, and the gas diffusion electrode at cathode side is cut to fit this flow field size (5.0cm×1.3cm). Then five different partially-catalyzed MEAs with 1mm width corresponding to different locations from the middle of the gas channel to the middle of the land area are made. Fuel cells with each of the partially-catalyzed MEAs have been tested and the results provide the lateral current density distribution across the channel and the land areas. In the high cell voltage region, local current density is highest under the center of the land area and decreases toward the center of the channel area; while in the low cell voltage region local current density is highest under the middle of the channel area and decrease toward the center of the land area. Different flow rates are tested at the cathode side of the cell to study their effects on the local current density performance along the land-channel direction. And the results show that the flow rate barely has the effect on the current at the high cell voltage region, while it plays a significant role at the low voltage region due to the mass transport effect.

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