scholarly journals THERMAL, DYNAMIC MECHANICAL ANALYSIS AND MECHANICAL PROPERTIES OF POLYBUTYLENE TEREPHTHALATE/POLYETHYLENE TEREPHTHALATE BLENDS

2020 ◽  
Vol 82 (5) ◽  
Author(s):  
Muhammad Akmal Ahmad Saidi ◽  
Azman Hassan ◽  
Mat Uzir Wahit ◽  
Lai Jau Choy ◽  
Hazleen Anuar
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Dynamic Mechanical Analysis ◽  
Polyethylene Terephthalate ◽  
Mechanical Analysis ◽  
Polybutylene Terephthalate ◽  
Elongation At Break ◽  
Dynamic Mechanical

Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and mechanical tests were conducted to characterize the properties of polybutylene terephthalate/polyethylene terephthalate (PBT/PET) blends. PBT and PET were blended at different PBT/PET ratios (80/20, 60/40, 40/60, 20/80) via twin screw extruder prior to injection molding. DSC characterization showed a single glass transition temperature for all PBT/PET blends indicating that the miscibility occurred in the amorphous region. From DMA results, loss modulus and tan δ also showed a single peak for all PBT/PET blends, confirming the DSC results. At room temperature, PBT/PET 20/80 has the highest storage modulus followed by PBT/PET 80/20 blend. PET has higher tensile strength, flexural strength, Young’s and flexural modulus than PBT but lower in elongation at break and impact strength. PBT/PET 80/20 blend has the highest tensile strength, flexural strength, elongation at break, and impact strength compared to other PBT/PET blends. PBT/PET 80/20 blend can be suggested as an optimum formulation with balanced mechanical properties in terms of stiffness and toughness.

Direct Reactive Compatibilization of GMA on PE/Wood-Flour Composite

2011 ◽  
Vol 378-379 ◽  
pp. 735-739
Author(s):  
Yue Wen Li ◽  
Xin Hua Chen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Wood Flour ◽  
Reactive Extrusion ◽  
Rupture Surface ◽  
Elongation At Break ◽  
Reactive Compatibilization ◽  
Anchoring Strength

Reactive compatibilization between high-density polyethylene(HDPE) and wood-flour was achieved via direct reactive extrusion of glycidyl methacrylate(GMA), initiator, HDPE and wood-flour. Impact rupture surface of the composite was observed by scanning electron microscope(SEM), and its load deformation temperature(HDT) and mechanical properties were tested. Effect of GMA dosage and extrusion temperature on reactive compatibilization of the composite was analysed. The result indicated that the anchoring strength of interface in the composite was obviously strengthened, and its HDT, tensile strength, flexural strength, notched impact strength and elongation at break of the composite were distinctly improved due to the addition of GMA and dicumyl peroxide(DCP). When the composite was extruded at 180°C, the peak values of its HDT, tensile strength, flexural strength, elongation at break and notched impact strength respectively were 84°C, 40Mpa, 45Mpa, 11% and 6.6KJ.m-2, which respectively increased by 17°C, 74%, 36%, 83% and 69% than that of the composite without reactive compatibilization, and when the composite was extruded at 190°C, the peak values of its HDT, tensile strength, flexural strength, elongation at break and notched impact strength respectively were 84°C, 40Mpa, 44Mpa, 11% and 6.6KJ.m-2, which respectively increased by 20°C, 60%, 26%, 83% and 83% than that of the composite without reactive compatibilization. When GMA usage increased, the HDT and mechanical properties of the composite increased first, then descended, and the optimum usage of GMA was 1wt%-3wt%.

scholarly journals Tensile and dynamic mechanical analysis of the distal portion of mussel ( Mytilus edulis ) byssal threads

2007 ◽  
Vol 4 (17) ◽  
pp. 1159-1167 ◽  
Author(s):  
N Aldred ◽  
T Wills ◽  
D.N Williams ◽  
A.S Clare
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Glass Transition ◽  
Ultimate Tensile Strength ◽  
Tensile Stress ◽  
Thermal Cycling ◽  
Dynamic Mechanical Analysis ◽  
Mechanical Analysis ◽  
Distal Portion ◽  
Dynamic Mechanical

Dynamic mechanical analysis was used to record the behaviour of hydrated and dehydrated byssal threads under tensile stress and during dynamic thermal cycling. Fresh byssi, and byssi aged two weeks prior to testing, were used to further study the effects of age on the mechanical properties of this material. It was found that while older threads demonstrated increased stiffness, age did not necessarily affect their ultimate tensile strength. Dehydration had a more pronounced effect on thread stiffness and also increased the ultimate strength of the material. In their dry state, byssal threads displayed multiple yield points under tension and these, it is suggested, could equate to different phases within the bulk of the material. Dynamic analysis revealed glass transition ( T g ) and ecologically relevant operational temperatures for byssi, where their modulus ( E ′) remained constant. These discoveries are related to the ecological function of byssal threads and to the emerging field of biomimetics.

Mechanical Property Improvement of Poly(Butylene Succinate) by Reinforcing with Modified Fumed Silica

2014 ◽  
Vol 1025-1026 ◽  
pp. 215-220 ◽  
Author(s):  
Sasirada Weerasunthorn ◽  
Pranut Potiyaraj
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Fumed Silica ◽  
Tensile Modulus ◽  
Silica Particles ◽  
Melt Mixing ◽  
Butylene Succinate ◽  
Ir Spectrophotometry

Fumed silica particles (SiO2) were directly added into poly (butylene succinate) (PBS) by melt mixing process. The effects of amount of fumed silica particles on mechanical properties of PBS/fumed silica composites, those are tensile strength, tensile modulus, impact strength as well as flexural strength, were investigated. It was found that the mechanical properties decreased with increasing fumed silica loading (0-3 wt%). In order to increase polymer-filler interaction, fumed silica was treated with 3-glycidyloxypropyl trimethoxysilane (GPMS), and its structure was analyzed by FT-IR spectrophotometry. The PBS/modified was found to possess better tensile strength, tensile modulus, impact strength and flexural strength that those of PBS/fumed silica composites.

scholarly journals The Structure and Mechanical Properties of Hemp Fibers-Reinforced Poly(ε-Caprolactone) Composites Modified by Electron Beam Irradiation

2021 ◽  
Vol 11 (12) ◽  
pp. 5317
Author(s):  
Rafał Malinowski ◽  
Aneta Raszkowska-Kaczor ◽  
Krzysztof Moraczewski ◽  
Wojciech Głuszewski ◽  
Volodymyr Krasinskyi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Electron Beam ◽  
Impact Strength ◽  
Flexural Modulus ◽  
Natural Fibers ◽  
High Energy ◽  
Electron Radiation ◽  
Elongation At Break ◽  
Hemp Fibers

The need for the development of new biodegradable materials and modification of the properties the current ones possess has essentially increased in recent years. The aim of this study was the comparison of changes occurring in poly(ε-caprolactone) (PCL) due to its modification by high-energy electron beam derived from a linear electron accelerator, as well as the addition of natural fibers in the form of cut hemp fibers. Changes to the fibers structure in the obtained composites and the geometrical surface structure of sample fractures with the use of scanning electron microscopy were investigated. Moreover, the mechanical properties were examined, including tensile strength, elongation at break, flexural modulus and impact strength of the modified PCL. It was found that PCL, modified with hemp fibers and/or electron radiation, exhibited enhanced flexural modulus but the elongation at break and impact strength decreased. Depending on the electron radiation dose and the hemp fibers content, tensile strength decreased or increased. It was also found that hemp fibers caused greater changes to the mechanical properties of PCL than electron radiation. The prepared composites exhibited uniform distribution of the dispersed phase in the polymer matrix and adequate adhesion at the interface between the two components.

A novel recycled polyethylene terephthalate/polyamide 11 (rPET/PA11) thermoplastic blend

2021 ◽  
pp. 147776062110010
Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flexural Strength ◽  
Polyethylene Terephthalate ◽  
Practical Implication ◽  
Polyamide 11 ◽  
Recycled Polyethylene ◽  
Twin Screw ◽  
Electron Microscopy Analysis ◽  
The Impact

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.

scholarly journals Styrene–Acrylic Emulsion with “Transition Layer” for Damping Coating: Synthesis and Characterization

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1406
Author(s):  
Daoyuan Chen ◽  
Mingjin Ding ◽  
Zhixiong Huang ◽  
Yanbing Wang
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Transition Layer ◽  
Testing Machine ◽  
Dynamic Mechanical Properties ◽  
Mechanical Analysis ◽  
Latex Film ◽  
Seeded Emulsion Polymerization ◽  
Acrylic Emulsion ◽  
Dynamic Mechanical

In order to study the dynamic mechanical properties of styrene–acrylic latex with a core/shell structure, a variety of latexes were synthesized by semi-continuous seeded emulsion polymerization based on “particle design” with the same material. The latexes were characterized by rotary viscosimeter, dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR), transmission electron microscope (TEM), dynamic mechanical analysis (DMA), and universal testing machine. The effects of difference at the glass transition temperature (Tg) of core and shell and the introduction of the “transition layer” on the damping and mechanical properties of latex film were studied. The results indicate that as the Tg of core and shell gets closer, the better the compatibility of core and shell, from phase separation to phase continuity. Furthermore, the introduction of the “transition layer” can effectively improve the tensile strength and tan δ (max) of the latex film. The tensile strength and maximum loss factor (f = 1 Hz) of latex with the “transition layer” increased by 36.73% and 29.11% respectively compared with the latex without the “transition layer”. This work provides a reference for the design of emulsion for damping coating.

scholarly journals A pilot study of solvent-based cleaning of yellow ochre oil paint: effect on mechanical properties

2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Ashley Amanda Freeman ◽  
Judith Lee ◽  
Cecil Krarup Andersen ◽  
Naoki Fujisawa ◽  
Michał Łukomski ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Pilot Study ◽  
Dynamic Mechanical Analysis ◽  
Mechanical Analysis ◽  
Deionized Water ◽  
Dynamic Mechanical ◽  
Yellow Ochre ◽  
Mineral Spirits ◽  
Paint Films

AbstractNanoindentation and dynamic mechanical analysis were used to measure changes in the surface and bulk mechanical properties of Winsor & Newton Yellow Ochre oil paint films following exposure to deionized water, aliphatic mineral spirits (Shellsol D40™), and D5 silicone solvent (decamethylcyclopentasiloxane). Yellow ochre paint films were exposed to the selected solvents by 24-h immersion, and sponge-cleaning. 24-h immersion in deionised water and Shellsol D40 caused measurable changes to bulk and surface mechanical properties. However, there were no measurable changes to the bulk or surface mechanical properties following sponge cleaning.

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