The chlorine isotope composition of iron meteorites: Evidence for the Cl isotope composition of the solar nebula and implications for extensive devolatilization during planet formation

2019 ◽  
Vol 54 (7) ◽  
pp. 1619-1631
Author(s):  
Anthony Gargano ◽  
Zachary Sharp
Keyword(s):  
Planet Formation ◽  
Solar Nebula ◽  
Isotope Composition ◽  
Iron Meteorites ◽  
Chlorine Isotope

scholarly journals Chlorine isotope composition in chlorofluorocarbons CFC-11, CFC-12 and CFC-113 in firn, stratospheric and tropospheric air

2015 ◽  
Vol 15 (12) ◽  
pp. 6867-6877 ◽  
Author(s):  
S. J. Allin ◽  
J. C. Laube ◽  
E. Witrant ◽  
J. Kaiser ◽  
E. McKenna ◽  
...  
Keyword(s):  
Isotope Fractionation ◽  
Isotope Composition ◽  
Stratospheric Ozone ◽  
Standard Uncertainty ◽  
Gas Chromatography Mass Spectrometry ◽  
Sources And Sinks ◽  
Chlorine Isotope ◽  
Tropospheric Measurements ◽  
Single Detector

Abstract. The stratospheric degradation of chlorofluorocarbons (CFCs) releases chlorine, which is a major contributor to the destruction of stratospheric ozone (O3). A recent study reported strong chlorine isotope fractionation during the breakdown of the most abundant CFC (CFC-12, CCl2F2, Laube et al., 2010a), similar to effects seen in nitrous oxide (N2O). Using air archives to obtain a long-term record of chlorine isotope ratios in CFCs could help to identify and quantify their sources and sinks. We analyse the three most abundant CFCs and show that CFC-11 (CCl3F) and CFC-113 (CClF2CCl2F) exhibit significant stratospheric chlorine isotope fractionation, in common with CFC-12. The apparent isotope fractionation (ϵapp) for mid- and high-latitude stratospheric samples are respectively −2.4 (0.5) and −2.3 (0.4) ‰ for CFC-11, −12.2 (1.6) and −6.8 (0.8) ‰ for CFC-12 and −3.5 (1.5) and −3.3 (1.2) ‰ for CFC-113, where the number in parentheses is the numerical value of the standard uncertainty expressed in per mil. Assuming a constant isotope composition of emissions, we calculate the expected trends in the tropospheric isotope signature of these gases based on their stratospheric 37Cl enrichment and stratosphere–troposphere exchange. We compare these projections to the long-term δ (37Cl) trends of all three CFCs, measured on background tropospheric samples from the Cape Grim air archive (Tasmania, 1978–2010) and tropospheric firn air samples from Greenland (North Greenland Eemian Ice Drilling (NEEM) site) and Antarctica (Fletcher Promontory site). From 1970 to the present day, projected trends agree with tropospheric measurements, suggesting that within analytical uncertainties, a constant average emission isotope delta (δ) is a compatible scenario. The measurement uncertainty is too high to determine whether the average emission isotope δ has been affected by changes in CFC manufacturing processes or not. Our study increases the suite of trace gases amenable to direct isotope ratio measurements in small air volumes (approximately 200 mL), using a single-detector gas chromatography–mass spectrometry (GC–MS) system.

scholarly journals Chlorine isotope composition in chlorofluorocarbons CFC-11, CFC-12 and CFC-113 in firn, stratospheric and tropospheric air

2014 ◽  
Vol 14 (23) ◽  
pp. 31813-31841
Author(s):  
S. J. Allin ◽  
J. C. Laube ◽  
E. Witrant ◽  
J. Kaiser ◽  
E. McKenna ◽  
...  
Keyword(s):  
Isotope Fractionation ◽  
Isotope Composition ◽  
Stratospheric Ozone ◽  
Isotope Ratios ◽  
Gas Chromatography Mass Spectrometry ◽  
Chlorine Isotope ◽  
Site Model ◽  
Tropospheric Measurements ◽  
Single Detector

Abstract. The stratospheric degradation of chlorofluorocarbons (CFCs) releases chlorine, which is a major contributor to the destruction of stratospheric ozone (O3). A recent study reported strong chlorine isotope fractionation during the breakdown of the most abundant CFC (CFC-12, CCl2F2), similar to effects seen in nitrous oxide (N2O). Using air archives to obtain a long-term record of chlorine isotope ratios in CFCs could help to identify and quantify their sources and sinks. We analyse the three most abundant CFCs and show that CFC-11 (CCl3F) and CFC-113 (CClF2CCl2F) exhibit significant stratospheric chlorine isotope fractionation, in common with CFC-12. The apparent isotope fractionation (ϵapp) for mid- and high-latitude stratospheric samples are (−2.4 ± 0.5) and (−2.3 ± 0.4)‰ for CFC-11, (−12.2 ± 1.6) and (−6.8 ± 0.8)‰ for CFC-12 and (−3.5 ± 1.5) and (−3.3 ± 1.2)‰ for CFC-113, respectively. Assuming a constant source isotope composition, we estimate the expected trends in the tropospheric isotope signature of these gases due to their stratospheric 37Cl enrichment and stratosphere–troposphere exchange. We compare these model results to the long-term δ(37Cl) trends of all three CFCs, measured on background tropospheric samples from the Cape Grim air archive (Tasmania, 1978–2010) and tropospheric firn air samples from Greenland (NEEM site) and Antarctica (Fletcher Promontory site). Model trends agree with tropospheric measurements within analytical uncertainties. From 1970 to the present-day, we find no evidence for variations in chlorine isotope ratios associated with changes in CFC manufacturing processes. Our study increases the suite of trace gases amenable to direct isotope ratio measurements in small air volumes, using a single-detector gas chromatography-mass spectrometry system.

The Chlorine Isotope Composition of Earth's Mantle

Science ◽  
2008 ◽  
Vol 319 (5869) ◽  
pp. 1518-1520 ◽  
Author(s):  
M. Bonifacie ◽  
N. Jendrzejewski ◽  
P. Agrinier ◽  
E. Humler ◽  
M. Coleman ◽  
...  
Keyword(s):  
Isotope Composition ◽  
Chlorine Isotope ◽  
Earth’S Mantle

scholarly journals The bromine and chlorine isotope composition of primary halite deposits and their significance for the secular isotope composition of seawater

2019 ◽  
Vol 264 ◽  
pp. 13-29 ◽  
Author(s):  
H.G.M Eggenkamp ◽  
P. Louvat ◽  
P. Agrinier ◽  
M. Bonifacie ◽  
A. Bekker ◽  
...  
Keyword(s):  
Isotope Composition ◽  
Chlorine Isotope

scholarly journals Tungsten isotopic constraints on the age and origin of chondrules

2016 ◽  
Vol 113 (11) ◽  
pp. 2886-2891 ◽  
Author(s):  
Gerrit Budde ◽  
Thorsten Kleine ◽  
Thomas S. Kruijer ◽  
Christoph Burkhardt ◽  
Knut Metzler
Keyword(s):  
Planet Formation ◽  
Solar Nebula ◽  
Carbonaceous Chondrite ◽  
Critical Role ◽  
Parent Body ◽  
Uneven Distribution ◽  
Time Interval ◽  
Ordinary Chondrites ◽  
Chondrule Formation ◽  
Isotopic Constraints

Chondrules may have played a critical role in the earliest stages of planet formation by mediating the accumulation of dust into planetesimals. However, the origin of chondrules and their significance for planetesimal accretion remain enigmatic. Here, we show that chondrules and matrix in the carbonaceous chondrite Allende have complementary 183W anomalies resulting from the uneven distribution of presolar, stellar-derived dust. These data refute an origin of chondrules in protoplanetary collisions and, instead, indicate that chondrules and matrix formed together from a common reservoir of solar nebula dust. Because bulk Allende exhibits no 183W anomaly, chondrules and matrix must have accreted rapidly to their parent body, implying that the majority of chondrules from a given chondrite group formed in a narrow time interval. Based on Hf-W chronometry on Allende chondrules and matrix, this event occurred ∼2 million years after formation of the first solids, about coeval to chondrule formation in ordinary chondrites.

scholarly journals The Relationship of Meteoritic Parent Body Thermal Histories and Electromagnetic Heating by a Pre-Main Sequence T Tauri Sun

1971 ◽  
Vol 12 ◽  
pp. 239-245 ◽  
Author(s):  
C.P. Sonett
Keyword(s):  
Main Sequence ◽  
Solar Nebula ◽  
Parent Body ◽  
Convincing Evidence ◽  
Iron Meteorites ◽  
T Tauri ◽  
Diffusion Studies ◽  
Thermal Histories ◽  
Relationship Of ◽  
The Relationship

Convincing evidence exists that meteoritic matter was reheated shortly after the initial condensation of the solar nebula for those meteorites thought to be derived from parent bodies. This evidence takes the form of cooling rates carefully determined from diffusion studies of the migration rate of Ni across kamacite-taenite boundaries in iron meteorites (Fish, Goles, and Anders, 1960; Goldstein and Ogilvie, 1965; Goldstein and Short, 1967; Wood, 1964). The notion that the irons condensed directly from the solar nebula requires that these measurements and the existence of large Widmanstätten figures be explained as a condensation event. This seems rather unlikely and, in any event, requires a far more complex explanation than heating and melting in a parent body.

scholarly journals The chlorine isotopic composition of Martian meteorites 1: Chlorine isotope composition of Martian mantle and crustal reservoirs and their interactions

2016 ◽  
Vol 51 (11) ◽  
pp. 2092-2110 ◽  
Author(s):  
J. T. Williams ◽  
C. K. Shearer ◽  
Z. D. Sharp ◽  
P. V. Burger ◽  
F. M. McCubbin ◽  
...  
Keyword(s):  
Isotopic Composition ◽  
Isotope Composition ◽  
Chlorine Isotope ◽  
Martian Meteorites
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