Theoretical and experimental investigation of high-current solid-state opening switch based on solid solution (V/sub 1-x/Cr/sub x/)/sub 2/O/sub 3/

Author(s):  
Yu.B. Kudasov ◽  
I.V. Makarov ◽  
A.V. Filippov ◽  
V.A. Letyagin ◽  
M.P. Monakhov ◽  
...  
2021 ◽  
Vol 2 (1) ◽  
pp. 39-48
Author(s):  
Nguyen H. H. Phuc ◽  
Takaki Maeda ◽  
Tokoharu Yamamoto ◽  
Hiroyuki Muto ◽  
Atsunori Matsuda

A solid solution of a 100Li3PS4·xLi3PO4 solid electrolyte was easily prepared by liquid-phase synthesis. Instead of the conventional solid-state synthesis methods, ethyl propionate was used as the reaction medium. The initial stage of the reaction among Li2S, P2S5 and Li3PO4 was proved by ultraviolet-visible spectroscopy. The powder X-ray diffraction (XRD) results showed that the solid solution was formed up to x = 6. At x = 20, XRD peaks of Li3PO4 were detected in the prepared sample after heat treatment at 170 °C. However, the samples obtained at room temperature showed no evidence of Li3PO4 remaining for x = 20. Solid phosphorus-31 magic angle spinning nuclear magnetic resonance spectroscopy results proved the formation of a POS33− unit in the sample with x = 6. Improvements of ionic conductivity at room temperature and activation energy were obtained with the formation of the solid solution. The sample with x = 6 exhibited a better stability against Li metal than that with x = 0. The all-solid-state half-cell employing the sample with x = 6 at the positive electrode exhibited a better charge–discharge capacity than that employing the sample with x = 0.


Author(s):  
A.S. Boriskin ◽  
P.N. Burenkov ◽  
V.A. Demidov ◽  
P.I. Golyakov ◽  
S.A. Kazakov ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (4) ◽  
pp. 2019-2024 ◽  
Author(s):  
Jianming Deng ◽  
Aimei Yang ◽  
M. A. Farid ◽  
Hao Zhang ◽  
Jian Li ◽  
...  

The solid solution (Eu1−xMnx)MnO3−δ (0 ≤ x ≤ 0.126) has been synthesized using a conventional solid-state method.


1993 ◽  
Vol 29 (1) ◽  
pp. 911-914
Author(s):  
E.E. Bowles ◽  
W.G. Homeyer ◽  
J.M. Rawls ◽  
M.W. Heyse ◽  
J.B. Cornette ◽  
...  

2021 ◽  
Vol 1016 ◽  
pp. 990-996
Author(s):  
Takeshi Nagase

Fast electron irradiation can induce the solid-state amorphization (SSA) of many intermetallic compounds. The occurrence of SSA stimulated by fast electron irradiation was found in the Al0.5TiZrPdCuNi high-entropy alloy (HEA). The relationship between the occurrence of SSA in intermetallic compounds under fast electron irradiation and the empirical alloy parameters for predicting the solid-solution-formation tendency in HEAs was discussed. The occurrence of SSA in intermetallic compounds was hardly predicted, only by the alloy parameters of δ or ΔHmix, which have been widely used for predicting solid-solution formation in HEAs. All intermetallic compounds with ΔHmix ≤ -35 kJ/mol and those with δ ≥ 12.5 exhibit the occurrence of SSA. This implies that the intermetallic compounds with a largely negative ΔHmix value and a largely positive δ parameter are favorable for the occurrence of SSA.


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