New elements in Si technology-a contamination risk?

Author(s):  
W. Pamler
Keyword(s):  
Author(s):  
MARCO ANTONIO FERREIRA GOMES ◽  
CLÁUDIO A. SPADOTTO ◽  
VERA LÚCIA LANCHOTTE

Pretendeu-se mostrar que o herbicida Tebuthiuron, selecionado entre outros usados na cultura de cana-de-açúcar, oferece risco de contaminação para a água subterrânea em função de suas características físico-químicas, principalmente, quando aplicado em áreas de recarga direta de aqüíferos consideradas de alta vulnerabilidade natural. Assim, efetuou-se monitoramento do referido herbicida no período compreendido entre 1995 e 1999, coletando amostras de água de poço semi-artesiano, com 53 metros de profundidade, localizado na microbacia do Córrego Espraiado, município de Ribeirão Preto/SP, Brasil, no qual tem sido freqüente o uso do produto em questão. Para efeito de testemunha da amostra de água foi considerado um poço semi-artesiano de profundidade semelhante, localizado cerca de três quilômetros de distância do poço objeto de monitoramento. Os resultados obtidos mostraram que o Tebuthiuron está presente em todas as amostras analisadas, embora em concentrações abaixo do nível crítico para padrão de potabilidade, conforme os limites mais restritivos estabelecidos pela Organização Mundial de Saúde (para os pesticidas em uso é de 0,1 µg/L por pesticida e de 0,5 µg/L para pesticidas totais). Mesmo com os baixos valores de concentração encontrados fica evidente que o Tebuthiuron está atingindo a água subterrânea podendo aumentar sua concentração pela existência de condições ambientais favoráveis à preservação da molécula em profundidade (tais como baixa temperatura, baixa atividade biológica e ausência de luz). Caso o nível crítico seja atingido, o risco de contaminação poderia ser minimizado por meio da substituição do Tebuthiuron por outro herbicida com menor mobilidade no perfil do solo. OCCURRENCE OF THE HERBICIDE TEBUTHIURON IN GROUNDWATER OF ESPRAIADO CATCHMENT RIBEIRAO PRETO - SP (BRASIL) Abstract The herbicide Tebuthiuron, selected among others utilized in sugar-cane crop, shows groundwater contamination risk due to its physicochemical properties, mainly, when applied in direct recharge areas of aquifers considered of high natural vulnerability. In this context, the monitoring of this herbicide in the period of 1995 through 1999 was realized, by collecting water samples of aquifers 53 m depht, located in Espraiado catchment, Ribeirao Preto/SP (Brazil) in which the product has been extensively used. For blank assays it was utilized water samples collected similarly 3 Km away from the monitoring area. The results obtained showed that Tebuthiuron is present in all analyzed samples. Although in lower concentrations of the critical level for drinkable water, following the restrictive limits established by World Health Organization (for pesticides in use is 0,1 µg/L by pesticide and of 0,5 µg/L for total pesticides). Even if the low concentration values found it is evident that the Tebuthiuron affects the groundwater, and could enhance its concentration by favorable ambiental conditions for molecule preservation in deep water (such as low temperature, low biological activity and absence of light). The present scenary reflects contamination risk in case of reaching the critical level, which could only be minimized by the substitution of Thebuthiuron for other herbicide with lower soil mobility.


2021 ◽  
Vol 11 (7) ◽  
Author(s):  
Ratha Phok ◽  
Nandalal Kosgallana Duwage Wasantha ◽  
Weerakoon Sumana Bandara ◽  
Pitawala Herath Mudiyanselage Thalapitiye Ge ◽  
Dharmagunawardhane Hingure Arachchilage

AbstractGroundwater vulnerability assessment has become a crucial step in successfully protecting groundwater against pollution. An attempt of this study has been made to evaluate groundwater contamination risk using intrinsic vulnerability and land-uses in Vanathavillu, Kalpitiya and Katana area in Sri Lanka, using coupled DRASTIC with GIS as feasible methodology. The findings reveal that the groundwater in the areas under study falls under very low to high contamination risk. The higher risk of contamination has been identified in most of the Kalpitiya (about 82%) with the moderate along the beach in the west and next to Puttalam lagoon in the northeast and southeast. This is mainly due to pollution risk inherent with intense vegetable cultivation, over pumping, shallow groundwater tables and permeable sandy soil. Vanathavillu is under very low to moderate contamination risk, in which the moderate risk (about 13%) has especially been found the center, central southwest and west of the area. The relative less deep groundwater tables, possible seepage from the underlying limestone aquifer and less permeable red earth soil could be cause for the moderate risk in the area. Furthermore, results show that the Katana has low to moderately high groundwater contamination risk. Nitrate has a good agreement with the different pollution risk classes and that nitrate can be used as an indicator of aquifer degradation inherent with land-use activities in the coastal areas. Groundwater quality monitoring network should be set up to minimize the anthropogenic acts, particularly in high and moderate contamination risk zones.


2020 ◽  
Vol 115 ◽  
pp. 106424 ◽  
Author(s):  
Daniele la Cecilia ◽  
Giovanni M. Porta ◽  
Fiona H.M. Tang ◽  
Monica Riva ◽  
Federico Maggi

2012 ◽  
Vol 29 (4) ◽  
pp. 750-760 ◽  
Author(s):  
Osric Tening Forton ◽  
Veronica E. Manga ◽  
Aaron S. Tening ◽  
Akwinga V. Asaah

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