Time dependent polymerization on microfilled and small particle dental composites

Author(s):  
F. Malik ◽  
T.K. Vaidyanathan
Author(s):  
Gayle A. Laughlin ◽  
John L. Williams ◽  
J. David Eick

The purpose of this paper is to apply a finite deformation, elastic/viscoplastic approach to predict curing stresses in three light-cured dental composites, using Perzyna’s theory. Time-dependent constitutive parameters were obtained from mercury dilatometry, dynamic mechanical analysis and constrained shrinkage strerss testing. The numerical approach was verified by using the results of an experiment on a simple aluminum tooth model of a cavity preparation that was bulk-filled with light-cured dental composite restorative materials. The numerically predicted strain patterns were similar to those seen experimentally for the three different dental composites.


Author(s):  
H.-J. Ou

The understanding of the interactions between the small metallic particles and ceramic surfaces has been studied by many catalyst scientists. We had developed Scanning Reflection Electron Microscopy technique to study surface structure of MgO hulk cleaved surface and the interaction with the small particle of metals. Resolutions of 10Å has shown the periodic array of surface atomic steps on MgO. The SREM observation of the interaction between the metallic particles and the surface may provide a new perspective on such processes.


Author(s):  
B. M. Culbertson ◽  
M. L. Devinev ◽  
E. C. Kao

The service performance of current dental composite materials, such as anterior and posterior restoratives and/or veneer cements, needs to be improved. As part of a comprehensive effort to find ways to improve such materials, we have launched a broad spectrum study of the physicochemical and mechanical properties of photopolymerizable or visible light cured (VLC) dental composites. The commercially available VLC materials being studied are shown in Table 1. A generic or neat resin VLC system is also being characterized by SEM and TEM, to more fully understand formulation variables and their effects on properties.At a recent dental research meeting, we reported on the differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) characterization of the materials in Table 1. It was shown by DSC and DMA that the materials are substantially undercured by commonly used VLC techniques. Post curing in an oral cavity or a dry environment at 37 to 50°C for 7 or more hours substantially enhances the cure of the materials.


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