The Effect of Grain Size and Volume Fraction on Charge Transport in Thermoelectric Nanocomposite of Bi2Te3-Sb2Te3

Author(s):  
Payam Norouzzadeh ◽  
Daryoosh Vashaee
2014 ◽  
Vol 922 ◽  
pp. 568-573
Author(s):  
Victor Carretero Olalla ◽  
N. Sanchez Mouriño ◽  
Philippe Thibaux ◽  
Leo Kestens ◽  
Roumen H. Petrov

Control of ductile fracture propagation is one of the major concerns for pipeline industry, particularly with the increasing demand of new control rolled steel grades required to maintain integrity at high operational pressures. The objective of this research is to understand which microstructural features govern crack propagation, and to analyse the effect of two of them (average grain size, and volume fraction of pearlite). The main disadvantage during classical Charpy test was to discriminate the crack initiation and propagation energy during fracture of a notched sample. The initiation appears to be caused by the stress state in the neighbouring of Ti-containing precipitates or pearlite particles (no presence of M/A constituents or MnS inclusions was detected in the evaluated grades), propagation-arrest of the crack is assumed to play the main role concerning the control of fracture. Our approach to characterize the fracture resistance is to measure the energy absorbed during the crack propagation stage by means of load-displacement curves obtained via instrumented Charpy test. It was observed that the energy absorbed during crack propagation is not influenced by the average grain size but by the fraction and the morphological (banded-not banded) distribution of second pearlitic phase. This suggests that a different approach to characterize the heterogeneities in grain size clustering might be followed to correlate the energy measured during crack propagation and the morphological features of the steel.


2013 ◽  
Vol 275-277 ◽  
pp. 1833-1837
Author(s):  
Ke Lu Wang ◽  
Shi Qiang Lu ◽  
Xin Li ◽  
Xian Juan Dong

A Johnson-Mehl-Avrami-Kolmogorov (JMAK)-model was established for dynamic recrystallization in hot deformation process of 52100 steel. The effects of hot deformation temperature, true strain and strain rate on the microstructural evolution of the steel were physically studied by using Gleeble-1500 thermo-mechanical simulator and the experimental results were used for validation of the JMAK-model. Through simulation and experiment, it is found that the predicted results of DRX volume fraction, DRX grain size and average grain size are in good agreement with the experimental ones.


2010 ◽  
Vol 2010 ◽  
pp. 1-16 ◽  
Author(s):  
Yngve Bergström ◽  
Ylva Granbom ◽  
Dirk Sterkenburg

A dislocation model, accurately describing the uniaxial plastic stress-strain behavior of dual phase (DP) steels, is proposed and the impact of martensite content and ferrite grain size in four commercially produced DP steels is analyzed. It is assumed that the plastic deformation process is localized to the ferrite. This is taken into account by introducing a nonhomogeneity parameter, f(ε), that specifies the volume fraction of ferrite taking active part in the plastic deformation process. It is found that the larger the martensite content the smaller the initial volume fraction of active ferrite which yields a higher initial deformation hardening rate. This explains the high energy absorbing capacity of DP steels with high volume fractions of martensite. Further, the effect of ferrite grain size strengthening in DP steels is important. The flow stress grain size sensitivity for DP steels is observed to be 7 times larger than that for single phase ferrite.


2011 ◽  
Vol 347-353 ◽  
pp. 870-873
Author(s):  
Chun Rong Xue

Nanocrystalline silicon film has become the research hit of today’ s P-V solar technology. It’s optical band gap was controlled through changing the grain size and crystalline volume fraction for the quanta dimension effect. The crystalline volume fraction in nc-Si:H is modulated by varying the hydrogen concentration in the silane plasma. Also, the crystallinity of the material increases with increasing hydrogen dilution ratio, the band tail energy width of the nc-Si:H concurrently decreases. Two sets of nc-Si:H solar cells were made with different layer thicknesss, their electronic and photonic bandgap, absorption coefficient, optical band gap, nanocrystalline grain size(D), and etc have been stuied. In addition, we discussed the relationship between the stress of nc-Si thin films and H2 ratio. At last nc-Si:H solar cells have been designed and prepared successfully in the optimized processing parameters.


2007 ◽  
Vol 558-559 ◽  
pp. 1201-1206 ◽  
Author(s):  
Mihaela Teodorescu ◽  
Patrice Lasne ◽  
Roland E. Logé

The present work concerns the simulation of metallurgical evolutions in 3D multi-pass forming processes. In this context, the analyzed problem is twofold. One point refers to the management of the microstructure evolution during each pass or each inter-pass period and the other point concerns the management of the multi-pass aspects (different grain categories, data structure). In this framework, a model is developed and deals with both aspects. The model considers the microstructure as a composite made of a given (discretized) number of phases which have their own specific properties. The grain size distribution and the recrystallized volume fraction distribution of the different phases evolve continuously during a pass or inter-pass period. With this approach it is possible to deal with the heterogeneity of the microstructure and its evolution in multi-pass conditions. Both dynamic and static recrystallization phenomena are taken into account, with typical Avrami-type equations. The present model is implemented in the Finite Element code FORGE2005®. 3D numerical simulation results for a multi-pass process are presented.


2012 ◽  
Vol 191 ◽  
pp. 145-150 ◽  
Author(s):  
Michał Stopyra ◽  
Robert Jarosz ◽  
Andrzej Kiełbus

The paper presents analysis of section thickness’ influence on microstructure of Elektron 21 and QE22 magnesium alloys in the form of a stepped casting test. Solid solution grain size and volume fraction of eutectic areas were measured using light microscope and sterological methods. The results showed the significant increase of grain size caused by wall thickness and its slight decrease connected with the distance beetwen analysed section and the gating system. This relationship was confirmed using statistical methods. QE22 alloy demonstrated finer grain structure than Elektron 21 alloy as well as lesser susceptibility of grain size to solidification conditions


2017 ◽  
Vol 140 (2) ◽  
Author(s):  
B. Ravi Kumar ◽  
Vishal Singh ◽  
Tarun Nanda ◽  
Manashi Adhikary ◽  
Nimai Halder ◽  
...  

The authors simulated the industrially used continuous annealing conditions to process dual phase (DP) steels by using a custom designed annealing simulator. Sixty-seven percentage of cold rolled steel sheets was subjected to different processing routes, including the conventional continuous annealing line (CAL), intercritical annealing (ICA), and thermal cycling (TC), to investigate the effect of change in volume fraction, shape, and spatial distribution of martensite on tensile deformation characteristics of DP steels. Annealing parameters were derived using commercial software, including thermo-calc, jmat-pro, and dictra. Through selection of appropriate process parameters, the authors found out possibilities of significantly altering the volume fraction, morphology, and grain size distribution of martensite phase. These constituent variations showed a strong influence on tensile properties of DP steels. It was observed that TC route modified the martensite morphology from the typical lath type to in-grain globular/oblong type and significantly reduced the martensite grain size. This route improved the strength–ductility combination from 590 MPa–33% (obtained through CAL route) to 660 MPa–30%. Finally, the underlying mechanisms of crack initiation/void formation, etc., in different DP microstructures were discussed.


2005 ◽  
Vol 495-497 ◽  
pp. 609-614
Author(s):  
Michael Ferry

The effect of fine particles on the uniformity of grain coarsening in a submicron grained Al-Sc alloy containing significant local variations in texture has been investigated using high resolution EBSD. The alloy was processed by severe plastic deformation and low temperature ageing to generate a fine-grained (0.8 µm diameter) microstructure containing either a dispersion of nanosized Al3Sc particles or a particle-free matrix. The initial processing generated a uniform grain size distribution, but the distribution of grain orientations was inhomogeneous with the microstructure containing colonies of grains consisting predominantly of either HAGBs or LAGBs with the latter possessing orientation gradients of up to 10 o/µm. Despite the marked differences in boundary character between these regions, the alloy undergoes slow and uniform grain coarsening during annealing at temperatures up to 500 oC with no marked change in the grain size distribution, boundary distribution and texture. A model of grain coarsening that takes into account the influence of fine particles on the kinetics of grain growth within an orientation gradient is outlined. The model predicts that a large volume fraction of fine particles (large f/r-value) tends to homogenize the overall rate of grain coarsening despite the presence of orientation gradients in the microstructure.


Metals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1019 ◽  
Author(s):  
Angella ◽  
Donnini ◽  
Ripamonti ◽  
Górny ◽  
Zanardi

Tensile testing on ductile iron GJS 400 with different microstructures produced through four different cooling rates was performed in order to investigate the relevance of the microstructure’s parameters on its plastic behaviour. Tensile flow curve modelling was carried out with the Follansbee and Estrin-Kocks-Mecking approach that allowed for an explicit correlation between plastic behaviour and some microstructure parameters. In the model, the ferritic grain size and volume fraction of pearlite and ferrite gathered in the first part of this investigation were used as inputs, while other parameters, like nodule count and interlamellar spacing in pearlite, were neglected. The model matched very well with the experimental flow curves at high strains, while some mismatch was found only at small strains, which was ascribed to the decohesion between the graphite nodules and the ferritic matrix that occurred just after yielding. It can be concluded that the plastic behaviour of GJS 400 depends mainly on the ferritic grain size and pearlitic volume fraction, and other microstructure parameters can be neglected, primarily because of their high nodularity and few defects.


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