Squeezing lone pairs: TheA17 toA7 pressure-induced phase transition in black phosphorus

2012 ◽  
Vol 85 (1) ◽  
Author(s):  
Salah Eddine Boulfelfel ◽  
Gotthard Seifert ◽  
Yuri Grin ◽  
Stefano Leoni
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
Lone Pairs

Charged impurity-tuning of midgap states in biased Bernal bilayer black phosphorus: an anisotropic electronic phase transition

2018 ◽  
Vol 20 (38) ◽  
pp. 25044-25051 ◽  
Author(s):  
P. T. T. Le ◽  
K. Mirabbaszadeh ◽  
M. Davoudiniya ◽  
M. Yarmohammadi
Keyword(s):  
Phase Transition ◽  
Electric Field ◽  
Green’S Function ◽  
Green's Function ◽  
Black Phosphorus ◽  
Function Technique ◽  
Continuum Approximation ◽  
Charged Impurity ◽  
Electronic Phase ◽  
The Continuum

Tuning of the electronic phase of Bernal bilayer black phosphorus was investigated using a charged impurity and an electric field beyond the continuum approximation: the Green's function technique.

Pressure quenching: a new route for the synthesis of black phosphorus

2018 ◽  
Vol 5 (3) ◽  
pp. 669-674 ◽  
Author(s):  
Qiushi Sun ◽  
Xudong Zhao ◽  
Yi Feng ◽  
Yunpeng Wu ◽  
Ziqing Zhang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
Red Phosphorus ◽  
Quenching Method ◽  
Pressure Quenching

The phase transition was observed between red phosphorus and black phosphorus under 0.5 GPa by using pressure quenching method.

scholarly journals Bending-induced phase transition in monolayer black phosphorus

2015 ◽  
Vol 24 (8) ◽  
pp. 086401 ◽  
Author(s):  
Dou-Xing Pan ◽  
Tzu-Chiang Wang ◽  
Wan-Lin Guo
Keyword(s):  
Phase Transition ◽  
Black Phosphorus

Amine-induced phase transition from white phosphorus to red/black phosphorus for Li/K-ion storage

2019 ◽  
Vol 55 (47) ◽  
pp. 6751-6754 ◽  
Author(s):  
Yang Li ◽  
Song Jiang ◽  
Yong Qian ◽  
Ying Han ◽  
Jie Zhou ◽  
...  
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
White Phosphorus ◽  
Red Phosphorus ◽  
Novel Approach ◽  
Ion Storage

A novel approach of phase transition via amines-induced is designed to obtain red phosphorus and black phosphorus.

Reversible Pressure-Induced Partial Phase Transition in Few-Layer Black Phosphorus

Nano Letters ◽  
2020 ◽  
Vol 20 (8) ◽  
pp. 5929-5935
Author(s):  
Anirban Kundu ◽  
Damien Tristant ◽  
Natalya Sheremetyeva ◽  
Anthony Yoshimura ◽  
Abraao Torres Dias ◽  
...  
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
Partial Phase

scholarly journals Pressure-induced phase transitions and superconductivity in a black phosphorus single crystal

2018 ◽  
Vol 115 (40) ◽  
pp. 9935-9940 ◽  
Author(s):  
Xiang Li ◽  
Jianping Sun ◽  
Prashant Shahi ◽  
Miao Gao ◽  
Allan H. MacDonald ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Pressure ◽  
Single Crystal ◽  
Transport Properties ◽  
Density Functional ◽  
Black Phosphorus ◽  
Cubic Phase ◽  
Superconducting Transition ◽  
Quantum Oscillations ◽  
Mr Effect

We report a thorough study of the transport properties of the normal and superconducting states of black phosphorus (BP) under magnetic field and high pressure with a large-volume apparatus that provides hydrostatic pressure to induce transitions from the layered A17 phase to the layered A7 phase and to the cubic phase of BP. Quantum oscillations can be observed atP≥ 1 GPa in both resistivity and Hall voltage, and their evolutions with pressure in the A17 phase imply a continuous enlargement of Fermi surface. A significantly large magnetoresistance (MR) at low temperatures is observed in the A7 phase that becomes superconducting below a superconducting transition temperatureTc∼ 6–13 K.Tcincreases continuously with pressure on crossing the A7 to the cubic phase boundary. The strong MR effect can be fit by a modified Kohler’s rule. A correlation betweenTcand fitting parameters suggests that phonon-mediated interactions play dominant roles in driving the Cooper pairing, which is further supported by our density functional theory (DFT) calculations. The change of effective carrier mobility in the A17 phase under pressure derived from the MR effect is consistent with that obtained from the temperature dependence of the quantum oscillations. In situ single-crystal diffraction under high pressure indicates a total structural reconstruction instead of simple stretching of the A17 phase layers in the A17-to-A7-phase transition. This finding helps us to interpret transport properties on crossing the phase transition under high pressure.

Magnetic field-induced electronic phase transition in the Dirac semimetal state of black phosphorus under pressure

2018 ◽  
Vol 63 (23) ◽  
pp. 1539-1544 ◽  
Author(s):  
Zeliang Sun ◽  
Ziji Xiang ◽  
Zhongyi Wang ◽  
Jinglei Zhang ◽  
Long Ma ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Phase Transition ◽  
Black Phosphorus ◽  
Dirac Semimetal ◽  
Electronic Phase

A Novel Mild Phase-Transition to Prepare Black Phosphorus Nanosheets with Excellent Energy Applications

Small ◽  
2016 ◽  
Vol 13 (7) ◽  
pp. 1602243 ◽  
Author(s):  
Gang Zhao ◽  
Tailin Wang ◽  
Yongliang Shao ◽  
Yongzhong Wu ◽  
Baibiao Huang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
Energy Applications
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