Pressure quenching: a new route for the synthesis of black phosphorus

2018 ◽  
Vol 5 (3) ◽  
pp. 669-674 ◽  
Author(s):  
Qiushi Sun ◽  
Xudong Zhao ◽  
Yi Feng ◽  
Yunpeng Wu ◽  
Ziqing Zhang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
Red Phosphorus ◽  
Quenching Method ◽  
Pressure Quenching

The phase transition was observed between red phosphorus and black phosphorus under 0.5 GPa by using pressure quenching method.

Amine-induced phase transition from white phosphorus to red/black phosphorus for Li/K-ion storage

2019 ◽  
Vol 55 (47) ◽  
pp. 6751-6754 ◽  
Author(s):  
Yang Li ◽  
Song Jiang ◽  
Yong Qian ◽  
Ying Han ◽  
Jie Zhou ◽  
...  
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
White Phosphorus ◽  
Red Phosphorus ◽  
Novel Approach ◽  
Ion Storage

A novel approach of phase transition via amines-induced is designed to obtain red phosphorus and black phosphorus.

Preparation of a graphene–phosphorene composite by pressure quenching and its ferromagnetism

2020 ◽  
Vol 56 (13) ◽  
pp. 2016-2019
Author(s):  
Yunpeng Wu ◽  
Qiushi Sun ◽  
Deyang Yu ◽  
Yifei Teng ◽  
Xilong Liu ◽  
...  
Keyword(s):  
One Step ◽  
Quenching Method ◽  
Strong Ferromagnetism ◽  
Pressure Quenching

A graphene–phosphorene composite was fabricated by a pressure quenching method in one step and it shows strong ferromagnetism.

The mechanism of structural changes and crystallization kinetics of amorphous red phosphorus to black phosphorus under high pressure

2019 ◽  
Vol 55 (56) ◽  
pp. 8094-8097 ◽  
Author(s):  
Heng Xiang ◽  
Yuting Nie ◽  
Hechuang Zheng ◽  
Xuhui Sun ◽  
Xueliang Sun ◽  
...  
Keyword(s):  
High Pressure ◽  
Crystallization Kinetics ◽  
Structural Changes ◽  
Black Phosphorus ◽  
Crystallization Mechanism ◽  
Red Phosphorus ◽  
Kinetics Of

Revealing the untraditional crystallization mechanism of amorphous red phosphorus to black phosphorus under high pressure.

An easy route to synthesize high-quality black phosphorus from amorphous red phosphorus

2019 ◽  
Vol 236 ◽  
pp. 56-59 ◽  
Author(s):  
G. Tiouitchi ◽  
M. Ait Ali ◽  
A. Benyoussef ◽  
M. Hamedoun ◽  
A. Lachgar ◽  
...  
Keyword(s):  
Black Phosphorus ◽  
Red Phosphorus ◽  
High Quality

Boundary Lubricating Properties of Black Phosphorus Nanosheets in Polyalphaolefin Oil

2019 ◽  
Vol 141 (7) ◽  
Author(s):  
Yufu Xu ◽  
Jingyuan Yu ◽  
Yinghui Dong ◽  
Tao You ◽  
Xianguo Hu
Keyword(s):  
Boundary Lubrication ◽  
Laser Scanning ◽  
Chemical Elements ◽  
Black Phosphorus ◽  
3D Laser Scanning ◽  
Red Phosphorus ◽  
Scanning Microscope ◽  
Lubrication Regime ◽  
Tribological Application ◽  
Lubricating Properties

As a novel layered material, black phosphorus (BP) shows unexpected characteristics in many aspects including tribological application. In this work, BP was prepared through ball milling from red phosphorus (RP). The boundary lubricating properties of the BP nanosheets were investigated on a ball-on-disk tribometer as lubricating additives in polyalphaolefin oil. The micromorphologies, concentration, and composition of the typical chemical elements on the worn surfaces were measured by the 3D laser scanning microscope, scanning electron microscope, and X-ray photoelectron spectrometer, respectively. The results show that bulk BP can be found after RP was milled at 500 rpm for 36 h. The Raman intensity of the BP increased initially and then decreased with the increase in milling time, and the maximum intensity can be obtained at 60 h. The BP nanosheets displayed excellent antifriction and anti-wear performances as lubricating additives in PAO6 oil for steel/steel contact in boundary lubrication regime. The boundary lubrication mechanism of the BP nanosheets is dominated by the physical slippery effect of the laminated nanosheets and the tribofilm on the rubbing surfaces.

Squeezing lone pairs: TheA17 toA7 pressure-induced phase transition in black phosphorus

2012 ◽  
Vol 85 (1) ◽  
Author(s):  
Salah Eddine Boulfelfel ◽  
Gotthard Seifert ◽  
Yuri Grin ◽  
Stefano Leoni
Keyword(s):  
Phase Transition ◽  
Black Phosphorus ◽  
Lone Pairs

Crystallization kinetics of amorphous red phosphorus to black phosphorus by chemical vapor transport

CrystEngComm ◽  
2021 ◽  
Author(s):  
Shuai Zhang ◽  
Shufang Ma ◽  
Xiaodong Hao ◽  
Qingming Liu ◽  
Yan yan Hou ◽  
...  
Keyword(s):  
Optoelectronic Devices ◽  
Chemical Vapor ◽  
Structural Features ◽  
Black Phosphorus ◽  
Vapor Transport ◽  
Chemical Vapor Transport ◽  
Red Phosphorus ◽  
Broad Application ◽  
Kinetics Of ◽  
Application Prospects

Black phosphorus (BP) is an emerging two-dimensional semiconductor material, which has interesting structural features and broad application prospects in the fields of optoelectronic devices, energy storage, and biomedicine. However, a...

Charged impurity-tuning of midgap states in biased Bernal bilayer black phosphorus: an anisotropic electronic phase transition

2018 ◽  
Vol 20 (38) ◽  
pp. 25044-25051 ◽  
Author(s):  
P. T. T. Le ◽  
K. Mirabbaszadeh ◽  
M. Davoudiniya ◽  
M. Yarmohammadi
Keyword(s):  
Phase Transition ◽  
Electric Field ◽  
Green’S Function ◽  
Green's Function ◽  
Black Phosphorus ◽  
Function Technique ◽  
Continuum Approximation ◽  
Charged Impurity ◽  
Electronic Phase ◽  
The Continuum

Tuning of the electronic phase of Bernal bilayer black phosphorus was investigated using a charged impurity and an electric field beyond the continuum approximation: the Green's function technique.

A black/red phosphorus hybrid as an electrode material for high-performance Li-ion batteries and supercapacitors

2017 ◽  
Vol 5 (14) ◽  
pp. 6581-6588 ◽  
Author(s):  
Xinhang Chen ◽  
Guanghua Xu ◽  
Xiaohui Ren ◽  
Zhongjun Li ◽  
Xiang Qi ◽  
...  
Keyword(s):  
Electrode Material ◽  
High Performance ◽  
Black Phosphorus ◽  
Sonochemical Method ◽  
Li Ion Batteries ◽  
Red Phosphorus ◽  
Li Ion

A single elemental hybrid composed of black phosphorus (BP) and red phosphorus (RP) is synthesized via a feasible sonochemical method.

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