scholarly journals Electronic structure of aMn6(S=4)single molecule magnet grafted on Au(111)

2008 ◽  
Vol 77 (8) ◽  
Author(s):  
U. del Pennino ◽  
V. Corradini ◽  
R. Biagi ◽  
V. De Renzi ◽  
F. Moro ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Single Molecule ◽  
Single Molecule Magnet

scholarly journals Electronic structure study by means of x-ray spectroscopy and theoretical calculations of the “ferric star” single molecule magnet

2006 ◽  
Vol 124 (4) ◽  
pp. 044503 ◽  
Author(s):  
A. F. Takács ◽  
M. Neumann ◽  
A. V. Postnikov ◽  
K. Kuepper ◽  
A. Scheurer ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Single Molecule ◽  
Theoretical Calculations ◽  
Structure Study ◽  
Single Molecule Magnet ◽  
X Ray

scholarly journals Luminescence‐Driven Electronic Structure Determination in a Textbook Dimeric Dy III ‐Based Single‐Molecule Magnet

2020 ◽  
Vol 26 (19) ◽  
pp. 4389-4395 ◽  
Author(s):  
Djamila Guettas ◽  
Frédéric Gendron ◽  
Guglielmo Fernandez Garcia ◽  
François Riobé ◽  
Thierry Roisnel ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Single Molecule ◽  
Structure Determination ◽  
Single Molecule Magnet

scholarly journals Correction: Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization

2019 ◽  
Vol 10 (11) ◽  
pp. 3429-3429
Author(s):  
Mauro Perfetti ◽  
Maren Gysler ◽  
Yvonne Rechkemmer-Patalen ◽  
Peng Zhang ◽  
Hatice Taştan ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Single Molecule ◽  
Single Molecule Magnet

Correction for ‘Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization’ by Mauro Perfetti et al., Chem. Sci., 2019, 10, 2101–2110.

scholarly journals Multitechnique investigation of Dy3 – implications for coupled lanthanide clusters

2016 ◽  
Vol 7 (7) ◽  
pp. 4347-4354 ◽  
Author(s):  
Maren Gysler ◽  
Fadi El Hallak ◽  
Liviu Ungur ◽  
Raphael Marx ◽  
Michael Hakl ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Electronic Structure ◽  
Infrared Spectroscopy ◽  
Single Molecule ◽  
Far Infrared ◽  
Far Infrared Spectroscopy ◽  
Single Molecule Magnet ◽  
Torque Magnetometry

Torque magnetometry and far-infrared spectroscopy elucidate electronic structure and magnetic properties of Dy3 single molecule magnet.

scholarly journals Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization

2019 ◽  
Vol 10 (7) ◽  
pp. 2101-2110 ◽  
Author(s):  
Mauro Perfetti ◽  
Maren Gysler ◽  
Yvonne Rechkemmer-Patalen ◽  
Peng Zhang ◽  
Hatice Taştan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Electronic Structure ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Depth Determination

We present the in-depth determination of the magnetic properties and electronic structure of the luminescent and volatile dysprosium-based single molecule magnet [Dy2(bpm)(fod)6] (Hfod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione, bpm = 2,2-bipyrimidine).

Exchange-Biasing in a Dinuclear Dysprosium(III) Single-Molecule Magnet with a Large Energy Barrier for Magnetization Reversal

2019 ◽  
Author(s):  
Tian Han ◽  
Marcus J. Giansiracusa ◽  
Zi-Han Li ◽  
You-Song Ding ◽  
Nicholas F. Chilton ◽  
...  
Keyword(s):  
Single Molecule ◽  
Magnetization Reversal ◽  
Energy Barrier ◽  
Magnetic Hysteresis ◽  
Large Energy ◽  
Magnetic Studies ◽  
Bridging Ligands ◽  
Single Molecule Magnet ◽  
Exchange Biasing

A dichlorido-bridged dinuclear dysprosium(III) single-molecule magnet [Dy<sub>2</sub>L<sub>2</sub>(<i>µ</i>-Cl)<sub>2</sub>(THF)<sub>2</sub>] has been made using a diamine-bis(phenolate) ligand, H<sub>2</sub>L. Magnetic studies show an energy barrier for magnetization reversal (<i>U</i><sub>eff</sub>) around 1000 K. Exchange-biasing effect is clearly seen in magnetic hysteresis with steps up to 4 K. <i>Ab</i> initio calculations exclude the possibility of pure dipolar origin of this effect leading to the conclusion that super-exchange <i>via</i> the chloride bridging ligands is important.

Correlating Blocking Temperatures in Single Molecule Magnets with Raman Relaxation

2018 ◽  
Author(s):  
Marcus J. Giansiracusa ◽  
Andreas Kostopoulos ◽  
George F. S. Whitehead ◽  
David Collison ◽  
Floriana Tuna ◽  
...  
Keyword(s):  
Relaxation Time ◽  
Single Molecule ◽  
Energy Barrier ◽  
Thermal Relaxation ◽  
Relaxation Mechanism ◽  
Blocking Temperature ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Key Parameter

We report a six coordinate DyIII single-molecule magnet<br>(SMM) with an energy barrier of 1110 K for thermal relaxation of<br>magnetization. The sample shows no retention of magnetization<br>even at 2 K and this led us to find a good correlation between the<br>blocking temperature and the Raman relaxation regime for SMMs.<br>The key parameter is the relaxation time (𝜏<sub>switch</sub>) at the point where<br>the Raman relaxation mechanism becomes more important than<br>Orbach.

scholarly journals Solid‐State Near‐Infrared Circularly Polarized Luminescence from Chiral YbIII‐Single‐Molecule Magnet

2021 ◽  
Author(s):  
Fabrice Pointillart ◽  
Bertrand Lefeuvre ◽  
Carlo Andrea Mattei ◽  
Jessica Flores Gonzalez ◽  
Frédéric Gendron ◽  
...  
Keyword(s):  
Solid State ◽  
Single Molecule ◽  
Near Infrared ◽  
Circularly Polarized ◽  
Single Molecule Magnet ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence
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