scholarly journals Multitechnique investigation of Dy3 – implications for coupled lanthanide clusters

2016 ◽  
Vol 7 (7) ◽  
pp. 4347-4354 ◽  
Author(s):  
Maren Gysler ◽  
Fadi El Hallak ◽  
Liviu Ungur ◽  
Raphael Marx ◽  
Michael Hakl ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Electronic Structure ◽  
Infrared Spectroscopy ◽  
Single Molecule ◽  
Far Infrared ◽  
Far Infrared Spectroscopy ◽  
Single Molecule Magnet ◽  
Torque Magnetometry

Torque magnetometry and far-infrared spectroscopy elucidate electronic structure and magnetic properties of Dy3 single molecule magnet.

scholarly journals Determination of the electronic structure of a dinuclear dysprosium single molecule magnet without symmetry idealization

2019 ◽  
Vol 10 (7) ◽  
pp. 2101-2110 ◽  
Author(s):  
Mauro Perfetti ◽  
Maren Gysler ◽  
Yvonne Rechkemmer-Patalen ◽  
Peng Zhang ◽  
Hatice Taştan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Electronic Structure ◽  
Single Molecule ◽  
Single Molecule Magnet ◽  
Depth Determination

We present the in-depth determination of the magnetic properties and electronic structure of the luminescent and volatile dysprosium-based single molecule magnet [Dy2(bpm)(fod)6] (Hfod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione, bpm = 2,2-bipyrimidine).

scholarly journals Synchrotron-Based High Resolution Far-Infrared Spectroscopy of trans-Butadiene

2020 ◽  
Vol 124 (12) ◽  
pp. 2427-2435 ◽  
Author(s):  
Marie-Aline Martin-Drumel ◽  
Jessica P. Porterfield ◽  
Manuel Goubet ◽  
Pierre Asselin ◽  
Robert Georges ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
High Resolution ◽  
Far Infrared ◽  
Far Infrared Spectroscopy

scholarly journals A Dy(III) Fluorescent Single-Molecule Magnet Based on a Rhodamine 6G Ligand

Inorganics ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 51
Author(s):  
Lin Miao ◽  
Mei-Jiao Liu ◽  
Man-Man Ding ◽  
Yi-Quan Zhang ◽  
Hui-Zhong Kou
Keyword(s):  
Magnetic Properties ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Rhodamine 6G ◽  
Bond Angle ◽  
Magnetic Measurements ◽  
Single Molecule Magnet ◽  
Lanthanide Metals ◽  
Process Studies ◽  
Dual Functions

The complexes of lanthanide metals, especially dysprosium, can generally exhibit excellent magnetic properties. By means of modifying ligands, dual functions or even multi-functions can be achieved. Here, we synthesized an eight-coordinate Dy(III) complex 1, [Dy(HL-o)2(MeOH)2](ClO4)3·4.5MeOH, which is single-molecule magnet (SMM), and the introduction of the rhodamine 6G chromophore in the ring-opened ligand HL-o realizes ligand-centered fluorescence in addition to SMM. Magnetic measurements and ab initio calculations indicate that the magnetic relaxation for complex 1 should be due to the Raman relaxation process. Studies on magneto-structural correlationship of the rhodamine salicylaldehyde hydrazone Dy(III) complexes show that the calculated energy of the first Kramers Doublet (EKD1) is basically related to the Ophenoxy-Dy-Ophenoxy bond angle, i.e., the larger Ophenoxy-Dy-Ophenoxy bond angle corresponds to a larger EKD1.

Multifunctional properties of {CuII2LnIII2} systems involving nitrogen-rich nitronyl nitroxide: single-molecule magnet behavior, luminescence, magnetocaloric effects and heat capacity

2021 ◽  
Author(s):  
Hongdao Li ◽  
Pei Jing ◽  
Jiao Lu ◽  
Lu Xi ◽  
Qi Wang ◽  
...  
Keyword(s):  
Heat Capacity ◽  
Magnetic Properties ◽  
Single Molecule ◽  
Nitroxide Radical ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical ◽  
Single Molecule Magnet ◽  
Luminescence Behavior ◽  
Multifunctional Properties

A family of 3d–4f heterometallic ring-shaped clusters on the basis of a nitrogen-rich nitronyl nitroxide radical have been obtained, and they feature polyfunctionality including magnetic properties, thermodynamics and luminescence behavior.

Tunable Far-Infrared Spectroscopy of HF, H35Cl, and H37Cl in the 6 to 9 THz Region

1999 ◽  
Vol 194 (2) ◽  
pp. 283-284 ◽  
Author(s):  
Hitoshi Odashima ◽  
Lyndon R. Zink ◽  
K.M. Evenson
Keyword(s):  
Infrared Spectroscopy ◽  
Far Infrared ◽  
Far Infrared Spectroscopy

High-resolution far-infrared spectroscopy at NSLS beamline U12IR

2008 ◽  
Vol 51 (5) ◽  
pp. 404-406 ◽  
Author(s):  
G.L. Carr ◽  
R.J. Smith ◽  
L. Mihaly ◽  
H. Zhang ◽  
D.H. Reitze ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
High Resolution ◽  
Far Infrared ◽  
Far Infrared Spectroscopy
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