Probing electron correlation, charge transfer, and Coster-Kronig transitions at the3dand4dthresholds of Nd by resonant inelastic scattering

1999 ◽  
Vol 59 (8) ◽  
pp. 5452-5456 ◽  
Author(s):  
A. Moewes ◽  
D. L. Ederer ◽  
M. M. Grush ◽  
T. A. Callcott
Keyword(s):  
Charge Transfer ◽  
Inelastic Scattering ◽  
Electron Correlation

π-Back-Donation Effect of the Cyanide Ligands on the Electron Correlation and Charge Transfer in Prussian Blue RbMn[Fe(CN)6]

2010 ◽  
Vol 49 (7) ◽  
pp. 3086-3088 ◽  
Author(s):  
Chuan Tian ◽  
Erjun Kan ◽  
Changhoon Lee ◽  
Myung-Hwan Whangbo
Keyword(s):  
Charge Transfer ◽  
Prussian Blue ◽  
Electron Correlation ◽  
Cyanide Ligands ◽  
Back Donation

Vibrationally resolved inelastic scattering and charge transfer in H+ +C2H2 collisions

1991 ◽  
Vol 95 (11) ◽  
pp. 7969-7983 ◽  
Author(s):  
Natasha Aristov ◽  
Gereon Niedner‐Schatteburg ◽  
J. Peter Toennies ◽  
Ying‐Nan Chiu
Keyword(s):  
Charge Transfer ◽  
Inelastic Scattering

Core-hole induced charge transfer and Coster-Kronig enhanced fluorescence at the3dthreshold of lanthanum studied by resonant inelastic scattering

1998 ◽  
Vol 58 (24) ◽  
pp. R15951-R15954 ◽  
Author(s):  
A. Moewes ◽  
S. Stadler ◽  
R. P. Winarski ◽  
D. L. Ederer ◽  
M. M. Grush ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Inelastic Scattering ◽  
Enhanced Fluorescence ◽  
Core Hole ◽  
Induced Charge

scholarly journals Electron Density Distributions and Atomic Charges

1993 ◽  
Vol 48 (1-2) ◽  
pp. 180-192 ◽  
Author(s):  
B. Hess ◽  
H. L. Lin ◽  
J. E. Niu ◽  
W. H. E. Schwarz
Keyword(s):  
Charge Transfer ◽  
Electron Correlation ◽  
Form Factors ◽  
Ionic Charge ◽  
Small Perturbations ◽  
X Ray ◽  
Crystal Fields ◽  
Density Distributions ◽  
Ionic Systems ◽  
Partial Charges

Abstract Accurate electron densities and X-ray form factors of Li, Be, F and their ions have been calculated. Electron correlation, crystal fields and ionic charge transfer change the form factors by up to a few percent, mainly in the range of sin θ/ λ < 1/3 Â -1 . Although electron correlation and crystal fields are small perturbations, their effects on the density and form factor are not additive. Densities or form factors of atomic and ionic systems are very similar; [Li0F0] and [Li+F-] procrystals differ by an effective charge transfer of not more than 0.4 e. Charge transfer and charge overlap in crystals cannot be distinguished uniquely. When the experimental data on Li2BeF4 (approximately reproduced by 3/4 atomic plus 1/4 ionic procrystal) are interpreted from the atomic partial charges are as low as 0.1 e (Li+ 0.12Be+ 0.2F- 0.14); when interpreted from the ionic viewpoint,the charges are much higher, namely 0.7 e. Intermediate viewpoints are also possible.

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