π-Back-Donation Effect of the Cyanide Ligands on the Electron Correlation and Charge Transfer in Prussian Blue RbMn[Fe(CN)6]

2010 ◽  
Vol 49 (7) ◽  
pp. 3086-3088 ◽  
Author(s):  
Chuan Tian ◽  
Erjun Kan ◽  
Changhoon Lee ◽  
Myung-Hwan Whangbo
Keyword(s):  
Charge Transfer ◽  
Prussian Blue ◽  
Electron Correlation ◽  
Cyanide Ligands ◽  
Back Donation

X-RAY ABSORPTION EVIDENCE FOR THE BACK-DONATION IN IRON CYANIDE COMPLEXES

2002 ◽  
Vol 09 (01) ◽  
pp. 359-364 ◽  
Author(s):  
A. S. VINOGRADOV ◽  
A. B. PREOBRAJENSKI ◽  
S. A. KRASNIKOV ◽  
T. CHASSÉ ◽  
R. SZARGAN ◽  
...  
Keyword(s):  
Charge Transfer ◽  
High Resolution ◽  
Absorption Spectra ◽  
Spectral Characteristics ◽  
X Ray ◽  
Iron Cyanide ◽  
Cyanide Complexes ◽  
Cyanide Ligands ◽  
X Ray Absorption ◽  
Back Donation

High-resolution, uniformly calibrated Fe 2p 3/2 absorption spectra of various Fe(II) and Fe(III) compounds with the metal atom octahedrally coordinated to atomic and molecular ligands are analyzed expecting changes in the absorption spectra due to differences in the formal valence state and in the character of the chemical bond. Particular attention is given to revealing spectral characteristics of the 3d π–2π(π*) charge transfer (π-back-donation effect) between the iron atom and cyanide ligands.

Photoinduced effects on the magnetic properties of the (Fe0.2Cr0.8)1.5[Cr(CN)6] Prussian blue analogue

2019 ◽  
Vol 7 (8) ◽  
pp. 2305-2317
Author(s):  
Francisco Jesús Luque ◽  
Iwona Agnieszka Kowalik ◽  
Juan Pablo Prieto-Ruiz ◽  
Miguel Ángel Niño ◽  
Helena Prima-García ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Charge Transfer ◽  
Visible Light ◽  
Prussian Blue ◽  
Magnetic Moments ◽  
Lattice Misfit ◽  
Prussian Blue Analogue

Visible light absorbed by Fe cations in a Prussian blue analogue induces charge transfer, and reduces lattice misfit and magnetic moments.

Effect of electrolyte cations on the charge transfer in films of prussian blue

2000 ◽  
Vol 36 (5) ◽  
pp. 522-532 ◽  
Author(s):  
V. V. Kondrat’ev ◽  
A. V. Tikhomirova ◽  
S. V. Yakovleva ◽  
V. V. Malev
Keyword(s):  
Charge Transfer ◽  
Prussian Blue
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