Comment on ‘‘Quadrupolar glass freezing in solid hydrogen: Distribution functions for the orientational order parameters’’

1995 ◽  
Vol 51 (6) ◽  
pp. 3965-3965
Author(s):  
K. Walasek
2019 ◽  
Vol 21 (13) ◽  
pp. 6839-6843 ◽  
Author(s):  
Richard J. Mandle ◽  
John W. Goodby

Twist-bend (TB) phases possess a local helical structure with a pitch length of a few nanometers. X-ray scattering experiments on aligned samples of dimeric and oligomeric materials allows the orientational order parameters, orientational distribution functions and heliconical tilt angles to be calculated.


Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1262
Author(s):  
Mikhail A. Osipov ◽  
Maxim V. Gorkunov ◽  
Alexander A. Antonov

Density functional theory of rod-coil diblock copolymers, developed recently by the authors, has been generalised and used to study the liquid crystal ordering and microphase separation effects in the hexagonal, lamellar and nematic phases. The translational order parameters of rod and coil monomers and the orientational order parameters of rod-like fragments of the copolymer chains have been determined numerically by direct minimization of the free energy. The phase diagram has been derived containing the isotropic, the lamellar and the hexagonal phases which is consistent with typical experimental data. The order parameter profiles as functions of temperature and the copolymer composition have also been determined in different anisotropic phases. Finally, the spatial distributions of the density of rigid rod fragments and of the corresponding orientational order parameter in the hexagonal phase have been calculated.


2002 ◽  
Vol 116 (20) ◽  
pp. 9078-9088 ◽  
Author(s):  
Patrick Ilg ◽  
Martin Kröger ◽  
Siegfried Hess

Pramana ◽  
1982 ◽  
Vol 19 (4) ◽  
pp. 349-355 ◽  
Author(s):  
Srinivasa ◽  
M M M Abdoh ◽  
N C Shivaprakash ◽  
J Shashi-Dhara Prasad

2019 ◽  
Author(s):  
Richard Mandle ◽  
John W. Goodby

We compare the order parameters, orientational distribution functions (ODF) and heliconical tilt angles of the TB phase exhibited by a liquid-crystalline dimer (CB7CB) to a tetramer (O47) and hexamer (O67) by SAXS/WAXS. Following the N-TB phase transition we find that all order parameters decrease, and while 〈P2 〉 remains positive 〈P4 〉 becomes negative. For all three materials the order parameter 〈P6 〉 is near zero in both phases. The ODF is sugarloaf-like in the nematic phase and volcano-like in the TB phase, allowing us to estimate the heliconical tilt angle of each material and its thermal evolution. The heliconical tilt angle appears to be largely independent of the material studied despite the differing number of mesogenic units.


2009 ◽  
Vol 82 (6) ◽  
pp. 433-443 ◽  
Author(s):  
Gautam Sarkar ◽  
Malay Kumar Das ◽  
Ranjit Paul ◽  
Banani Das ◽  
Wolfgang Weissflog

1994 ◽  
Vol 49 (14) ◽  
pp. 9460-9468 ◽  
Author(s):  
K. Walasek ◽  
K. Lukierska-Walasek

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