scholarly journals Order parameters, orientational distribution functions and heliconical tilt angles of oligomeric liquid crystals

2019 ◽  
Vol 21 (13) ◽  
pp. 6839-6843 ◽  
Author(s):  
Richard J. Mandle ◽  
John W. Goodby

Twist-bend (TB) phases possess a local helical structure with a pitch length of a few nanometers. X-ray scattering experiments on aligned samples of dimeric and oligomeric materials allows the orientational order parameters, orientational distribution functions and heliconical tilt angles to be calculated.

2018 ◽  
Vol 46 (1) ◽  
pp. 11-24 ◽  
Author(s):  
Mark T. Sims ◽  
Laurence C. Abbott ◽  
Robert M. Richardson ◽  
John W. Goodby ◽  
John N. Moore

1979 ◽  
Vol 1 (1) ◽  
pp. 35-42 ◽  
Author(s):  
Aleksander Braude ◽  
Asger Lindegaard-Andersen ◽  
Kim Carneiro ◽  
Allan E. Underhill

RSC Advances ◽  
2017 ◽  
Vol 7 (64) ◽  
pp. 40480-40485 ◽  
Author(s):  
Richard J. Mandle ◽  
Stephen J. Cowling ◽  
John W. Goodby

A combination of microscopy, X-ray scattering, calorimetry and applied electric field studies demonstrates the 4-alkoxy-4′-nitrobiphenyls are potentially of use for next generation, backlight free scattering mode LCD devices.


2019 ◽  
Author(s):  
Richard Mandle ◽  
John W. Goodby

We compare the order parameters, orientational distribution functions (ODF) and heliconical tilt angles of the TB phase exhibited by a liquid-crystalline dimer (CB7CB) to a tetramer (O47) and hexamer (O67) by SAXS/WAXS. Following the N-TB phase transition we find that all order parameters decrease, and while 〈P2 〉 remains positive 〈P4 〉 becomes negative. For all three materials the order parameter 〈P6 〉 is near zero in both phases. The ODF is sugarloaf-like in the nematic phase and volcano-like in the TB phase, allowing us to estimate the heliconical tilt angle of each material and its thermal evolution. The heliconical tilt angle appears to be largely independent of the material studied despite the differing number of mesogenic units.


2018 ◽  
Vol 267 ◽  
pp. 286-296 ◽  
Author(s):  
Oleksandr Buluy ◽  
Natalie Aryasova ◽  
Oleksandr Tereshchenko ◽  
Yuriy Kurioz ◽  
Vassili Nazarenko ◽  
...  

Soft Matter ◽  
2019 ◽  
Vol 15 (16) ◽  
pp. 3315-3322 ◽  
Author(s):  
Taiki Hoshino ◽  
Masanari Nakayama ◽  
So Fujinami ◽  
Tomotaka Nakatani ◽  
Yoshiki Kohmura ◽  
...  

The static structure and dynamics of liquid-crystalline colloidal dispersions of hydroxyapatite nanorods are studied using X-ray scattering techniques.


1991 ◽  
Vol 46 (7) ◽  
pp. 605-608 ◽  
Author(s):  
E. Matsubara ◽  
Y. Waseda ◽  
A. P. Tsai ◽  
A. Inoue ◽  
T. Masumoto

A structural study of an as-quenched decagonal Al75Fe15Ni10 alloy has been carried out by anomalous x-ray scattering (AXS) as well as ordinary x-ray diffraction. The environmental radial distribution functions (RDFs) for Fe and Ni determined by the AXS measurements turned out to resemble each other and to be similar to the ordinary RDF obtained by ordinary x-ray diffraction. These results clearly show that the Ni and Fe atoms are homogeneously distributed and occupy the same sites in the decagonal structure of Al75Fe15Ni10.


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