Unification of polaron and soliton theories of exciton transport

1989 ◽  
Vol 40 (14) ◽  
pp. 9876-9887 ◽  
Author(s):  
David W. Brown ◽  
Zoran Ivić
Keyword(s):  
2020 ◽  
Author(s):  
Alvaro J Magdaleno ◽  
Michael Seitz ◽  
Michel Frising ◽  
Ana Herranz de la Cruz ◽  
Antonio I. Fernández-Domínguez ◽  
...  

We present transient microscopy measurements of interlayer energy transport in (PEA)<sub>2</sub>PbI<sub>4</sub> perovskite. We find efficient interlayer exciton transport (0.06 cm<sup>2</sup>/s), which translates into a diffusion length that exceeds 100 nm and a sub-ps timescale for energy transfer. While still slower than in-plane exciton transport (0.2 cm<sup>2</sup>/s), our results show that excitonic energy transport is considerably less anisotropic than charge-carrier transport for 2D perovskites.


2011 ◽  
Vol 96 (1) ◽  
pp. 10001 ◽  
Author(s):  
T. Scholak ◽  
T. Wellens ◽  
A. Buchleitner
Keyword(s):  

2021 ◽  
Vol 72 (1) ◽  
pp. 591-616 ◽  
Author(s):  
Wjatscheslaw Popp ◽  
Dominik Brey ◽  
Robert Binder ◽  
Irene Burghardt

Due to the subtle interplay of site-to-site electronic couplings, exciton delocalization, nonadiabatic effects, and vibronic couplings, quantum dynamical studies are needed to elucidate the details of ultrafast photoinduced energy and charge transfer events in organic multichromophoric systems. In this vein, we review an approach that combines first-principles parameterized lattice Hamiltonians with accurate quantum dynamical simulations using advanced multiconfigurational methods. Focusing on the elementary transfer steps in organic functional materials, we address coherent exciton migration and creation of charge transfer excitons in homopolymers, notably representative of the poly(3-hexylthiophene) material, as well as exciton dissociation at polymer:fullerene heterojunctions. We emphasize the role of coherent transfer, trapping effects due to high-frequency phonon modes, and thermal activation due to low-frequency soft modes that drive a diffusive dynamics.


2018 ◽  
Vol 113 (25) ◽  
pp. 252101 ◽  
Author(s):  
Darwin F. Cordovilla Leon ◽  
Zidong Li ◽  
Sung Woon Jang ◽  
Che-Hsuan Cheng ◽  
Parag B. Deotare
Keyword(s):  

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