Vibrational and electronic spectra of one-dimensional organic charge-transfer crystals: Model for a tetramerized cluster structure

1989 ◽  
Vol 40 (18) ◽  
pp. 12187-12195 ◽  
Author(s):  
M. Meneghetti ◽  
C. Pecile
Keyword(s):  
Charge Transfer ◽  
Electronic Spectra ◽  
Cluster Structure ◽  
One Dimensional

scholarly journals Twisted One-Dimensional Charge Transfer and Related Y-Shaped Chromophores with a 4H-Pyranylidene Donor: Synthesis and Optical Properties

2021 ◽  
Vol 86 (4) ◽  
pp. 3152-3163
Author(s):  
Víctor Tejeda-Orusco ◽  
Raquel Andreu ◽  
Jesús Orduna ◽  
Belén Villacampa ◽  
Santiago Franco ◽  
...  
Keyword(s):  
Optical Properties ◽  
Charge Transfer ◽  
One Dimensional

Synthesis and Electronic Spectra of Disilatriptycene Oligomers: Evidence for Electronic Delocalization along the One-Dimensional Arrangement of Bridge-Head Disilanes

2008 ◽  
Vol 27 (21) ◽  
pp. 5441-5445 ◽  
Author(s):  
Shohei Sase ◽  
Yoen-Seok Cho ◽  
Atsushi Kawachi ◽  
Atsushi Wakamiya ◽  
Shigehiro Yamaguchi ◽  
...  
Keyword(s):  
Electronic Spectra ◽  
One Dimensional ◽  
Electronic Delocalization ◽  
The One

Compressibility and High-Pressure Electrical Resistivity of One-Dimensional Phthalocyanine Conductors: The Relationship with d-π Charge Transfer

1997 ◽  
Vol 296 (1) ◽  
pp. 255-268 ◽  
Author(s):  
Toshihiro Hiejima ◽  
Kyuya Yakushi ◽  
Takafumi Adachi ◽  
Osamu Shimomura ◽  
Keiki Takeda ◽  
...  
Keyword(s):  
High Pressure ◽  
Electrical Resistivity ◽  
Charge Transfer ◽  
One Dimensional ◽  
The Relationship

X-ray diffuse scattering as precursor of incommensurate Peierls transitions in one-dimensional organic charge transfer conductors

2004 ◽  
Vol 219 (11) ◽  
Author(s):  
Jean-Paul Pouget
Keyword(s):  
Charge Transfer ◽  
Charge Density Wave ◽  
Diffuse Scattering ◽  
Lattice Distortion ◽  
Density Wave ◽  
Periodic Lattice ◽  
One Dimensional ◽  
X Ray ◽  
Charge Transfer Salts ◽  
A Charge

AbstractQuasi-one dimensional (1D) conductors of the TTF-TCNQ family of charge transfer salts exhibit a Peierls transition which stabilizes a periodic lattice distortion (PLD), accompanied by a charge density wave (CDW) modulation, with an incommensurate 2

One-dimensionality and neutral-to-ionic transition of some mixed-stack charge-transfer complexes

2002 ◽  
Vol 12 (9) ◽  
pp. 357-360
Author(s):  
M. Buron ◽  
E. Collet ◽  
M. H. Lemée-Cailleau ◽  
H. Cailleau ◽  
T. Luty ◽  
...  
Keyword(s):  
Phase Transition ◽  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
Giant Dielectric ◽  
Ionic Transition ◽  
The One ◽  
Ct Complexes ◽  
Dimerization Process

Mixed-stack charge-transfer (CT) complexes undergoing the neutral-ionic (N-I) phase transition are molecular materials formed of stacks where electron donor (D) and acceptor (A) molecules regularly alternate. In the N phase, the CT is low and molecules are situated on inversion centers, while in the I phase, the increase of CT is accompanied by a lattice distortion (dimerization process and symmetry breaking). The one-dimensional (1D) architecture triggers the chain multistability by stabilizing lattice-relaxed (LR)-CT excitations ...D° A° D° A° $(D^+A^-)(D^+A^-)(D^+A^-)$ Do A" D° A° D°... These 1D nano-scale objects are at the heart of the equilibrium N-I phase transition and govern the fascinating physical properties such as giant dielectric response or photo-induced phase transformations. In this contribution, the 1D character of these critical excitations will be demonstrated by direct observation using high resolution X-Ray diffraction.

scholarly journals Cluster Structure of Optimal Solutions in Bipartitioning of Small Worlds

Entropy ◽  
2020 ◽  
Vol 22 (11) ◽  
pp. 1319
Author(s):  
Adam Lipowski ◽  
António L. Ferreira ◽  
Dorota Lipowska
Keyword(s):  
Cluster Structure ◽  
Finite Size ◽  
Lattice Models ◽  
Square Lattice ◽  
Dimensional Case ◽  
Two Dimensional ◽  
Small Worlds ◽  
Replica Symmetry ◽  
One Dimensional ◽  
Optimal Partitions

Using simulated annealing, we examine a bipartitioning of small worlds obtained by adding a fraction of randomly chosen links to a one-dimensional chain or a square lattice. Models defined on small worlds typically exhibit a mean-field behavior, regardless of the underlying lattice. Our work demonstrates that the bipartitioning of small worlds does depend on the underlying lattice. Simulations show that for one-dimensional small worlds, optimal partitions are finite size clusters for any fraction of additional links. In the two-dimensional case, we observe two regimes: when the fraction of additional links is sufficiently small, the optimal partitions have a stripe-like shape, which is lost for a larger number of additional links as optimal partitions become disordered. Some arguments, which interpret additional links as thermal excitations and refer to the thermodynamics of Ising models, suggest a qualitative explanation of such a behavior. The histogram of overlaps suggests that a replica symmetry is broken in a one-dimensional small world. In the two-dimensional case, the replica symmetry seems to hold, but with some additional degeneracy of stripe-like partitions.

Sign in / Sign up

Export Citation Format

Share Document