Heteropolytungstate complexes of the lanthanide elements. Part II. Electronic spectra: a metal–ligand charge-transfer transition of cerium(III)

1971 ◽  
Vol 0 (0) ◽  
pp. 1937-1940 ◽  
Author(s):  
R. D. Peacock ◽  
T. J. R. Weakley
Keyword(s):  
Charge Transfer ◽  
Electronic Spectra ◽  
Charge Transfer Transition ◽  
Lanthanide Elements ◽  
Ligand Charge Transfer ◽  
Metal Ligand

Unusual metal-ligand charge transfer in ferrocene functionalized μ3-O iron carboxylates observed with Mössbauer spectroscopy

2016 ◽  
Vol 407 ◽  
pp. 87-91 ◽  
Author(s):  
Valeriu Mereacre ◽  
Martin Schlageter ◽  
Andreas Eichhöfer ◽  
Thomas Bauer ◽  
Juliusz A. Wolny ◽  
...  
Keyword(s):  
Mössbauer Spectroscopy ◽  
Charge Transfer ◽  
Mossbauer Spectroscopy ◽  
Mößbauer Spectroscopy ◽  
Ligand Charge Transfer ◽  
Metal Ligand

Os(II) Phosphors with Near-Infrared Emission Induced by Ligand-to-Ligand Charge Transfer Transition

2014 ◽  
Vol 53 (17) ◽  
pp. 9366-9374 ◽  
Author(s):  
Jia-Ling Liao ◽  
Yun Chi ◽  
Shih-Hung Liu ◽  
Gene-Hsiang Lee ◽  
Pi-Tai Chou ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Near Infrared ◽  
Infrared Emission ◽  
Charge Transfer Transition ◽  
Ligand Charge Transfer ◽  
Near Infrared Emission

Structural and spectroscopic studies of transition metal nitrite complexes. IV. Crystal structure and spectra of cis-Aquabis[N,N-dimethyl(ethane-1,2-diamine)]-nitronickel(II) perchlorate

1981 ◽  
Vol 34 (10) ◽  
pp. 2085 ◽  
Author(s):  
AJ Finney ◽  
MA Hitchman ◽  
CL Raston ◽  
GL Rowbottom ◽  
AH White
Keyword(s):  
Molecular Structure ◽  
Lower Energy ◽  
Crystal And Molecular Structure ◽  
Visible Region ◽  
Spectroscopic Studies ◽  
Charge Transfer Transition ◽  
Lower Energy Band ◽  
Ligand Charge Transfer ◽  
Vibrational Progression ◽  
Metal Ligand

The crystal and molecular structure of the complex cis-aquabis[N,N-dimethyl(ethane-l,2-diamine)]- nitronickel(11) perchlorate is reported and the stereochemistry is compared with those observed for other nickel nitrite complexes formed by substituted amines. The electronic spectrum of the complex in the visible region is unusual, showing bands with maxima at 17750 and 21000 cm-1. The latter peak consists of a poorly resolved vibrational progression having an interval of c.600cm-1. While the lower energy band is assigned to the second spin-allowed 'd-d' transition of an octahedral nickel(11) complex, it is suggested that the band at 21000 cm-1 is due either to a metal → ligand charge-transfer transition, or to an internal n(O)→ π* nitrite transition.

Kinetically stable metal ligand charge transfer complexes as crosslinks in nanogels/hydrogels: Physical properties and cytotoxicity

2015 ◽  
Vol 26 ◽  
pp. 136-144 ◽  
Author(s):  
Rong Wang ◽  
Sanne K. Both ◽  
Mike Geven ◽  
Lucia Calucci ◽  
Claudia Forte ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Physical Properties ◽  
Charge Transfer Complexes ◽  
Ligand Charge Transfer ◽  
Metal Ligand

Flexible Organic Phototransistor Array with Enhanced Responsivity via Metal–Ligand Charge Transfer

2016 ◽  
Vol 8 (11) ◽  
pp. 7291-7299 ◽  
Author(s):  
Xien Liu ◽  
Eun Kwang Lee ◽  
Dong Yeong Kim ◽  
Hojeong Yu ◽  
Joon Hak Oh
Keyword(s):  
Charge Transfer ◽  
Ligand Charge Transfer ◽  
Organic Phototransistor ◽  
Metal Ligand

Mononuclear oxo thiolato compounds of molybdenum(V)

1978 ◽  
Vol 31 (2) ◽  
pp. 279 ◽  
Author(s):  
IW Boyd ◽  
IG Dance ◽  
KS Murray ◽  
AG Wedd
Keyword(s):  
Magnetic Susceptibility ◽  
Charge Transfer ◽  
Solid State ◽  
Spectral Data ◽  
Electronic Spectra ◽  
Charge Transfer Transition ◽  
Electronic Spectral Data

The intensely blue salts B+ [MoO(SAr)4]- (B+ = quaternary cation; Ar = phenyl, p-tolyl) have been isolated. Magnetic susceptibility, e.s.r., conductance and electronic spectral data indicate that the complexes are essentially mononuclear both in the solid state and in solution. The solution electronic spectra exhibit an intense maximum at 598 nm, which is tentatively assigned to a sulphur-to-molybdenum charge- transfer transition.

scholarly journals Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions

2015 ◽  
Vol 6 (4) ◽  
pp. 2474-2487 ◽  
Author(s):  
Neil C. Tomson ◽  
Kamille D. Williams ◽  
Xuliang Dai ◽  
Stephen Sproules ◽  
Serena DeBeer ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Ligand Charge Transfer ◽  
Ligand Interactions ◽  
Metal Ligand

Covalent metal–ligand interactions can lead to Cu K pre-edge transitions that result from metal-to-ligand charge transfer, instead of 1s → 3d, character.

Metal−Ligand Charge-Transfer-Promoted Photoelectronic Bergman Cyclization of Copper Metalloenediynes:  Photochemical DNA Cleavage via C-4‘ H-Atom Abstraction

2003 ◽  
Vol 125 (21) ◽  
pp. 6434-6446 ◽  
Author(s):  
Pedro J. Benites ◽  
Rebecca C. Holmberg ◽  
Diwan S. Rawat ◽  
Brian J. Kraft ◽  
Lee J. Klein ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Dna Cleavage ◽  
Bergman Cyclization ◽  
Ligand Charge Transfer ◽  
Metal Ligand
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