Silicide formation at the Ti/Si(111) interface: Room-temperature reaction and Schottky-barrier formation

1987 ◽  
Vol 35 (12) ◽  
pp. 6213-6221 ◽  
Author(s):  
M. del Giudice ◽  
J. J. Joyce ◽  
M. W. Ruckman ◽  
J. H. Weaver
1990 ◽  
Vol 41-42 ◽  
pp. 169-173 ◽  
Author(s):  
N. Esser ◽  
M. Hünermann ◽  
U. Resch ◽  
D. Spaltmann ◽  
J. Geurts ◽  
...  

1986 ◽  
Vol 77 ◽  
Author(s):  
K. K. Chin ◽  
R. Cao ◽  
T. Kendelewicz ◽  
K. Miyano ◽  
M. D. Williams ◽  
...  

ABSTRACTSchottky barrier formation at room temperature (RT) and low temperature (LT) is studied by photoemission. In the low Al coverage regime (from 0.001 to about 1 ML), it is found that, compared to RT pinning behavior, the n-GaAs(110) surface band bending is attenuated, while the p-GaAs(110) surface band bending is enhanced. This striking phenomenon indicates that, by lowering the substrate temperature, one reduces the disturbance of the GaAs(110) surface, and the surface Fermi level of the n- and p-GaAs(110) tends to go to the same position, the so-called Schottky limit that characterizes a perfect defect-free interface. However, as the coverage increases (up to 30 ML), a new mechanism (in the framework of the unified defect model, it is the formation of defect levels due to the energy released as the adsorbed Al atoms start to form clusters and replace Ga) associated with a disturbed surface becomes dominant. Thus, the LT Fermi level positions of n- and p-GaAs move towards the RT positions, the so-called Bardeen limit. This demonstrates that, by controlling the surface disturbance, one can modify the Schottky barrier formation process, going from the Schottky limit which does not have pinning centers to the Bardeen limit which suggests the existence of pinning centers.


2021 ◽  
Author(s):  
Josef Boronski ◽  
John Seed ◽  
Ashley Wooles ◽  
Stephen Liddle

Room temperature reaction of the uranium(IV)-carbene [U{C(SiMe3)(PPh2)}(BIPMTMS)(μ-Cl)Li(TMEDA)(μ-TMEDA)0.5]2 (1, BIPMTMS = C(PPh2NSiMe3)2) with white phosphorus (P4) produces the organo-P5 compound [P5{C(SiMe3)(PPh2)}2][Li(TMEDA)2] (2) and the uranium(IV)-methanediide [U{BIPMTMS}{Cl}{μ-Cl}2{Li(TMEDA)}] (3). This is an unprecedented...


1991 ◽  
Vol 58 (20) ◽  
pp. 2243-2245 ◽  
Author(s):  
Masao Yamada ◽  
Anita K. Wahi ◽  
Paul L. Meissner ◽  
Alberto Herrera‐Gomez ◽  
Tom Kendelewicz ◽  
...  

2018 ◽  
Vol 113 (22) ◽  
pp. 222402 ◽  
Author(s):  
L. Huang ◽  
H. Wu ◽  
P. Liu ◽  
X. M. Zhang ◽  
B. S. Tao ◽  
...  

1990 ◽  
Vol 41 (2) ◽  
pp. 991-994 ◽  
Author(s):  
M. Vos ◽  
C. M. Aldao ◽  
D. J. W. Aastuen ◽  
J. H. Weaver

1990 ◽  
Vol 64 (21) ◽  
pp. 2551-2554 ◽  
Author(s):  
S. Chang ◽  
L. J. Brillson ◽  
Y. J. Kime ◽  
D. S. Rioux ◽  
P. D. Kirchner ◽  
...  

1987 ◽  
Vol 35 (17) ◽  
pp. 9073-9084 ◽  
Author(s):  
M. Wittmer ◽  
P. Oelhafen ◽  
K. N. Tu

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