Correlation between the self-diffusion coefficient of lithium and the equation of state

1985 ◽  
Vol 32 (8) ◽  
pp. 5462-5463 ◽  
Author(s):  
K. Eftaxias ◽  
J. Grammatikakis ◽  
P. Varotsos
Keyword(s):  
Diffusion Coefficient ◽  
Equation Of State ◽  
The Self ◽  
Self Diffusion ◽  
Self Diffusion Coefficient

Investigation on the Diffusion Behavior of Mo-Ni Interface

2010 ◽  
Vol 152-153 ◽  
pp. 1607-1610 ◽  
Author(s):  
Wei Chan Cao ◽  
Shu Hua Liang ◽  
Yue Xin Xue ◽  
Xian Hui Wang
Keyword(s):  
Solid Solution ◽  
Diffusion Coefficient ◽  
Electron Microscope ◽  
Intermetallic Compound ◽  
Diffusion Layer ◽  
Interdiffusion Coefficient ◽  
The Self ◽  
Diffusion Behavior ◽  
Self Diffusion ◽  
Self Diffusion Coefficient

In order to gain a deep insight into the mechanism of Ni-doped Mo activated sintering process, the diffusion behavior of Mo-Ni interface was studied utilizing a Mo-Ni diffusion couple. The phase structure and composition on the diffusion layer were characterized and analyzed by means of scanning electron microscope and transmission electron microscope, the self diffusion coefficient and interdiffusion coefficient were calculated. The results show that a diffusion layer is formed between Mo and Ni after sintering at 1223k for 1h, which is comprised of a δ-NiMo intermetallic compound and a limit solid solution containing small amounts of nickel. The self diffusion coefficient and interdiffusion coefficient are 2.068×10-18cm2/s and 4.5×10-12cm2/s, respectively. It is suggested that the diffusion rate of Mo in δ-NiMo intermetallic compound and a limit solid solution containing small amounts of nickel is 106 times bigger than that of self diffusion, and the intermetallic compound layer provides a short diffusion path for Mo activated sintering.

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