scholarly journals Dramatic decrease of Joule losses in the coupling between a crystalline gold film and single colloidal CdSe/CdS nanocrystals at 4 K

2020 ◽  
Vol 101 (7) ◽  
Author(s):  
A. Coste ◽  
L. Moreaud ◽  
G. Colas des Francs ◽  
S. Buil ◽  
X. Quélin ◽  
...  
2010 ◽  
Vol 97 (5) ◽  
pp. 053109 ◽  
Author(s):  
I. Mallek-Zouari ◽  
S. Buil ◽  
X. Quélin ◽  
B. Mahler ◽  
B. Dubertret ◽  
...  

Author(s):  
M. Talianker ◽  
D.G. Brandon

A new specimen preparation technique for visualizing macromolecules by conventional transmission electron microscopy has been developed. In this technique the biopolymer-molecule is embedded in a thin monocrystalline gold foil. Such embedding can be performed in the following way: the biopolymer is deposited on an epitaxially-grown thin single-crystal gold film. The molecule is then occluded by further epitaxial growth. In such an epitaxial sandwich an occluded molecule is expected to behave as a crystal-lattice defect and give rise to contrast in the electron microscope.The resolution of the method should be limited only by the precision with which the epitaxially grown gold reflects the details of the molecular structure and, in favorable cases, can approach the lattice resolution limit.In order to estimate the strength of the contrast due to the void-effect arising from occlusion of the DNA-molecule in a gold crystal some calculations were performed.


2008 ◽  
Author(s):  
Vincenzo Resta ◽  
Anna Maria Laera ◽  
Maria Cristina Ferrara ◽  
Emanuela Piscopiello ◽  
Saverio Mazzarelli ◽  
...  

2019 ◽  
Author(s):  
Kam Sang Kwok ◽  
Yuxuan Wang ◽  
Michael Cao ◽  
Hao Shen ◽  
Weinan Xu ◽  
...  

<p>The local structure and geometry of catalytic interfaces can influence the selectivity of chemical reactions. Here, using a pre-strained polymer, we uniaxially compress a thin gold film to form a nano-folded catalyst. We observe two kinds of folds and can tune the ratio of loose to tight folds by varying the extent of pre-strain in the polymer. We characterize the nano-folded catalysts using x-ray diffraction, scanning, and transmission electron microscopy. We observe grain reorientation and coarsening in the nano-folded gold catalysts. Electroreduction of carbon dioxide with these nano-folded catalysts reveals an enhancement of Faradaic efficiency for carbon monoxide formation by a factor of about four. This result suggests that electrolyte mass transport limitations and an increase of the local pH in the tight folds of the catalyst outweigh the effects of alterations in grain characteristics. Together, our studies demonstrate that nano-folded geometries can significantly alter grain characteristics, mass transport, and catalytic selectivity. </p>


Chemosensors ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 173
Author(s):  
Dana Miu ◽  
Izabela Constantinoiu ◽  
Valentina Dinca ◽  
Cristian Viespe

Laser-deposited gold immobilization layers having different porosities were incorporated into love wave surface acoustic wave sensors (LW-SAWs). Variation of pulsed laser deposition parameters allows good control of the gold film morphology. Biosensors with various gold film porosities were tested using the biotin–avidin reaction. Control of the Au layer morphology is important since the biotin and avidin layer morphologies closely follow that of the gold. The response of the sensors to biotin/avidin, which is a good indicator of biosensor performance, is improved when the gold layer has increased porosity. Given the sizes of the proteins, the laser-deposited porous gold interfaces have optimal pore dimensions to ensure protein stability.


2012 ◽  
Vol 512-515 ◽  
pp. 1511-1515
Author(s):  
Chun Lin Zhao ◽  
Li Xing ◽  
Xiao Hong Liang ◽  
Jun Hui Xiang ◽  
Fu Shi Zhang ◽  
...  

Cadmium sulfide (CdS) nanocrystals (NCs) were self-assembled and in-situ immobilized on the dithiocarbamate (DTCs)-functionalized polyethylene glycol terephthalate (PET) substrates between the organic (carbon disulfide diffused in n-hexane) –aqueous (ethylenediamine and Cd2+ dissolved in water) interface at room temperature. Powder X-ray diffraction measurement revealed the hexagonal structure of CdS nanocrystals. Morphological studies performed by scanning electron microscopy (SEM) and high-resolution transmission electron microscope (HRTEM) showed the island-like structure of CdS nanocrystals on PET substrates, as well as energy-dispersive X-ray spectroscopy (EDS) confirmed the stoichiometries of CdS nanocrystals. The optical properties of DTCs modified CdS nanocrystals were thoroughly investigated by ultraviolet-visible absorption spectroscopy (UV-vis) and fluorescence spectroscopy. The as-prepared DTCs present intrinsic hydrophobicity and strong affinity for CdS nanocrystals.


Climate ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 126
Author(s):  
Moon Taveirne ◽  
Laura Ekemar ◽  
Berta González Sánchez ◽  
Josefine Axelsson ◽  
Qiong Zhang

Glacier mass balance is heavily influenced by climate, with responses of individual glaciers to various climate parameters varying greatly. In northern Sweden, Rabots Glaciär’s mass balance has decreased since it started being monitored in 1982. To relate Rabots Glaciär’s mass balance to changes in climate, the sensitivity to a range of parameters is computed. Through linear regression of mass balance with temperature, precipitation, humidity, wind speed and incoming radiation the climate sensitivity is established and projections for future summer mass balance are made. Summer mass balance is primarily sensitive to temperature at −0.31 m w.e. per °C change, while winter mass balance is mainly sensitive to precipitation at 0.94 m w.e. per % change. An estimate using summer temperature sensitivity projects a dramatic decrease in summer mass balance to −3.89 m w.e. for the 2091–2100 period under climate scenario RCP8.5. With large increases in temperature anticipated for the next century, more complex modelling studies of the relationship between climate and glacier mass balance is key to understanding the future development of Rabots Glaciär.


Nano Letters ◽  
2021 ◽  
Author(s):  
Mahima Makkar ◽  
Lakshay Dheer ◽  
Anjali Singh ◽  
Luca Moretti ◽  
Margherita Maiuri ◽  
...  

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